Metal–organic frameworks for organic transformations by photocatalysis and photothermal catalysis

Chemical Society Reviews, Год журнала: 2024, Номер 53(18), С. 9378 - 9418

Опубликована: Янв. 1, 2024

Organic transformation by light-driven catalysis, especially, photocatalysis and photothermal denoted as photo(thermal) is an efficient, green, economical route to produce value-added compounds. In recent years, owing their diverse structure types, tunable pore sizes, abundant active sites, metal-organic framework (MOF)-based catalysis has attracted broad interest in organic transformations. this review, we provide a comprehensive systematic overview of MOF-based for First, the general mechanisms, unique advantages, strategies improve performance MOFs are discussed. Then, outstanding examples transformations over introduced according reaction type. addition, several representative advanced characterization techniques used revealing charge kinetics intermediates presented. Finally, prospects challenges field proposed. This review aims inspire rational design development materials with improved catalysis.

Язык: Английский

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Unlocking the potential of TiO2-based photocatalysts for green hydrogen energy through water-splitting: Recent advances, future perspectives and techno feasibility assessment

International Journal of Hydrogen Energy, Год журнала: 2024, Номер 59, С. 958 - 981

Опубликована: Фев. 13, 2024

Язык: Английский

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Ruthenium‐Based Electrocatalysts for Hydrogen Evolution Reaction: from Nanoparticles to Single Atoms

Small, Год журнала: 2024, Номер 20(45)

Опубликована: Июль 27, 2024

Abstract Benefiting from similar hydrogen bonding energy to Pt and much lower price compare with Pt, Ru based catalysts are promising candidates for electrocatalytic evolution reaction (HER). The catalytic activity of nanoparticles can be enhanced through improving their dispersion by using different supports, the strong metal supports interaction further regulate performance. In addition, single‐atom (SACs) almost 100% atomic utilization attract great attention coordinative atmosphere single atoms adjusted supports. Moreover, syngenetic effects improve performance catalysts. this review, progress HER electrocatalysts summarized according existing forms, including (NPs), (SAs) combination both NPs SAs. common such as carbon materials, oxides, phosphides sulfides classified clarify active centers. Especially, possible mechanisms reasons improved discussed experimental results theoretical calculations. Finally, some challenges opportunities prospected facilitate development HER.

Язык: Английский

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Hierarchically porous three-dimensional-ordered macro-microporous metal-organic frameworks: Design, precise synthesis, and applications

Coordination Chemistry Reviews, Год журнала: 2024, Номер 517, С. 215996 - 215996

Опубликована: Июнь 19, 2024

Язык: Английский

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Towards bridging thermo/electrocatalytic CO oxidation: from nanoparticles to single atoms

Chemical Society Reviews, Год журнала: 2024, Номер 53(17), С. 8903 - 8948

Опубликована: Янв. 1, 2024

Proton exchange membrane fuel cells (PEMFCs), as a feasible alternative to replace the traditional fossil fuel-based energy converter, contribute significantly global sustainability agenda. At PEMFC anode, given high current density, Pt/C is deemed catalyst-of-choice ensure that hydrogen oxidation reaction (HOR) occurs at sufficiently fast pace. The performance of Pt/C, however, can only be achieved under premise purity used. For instance, in presence trace level carbon monoxide, typical contaminant during H

Язык: Английский

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Graphene-MOF hybrids in high-tech energy devices—present and future advances

Hybrid Advances, Год журнала: 2024, Номер 5, С. 100150 - 100150

Опубликована: Фев. 4, 2024

Graphene has been employed in the methodological energy maneuvers due to remarkable structure and features, however use is limited nanosheet aggregation issues. Metal-organic framework also used for systems, nevertheless possess low conductivity stability issues towards application. This state-of-the-art review designed present essential aspects of graphene metal-organic (MOF) hybrids utilization modern devices systems. Amid storage devices, graphene-MOF have found functional lithium ion batteries, supercapacitors, fuel cells. Graphene-MOF searched surface area, structural, microstructural, physical features. For formation related techniques such as template, heating, solution, situ, hydrothermal, freeze-drying, chemical vapor deposition, facile methods used. Consequently, electron conduction, electrochemical charge/energy density, charge-discharge, reversible capacity, cyclic stability, specific capacitance, electrocatalytic activity, oxygen reduction reactions, other factors cells reported. these developed electrode electrolyte formation. Future progress on designing efficient three dimensional materials may overawe synthesis, conductivity, challenges high performance device materials.

Язык: Английский

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Composition regulation of transition metal electrocatalysts derived from zeolite imidazolate frameworks for Zn-air batteries

Energy storage materials, Год журнала: 2024, Номер 70, С. 103556 - 103556

Опубликована: Июнь 1, 2024

Язык: Английский

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Advanced development of dual-atom catalysts: From synthesis methods to versatile electrocatalytic applications

Journal of Power Sources, Год журнала: 2024, Номер 613, С. 234923 - 234923

Опубликована: Июнь 19, 2024

Язык: Английский

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Tandem synergetic effect in symbiotic Co catalyst for enhanced oxygen reduction

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159687 - 159687

Опубликована: Янв. 1, 2025

Язык: Английский

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Screened (Co, Rh, Ir)–N4 graphene single atom catalysts for hydrogen production via tunable surrounding coordination shell: Computation and machine learning

International Journal of Hydrogen Energy, Год журнала: 2025, Номер 106, С. 186 - 193

Опубликована: Фев. 2, 2025

Язык: Английский

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