Chiral Metal–Organic Frameworks

Chemical Reviews, Год журнала: 2022, Номер 122(9), С. 9078 - 9144

Опубликована: Март 28, 2022

In the past two decades, metal-organic frameworks (MOFs) or porous coordination polymers (PCPs) assembled from metal ions clusters and organic linkers via metal-ligand bonds have captivated significant scientific interest on account of their high crystallinity, exceptional porosity, tunable pore size, modularity, diverse functionality. The opportunity to achieve functional materials by design with promising properties, unattainable for solid-state in general, distinguishes MOFs other classes materials, particular, traditional such as activated carbon, silica, zeolites, thereby leading complementary properties. Scientists conducted intense research production chiral MOF (CMOF) specific applications including but not limited recognition, separation, catalysis since discovery first CMOF (i.e., d- l-POST-1). At present, CMOFs become interdisciplinary between chirality chemistry, material which involve many subjects physics, optics, medicine, pharmacology, biology, crystal engineering, environmental science, etc. this review, we will systematically summarize recent progress regarding strategies, synthetic approaches, cutting-edge applications. highlight successful implementation asymmetric catalysis, enantioselective sensing. We envision that review provide readers a good understanding chemistry and, more importantly, facilitate endeavors rational multifunctional industrial implementation.

Язык: Английский

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The Past and the Future of Langmuir and Langmuir–Blodgett Films

Chemical Reviews, Год журнала: 2022, Номер 122(6), С. 6459 - 6513

Опубликована: Фев. 3, 2022

The Langmuir–Blodgett (LB) technique, through which monolayers are transferred from the air/water interface onto a solid substrate, was first method to allow for controlled assembly of organic molecules. With its almost 100 year history, it has been inspiration most methods functionalize surfaces and produce nanocoatings, in addition serving explore concepts molecular electronics nanoarchitectonics. This paper provides an overview history Langmuir LB films, including potential use devices discussion on why films seldom considered practical applications today. Emphasis is then given two areas where these offer unique opportunities, namely, mimicking cell membrane models exploiting nanoarchitectonics sensors, investigate recognitions, assemble machines. promising topics short- long-term prospects technique also highlighted.

Язык: Английский

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Beyond Platonic: How to Build Metal–Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes

Chemical Reviews, Год журнала: 2022, Номер 122(11), С. 10393 - 10437

Опубликована: Апрель 18, 2022

The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much work this area focused on the formation hollow self-assembled metal-organic architectures and exploration applications their confined nanospaces. These discrete, soluble structures incorporate metal ions as 'glue' to link organic ligands together into polyhedra.Most employed thus far have been highly symmetrical, these easiest prepare. Such high-symmetry contain pseudospherical cavities, so typically bind roughly spherical guests. Biomolecules high-value synthetic compounds are rarely isotropic, highly-symmetrical species. To bind, sense, separate, transform such substrates, new, lower-symmetry, cages needed. Herein we summarize approaches, which taken form first draft a handbook for design higher-complexity, architectures.

Язык: Английский

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Material Evolution with Nanotechnology, Nanoarchitectonics, and Materials Informatics: What will be the Next Paradigm Shift in Nanoporous Materials?

Advanced Materials, Год журнала: 2021, Номер 34(7)

Опубликована: Окт. 13, 2021

Abstract Materials science and chemistry have played a central significant role in advancing society. With the shift toward sustainable living, it is anticipated that development of functional materials will continue to be vital for sustaining life on our planet. In recent decades, rapid progress has been made owing advances experimental, analytical, computational methods, thereby producing several novel useful materials. However, most problems material are highly complex. Here, best strategy via implementation three key concepts discussed: nanotechnology as game changer, nanoarchitectonics an integrator, informatics super‐accelerator. Discussions from conceptual viewpoints example developments, chiefly focused nanoporous materials, presented. It coupling these strategies together open advanced routes swift design exploratory search truly solving real‐world problems. These result evolution

Язык: Английский

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There is still plenty of room for layer-by-layer assembly for constructing nanoarchitectonics-based materials and devices

Physical Chemistry Chemical Physics, Год журнала: 2021, Номер 24(7), С. 4097 - 4115

Опубликована: Дек. 2, 2021

While the layer-by-layer (LbL) assembly method has already reached a certain maturity, there is still plenty of room for expanding its usefulness fabrication nanoarchitectonics-based materials and devices.

Язык: Английский

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Nanoarchitectonics: the method for everything in materials science

Bulletin of the Chemical Society of Japan, Год журнала: 2023, Номер 97(1)

Опубликована: Дек. 1, 2023

Abstract Nanotechnology has revealed the science of nanoscale. The global challenge that will follow is to build functional materials with knowledge nanoscale phenomena. This task carried out by nanoarchitectonics as a postnanotechnology concept. goal material systems architecting atoms, molecules, and nanomaterials building blocks. Fundamentally, all are made atoms molecules. Therefore, nanoarchitectonics, which architects from can be universal way create materials. It may said method for everything in science. From basic units, living cells, complex systems, components nanoarchitectonics. paper presents recent examples research at various size levels, atomic cellular level, specifically, (i) atomistic (ii) molecular (iii) supramolecular (iv) inorganic (v) biomolecular (vi) cell-mimic (vii) cell-based possibility science, an integrative then explored.

Язык: Английский

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Materials Nanoarchitectonics from Atom to Living Cell: A Method for Everything

Bulletin of the Chemical Society of Japan, Год журнала: 2022, Номер 95(5), С. 774 - 795

Опубликована: Март 22, 2022

Abstract Promoted understanding of nanostructures and their functions significantly rely on rapid progress nanotechnology within a few decades. It would be fruitful way to consider materials science through regulation nanostructure regulations the basis nanotechnological accomplishments. As post-nanotechnology concept, new concept nanoarchitectonics has recently emerged as methodology produce functional from nanoscale units. In this review article, we discuss recent advances related approaches atom-scales living cell sizes. The multiscale are exemplified discussed including atom molecules nanoarchitectonics, supramolecular at cell-scale. Next, supracell-level is organization designed surfaces, sheets layered three-dimensional biofilms bioinks, challenges for cells liquid interface. All formed with fundamental units, atoms, molecules, nanomaterials, therefore, basic units can hypothetically applied any kind material. Therefore, could method everything in an analogy theory physics.

Язык: Английский

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Transition Metal Phosphide Nanoarchitectonics for Versatile Organic Catalysis

Small, Год журнала: 2023, Номер 19(11)

Опубликована: Янв. 17, 2023

Abstract Transition metal phosphides (TMP) posses unique physiochemical, geometrical, and electronic properties, which can be exploited for different catalytic applications, such as photocatalysis, electrocatalysis, organic catalysis, etc. Among others, the use of TMP catalysis is less explored still facing many complex challenges, necessitate development sustainable reaction protocols demonstrating high selectivity yield desired molecules significance. In this regard, controlled synthesis TMP‐based catalysts thorough investigations underlying mechanisms provide deeper insights toward practical achievement applications. This review aims at providing a comprehensive analysis on recent advancements in synthetic strategies tailored tunable engineering structural, properties TMP. addition, their unprecedented potential transformation reactions succinctly summarized critically analyzed. Finally, rational perspective future opportunities challenges emerging field provided. On account achievements accomplished using TMP, it highly anticipated that combined with advanced innovative technologies methodologies pave way large scale realization catalysis.

Язык: Английский

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Pore-engineered nanoarchitectonics for cancer therapy

NPG Asia Materials, Год журнала: 2023, Номер 15(1)

Опубликована: Март 31, 2023

Abstract Nanoarchitectonics describes the integration of nanotechnology with other fields as a postnanotechnology concept that elevates it to material science. Based on this fundamental principle, we address pore-engineered nanoarchitectonics application targets for cancer therapy by combining basic descriptions and exemplifying applications in review. The initial two sections briefly summarize basics according classification based (i) porosity (ii) composition. Afterward, main application-oriented section—designing mesoporous therapy—is presented. Various types drug delivery systems, including nanoparticles nanocarriers, endogenous stimuli-responsive delivery, exogenous targeted are described. Importantly, clinical translation materials is further discussed. Mesoporous unique offer network cavities vehicles nanocarriers. Regarding developments allow be broadly used settings, there several challenges should solved their application. From perspective, tremendous processes development materials.

Язык: Английский

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Layer-by-layer designer nanoarchitectonics for physical and chemical communications in functional materials

Chemical Communications, Год журнала: 2024, Номер 60(16), С. 2152 - 2167

Опубликована: Янв. 1, 2024

In nanoarchitectonics approaches, rational physical and chemical communications will lead to the development of more advanced functional materials. Layer-by-layer assembly can be a powerful tool for this purpose, as exemplified in feature paper.

Язык: Английский

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