A Dynamic Multiple Reaction Monitoring Analytical Method for the Determination of Fungicide Residues in Drinking Water DOI Open Access

Aggelos Arvanitidis,

George S. Adamidis,

Paraskevas Parlakidis

и другие.

Environments, Год журнала: 2023, Номер 11(1), С. 5 - 5

Опубликована: Дек. 26, 2023

The extensive use of fungicides causes their continuous release into the environment through spraying, soil seepage, leaching, and runoff. It has been observed that residues can be found in foods a variety environmental compartments, such as wastewater, lakes, rivers, sediments, drinking water sources (groundwater surface water), treated water, water. A sensitive GC-MS/MS, using dynamic multiple reaction monitoring, an analytical method was developed to determine 10 (azoxystrobin, boscalid, captan, cyproconazole, cyprodinil, hexaconazole, metalaxyl, myclobutanil, paclobutrazol, prochloraz) solid-phase extraction for sample preparations validations performed according SANTE 2019 guidelines. All demonstrated mild or medium matrix effects (ME) ranging from 40.1% 11.2%. Their recoveries ranged between 60% 110%. limits detection were equal higher than 0.01 μg/L. employed on 18 samples collected public taps Northern Evros, Greece, distributed six sampling sites. Azoxystrobin, cypronidil, paclobutrazol mean concentrations did not surpass allowable limit 0.1 μg/L set by EU any site. Hexaconazole one site, while prochloraz concentration showed exceedances all Captan detected myclobutanil permissible four presence fungicide studied area is mainly due occasional point-sources pollution preferential flow. Additionally, risk pesticides human health assessed two different age groups. sum hazard quotient values each less unity. Consequently, acute assessment procedure regards examined safe. Nevertheless, carcinogenic safe suggested USEPA both groups, existence raises concerns about chronic toxicity.

Язык: Английский

Sustainable Crop Protection via Robotics and Artificial Intelligence Solutions DOI Creative Commons
Vasiliki Balaska,

Zoe Adamidou,

Zisis Vryzas

и другие.

Machines, Год журнала: 2023, Номер 11(8), С. 774 - 774

Опубликована: Июль 25, 2023

Agriculture 5.0 refers to the next phase of agricultural development, building upon previous digital revolution in agrarian sector and aiming transform industry be smarter, more effective, ecologically conscious. Farming processes have already started becoming efficient due development technologies, including big data, artificial intelligence (AI), robotics, Internet Things (IoT), virtual augmented reality. Farmers can make most resources at their disposal thanks this data-driven approach, allowing them effectively cultivate sustain crops on arable land. The European Union (EU) aims food systems fair, healthy, environmentally sustainable through Green Deal its farm-to-fork, soil, biodiversity strategies, zero pollution action plan, upcoming use pesticides regulation. Many historical synthetic are not currently registered EU market. In addition, continuous a limited number active ingredients with same mode scales up pests/pathogens/weed resistance potential. Increasing plant protection challenges as well having fewer chemical apply require innovation smart solutions for crop production. Biopesticides tend pose risks human health environment, efficacy depends various factors that cannot controlled traditional application strategies. This paper disclose contribution robotic ecosystems, highlighting both limitations technology. Specifically, work documents current threats agriculture (climate change, invasive pests, diseases, costs) how robotics AI act countermeasures deal such threats. Finally, specific case studies intelligent analyzed, architecture our decision system is proposed.

Язык: Английский

Процитировано

93

Phytoremediation: A green and low-cost technology to remediate herbicides in the environment DOI
Gabriela Madureira Barroso, Edson Aparecido dos Santos, Fábio Ribeiro Pires

и другие.

Chemosphere, Год журнала: 2023, Номер 334, С. 138943 - 138943

Опубликована: Май 16, 2023

Язык: Английский

Процитировано

24

Aquatic Macrophytes in the Remediation of Atrazine in Water: A Study on Herbicide Tolerance and Degradation Using Eichhornia crassipes, Pistia stratiotes, and Salvinia minima DOI Creative Commons
María Carolina Ramírez Hernández, Jesley Nogueira Bandeira, María Gladis Rosero Alpala

и другие.

ACS Omega, Год журнала: 2025, Номер unknown

Опубликована: Март 15, 2025

Aquatic macrophytes can be used for herbicide remediation provided they exhibit tolerance to the contaminants. This research assessed potential of Salvinia minima, Echhornia crassipes, and Pistia stratiotes, some common aquatic native Brazil, their atrazine, an commonly detected in waterbodies. Plants were cultivated under controlled conditions with five atrazine concentrations (0, 2, 20, 200, 1000 μg L-1) 15 days. S. minima E. crassipes tolerated equal or less than 20 L-1 died at 200 L-1, indicating herbicide's toxicity its selectivity against sensitive species. P. stratiotes concentration up had growth reduced L-1. All species demonstrated ability reduce water lower, being most efficient, reducing by 43% 22% 2 respectively. Atrazine levels within Brazilian (2 CONAMA 2005) European (0.1 Directive 2013/33) regulatory limits do not selectively affect these Thus, show use arazine phytoremediation programs.

Язык: Английский

Процитировано

0

Dissipation Kinetics and Dietary Risk Assessment of Boscalid Residues in Two Table-Grape Varieties Under Field Conditions DOI Open Access

Paraskevas Parlakidis,

George S. Adamidis,

Theodoros Doulaveris

и другие.

Environments, Год журнала: 2025, Номер 12(5), С. 133 - 133

Опубликована: Апрель 22, 2025

Grape cultivation is crucial due to its significant dietary benefits and the production of various byproducts. Fungicides, like boscalid, are frequently applied protect grape crops from several disease, ensuring both yield quality. However, excessive or inappropriate application boscalid may pose health risks humans. Therefore, objectives this field study were (a) assess pre-harvest interval (PHI) dissipation in two table-grape varieties (Soultanina Crimson) under conditions (b) evaluate potential associated with consumption for adults children. The residue grapes was determined using a modified QuEChERS method coupled high-performance liquid chromatography diode array detector (HPLC–DAD). followed first- second-order kinetics, half-lives ranging 3.32 6.42 days PHIs 8.11 10.90 days. risk assessment indicated that early mid-post period could age groups, children facing three times adults.

Язык: Английский

Процитировано

0

Assessment of atrazine contamination in the Sele River estuary: spatial distribution, human health risks, and ecological implications in Southern Europe DOI Creative Commons

Elvira De Rosa,

Paolo Montuori, Fabiana Di Duca

и другие.

Environmental Sciences Europe, Год журнала: 2024, Номер 36(1)

Опубликована: Июнь 15, 2024

Abstract Background Overuse of pesticides is a major worldwide problem for the environment and human health. Atrazine (ATR) synthetic triazine herbicide that typically used to manage crops although it was banned many years ago, detected frequently with high persistence in aquatic environments. This study assesses health risks, temporal patterns spatial distribution ATR its degradation products (DPs) Sele River estuary within Southern European context.. It specifically investigates their occurrence water dissolved phase (WDP), suspended particulate matter (SPM), sediment. Results Sampling conducted across 10 sites throughout year’s four seasons. Amounts DPs ranged from 20.1 96.5 ng L −1 WDP, 5.4 60.2 SPM, 4.7 19.8 g sediment samples, signifying some pollution levels. Spatial mechanisms revealed southward movement mouth, intensifying during rainy season. In this area, risk evaluation also carried out. No sample contained or concentrations above recommended limits, which pose Non-carcinogenic Carcinogenic risk. The environmental low. Additionally, determined Incremental lifetime cancer (ILCR) value allowable range. Conclusion Despite long-standing prohibition, investigate levels sediments Europe. Beyond simply delineating status River, research delineates ecological repercussions on Thyrrenian Sea, providing essential data norms laws related contamination. Graphical

Язык: Английский

Процитировано

3

Occurrence and Risk Assessment of Atrazine and Diuron in Well and Surface Water of a Cornfield Rural Region DOI Open Access

Brenda Lagunas-Basave,

Alhelí Brito-Hernández,

Hugo Saldarriaga-Noreña

и другие.

Water, Год журнала: 2022, Номер 14(22), С. 3790 - 3790

Опубликована: Ноя. 21, 2022

Herbicides have contributed to increased agricultural production. However, their residual amount can cause negative effects on environmental and public health. Therefore, this work aimed determine the occurrence of both atrazine diuron in surface well water investigate link with drinking use. The samples were collected during dry rainy seasons three wells from a river pond located low plains Ixcatepec catchment, at Amacuáhuitl community municipality Arcelia, Guerrero State, center south México, which is rural where farming main activity. compounds obtained by solid phase extraction determined HPLC-MS quadrupole positive electrospray ionization mode. A geomorphic analysis was conducted inside catchment using digital elevation model Shuttle Radar Topography Mission, SRTM-v4. human risk for calculated according Hazard Quotient. concentrations between 5.77 402 ng L−1. Atrazine most abundant frequent pesticide found an average concentration 105.18 L−1, while that 86.56 highest levels Ushe, likely being result lowest flow stagnation water, cold-dry season consequence mobilization irrigation runoff. morphological indicated mainly reached body lower surfaces cultivated areas. linked agriculture activity within community. chemical properties compounds, crop irrigation, conditions could be contributing dispersion amounts herbicides hydrological system. estimation showed generate health problems children Azul as source water.

Язык: Английский

Процитировано

13

Effects of atrazine and S-metolachlor on stream periphyton taxonomic and fatty acid compositions DOI
Laura Malbezin, Soizic Morin, Isabelle Lavoie

и другие.

Ecotoxicology, Год журнала: 2024, Номер 33(2), С. 190 - 204

Опубликована: Фев. 22, 2024

Язык: Английский

Процитировано

2

Unraveling the effects of acrylonitrile butadiene styrene (ABS) microplastic ageing on the sorption and toxicity of ionic liquids with 2,4-D and glyphosate herbicides DOI Creative Commons
Natalia Lisiecka, Anna Parus, Maria Simpson

и другие.

Chemosphere, Год журнала: 2024, Номер 364, С. 143271 - 143271

Опубликована: Сен. 1, 2024

Язык: Английский

Процитировано

2

Classifying micropollutants by environmental risk in groundwater using screening analysis associated to a hybrid multicriteria method combining (Q)SAR tools, fuzzy AHP and ELECTRE DOI
Raquel Wielens Becker,

Débora Salmoria Araújo,

Letícia Alves Jachstet

и другие.

The Science of The Total Environment, Год журнала: 2023, Номер 892, С. 164588 - 164588

Опубликована: Июнь 2, 2023

Язык: Английский

Процитировано

5

Dissipation Kinetics, Leaching, and Ecological Risk Assessment of S-Metolachlor and Benfluralin Residues in Soil DOI Open Access

Paraskevas Parlakidis,

George S. Adamidis, Georgios D. Gikas

и другие.

Environments, Год журнала: 2024, Номер 11(1), С. 18 - 18

Опубликована: Янв. 18, 2024

The use of selective herbicides is one the best methods for weed management. However, extensive can have adverse impacts on non-target organisms. goals this study were to assess dissipation kinetics, leaching, and ecological risk assessment S-metolachlor benfluralin residues in silty loam soil planted with chickpea (Cicer arietinum L.). experimental setup included four different layers replications corresponding an randomized complete block design consisting 16 plots. application doses 1350 1920 g a.i./ha, respectively, according manufacturer recommendations. Soil samples split into depths, 0 20 cm (Layer A), 40 B), 60 C), 80 D), determine kinetics leaching behavior herbicides. Gas chromatography coupled electron capture detector (GC-ECD) method was developed validated determination soil. analytes extracted from distilled water ethyl acetate followed by solid-phase extraction (SPE). limit quantification (LOQ) 0.1 μg/g, recoveries ranges 81% 97% 88% 101%, relative standard deviations (RSD) less than 9.7%. (0–20 cm) first-order half-lives 21.66 30.13 days, respectively. results obtained 20–80 profile showed that both presented high following preferential flow. Also, a conducted top 0–20 profile, estimating toxicity–exposure ratio (TER) organisms quotient (RQ). mean herbicide levels found at studied days (2 h) experiment used assessment. In first case, pesticide concentration (MPC) gives worst-case scenario (ws); second (ds) given using respective MPC. all cases, TER RQ values corresponds higher

Язык: Английский

Процитировано

1