AAPS PharmSciTech, Год журнала: 2024, Номер 26(1)
Опубликована: Дек. 19, 2024
Язык: Английский
AAPS PharmSciTech, Год журнала: 2024, Номер 26(1)
Опубликована: Дек. 19, 2024
Язык: Английский
Microchemical Journal, Год журнала: 2024, Номер 204, С. 111056 - 111056
Опубликована: Июнь 24, 2024
Язык: Английский
Процитировано
6The Journal of Physical Chemistry C, Год журнала: 2024, Номер 129(1), С. 732 - 743
Опубликована: Дек. 19, 2024
Surface-anchored metal–organic frameworks (surMOFs) are crystalline, nanoporous, supramolecular materials mounted to substrates that have the potential for integration within device architectures relevant a variety of electronic, photonic, sensing, and gas storage applications. This research investigates thin film formation Cu-BDC (copper benzene-1,4-dicarboxylate) MOF system on carboxylic acid-terminated self-assembled monolayer by alternating deposition solution-phase inorganic organic precursors. X-ray diffraction (XRD) atomic force microscopy (AFM) characterization demonstrate crystalline films formed via Volmer–Weber growth. Changes in morphology as temperature increases seen AFM with more isolated nanorod-like crystallites observed at lower temperatures, while vertical nanoplatelet-like structures form higher temperatures. At 45 °C, nanoplatelets be composed fused nanorod segments aligned one direction. Ellipsometry confirms both increasing number cycles yield agreement infrared reflectance–absorbance spectroscopy (IRRAS) was further used characterize chemical binding orientation surface-bound nanostructures. In addition observing strong preferred nanostructures from enhancement symmetric carboxylate stretch absence antisymmetric stretch, IRRAS results show emergence new motif associated segmented nanoplatelet well high surface coverage after 12 cycles. From appearance this frequency peak alongside splitting BDC deformation modes, data support presence strained configuration accompanies AFM.
Язык: Английский
Процитировано
1Nanomaterials, Год журнала: 2024, Номер 14(23), С. 1902 - 1902
Опубликована: Ноя. 27, 2024
Not only are solutions to energy and environmental issues essential in long-term planning for the Earth’s ecological balance sustainable economic development, they also represent an urgent issue posing a direct threat human health [...]
Язык: Английский
Процитировано
0AAPS PharmSciTech, Год журнала: 2024, Номер 26(1)
Опубликована: Дек. 19, 2024
Язык: Английский
Процитировано
0