AAPS PharmSciTech, Journal Year: 2024, Volume and Issue: 26(1)
Published: Dec. 19, 2024
Language: Английский
AAPS PharmSciTech, Journal Year: 2024, Volume and Issue: 26(1)
Published: Dec. 19, 2024
Language: Английский
Microchemical Journal, Journal Year: 2024, Volume and Issue: 204, P. 111056 - 111056
Published: June 24, 2024
Language: Английский
Citations
6The Journal of Physical Chemistry C, Journal Year: 2024, Volume and Issue: 129(1), P. 732 - 743
Published: Dec. 19, 2024
Surface-anchored metal–organic frameworks (surMOFs) are crystalline, nanoporous, supramolecular materials mounted to substrates that have the potential for integration within device architectures relevant a variety of electronic, photonic, sensing, and gas storage applications. This research investigates thin film formation Cu-BDC (copper benzene-1,4-dicarboxylate) MOF system on carboxylic acid-terminated self-assembled monolayer by alternating deposition solution-phase inorganic organic precursors. X-ray diffraction (XRD) atomic force microscopy (AFM) characterization demonstrate crystalline films formed via Volmer–Weber growth. Changes in morphology as temperature increases seen AFM with more isolated nanorod-like crystallites observed at lower temperatures, while vertical nanoplatelet-like structures form higher temperatures. At 45 °C, nanoplatelets be composed fused nanorod segments aligned one direction. Ellipsometry confirms both increasing number cycles yield agreement infrared reflectance–absorbance spectroscopy (IRRAS) was further used characterize chemical binding orientation surface-bound nanostructures. In addition observing strong preferred nanostructures from enhancement symmetric carboxylate stretch absence antisymmetric stretch, IRRAS results show emergence new motif associated segmented nanoplatelet well high surface coverage after 12 cycles. From appearance this frequency peak alongside splitting BDC deformation modes, data support presence strained configuration accompanies AFM.
Language: Английский
Citations
1Nanomaterials, Journal Year: 2024, Volume and Issue: 14(23), P. 1902 - 1902
Published: Nov. 27, 2024
Not only are solutions to energy and environmental issues essential in long-term planning for the Earth’s ecological balance sustainable economic development, they also represent an urgent issue posing a direct threat human health [...]
Language: Английский
Citations
0AAPS PharmSciTech, Journal Year: 2024, Volume and Issue: 26(1)
Published: Dec. 19, 2024
Language: Английский
Citations
0