Enhanced photocatalytic degradation of acetaminophen over photo-assisted dual cocatalysts loading and heterojunction formation on PbBiO2Br

Journal of Alloys and Compounds, Год журнала: 2025, Номер unknown, С. 179917 - 179917

Опубликована: Март 1, 2025

Язык: Английский

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Synthesis and Characterization of a Novel Sol–Gel-Derived Ni-Doped TiO2 Photocatalyst for Rapid Visible Light-Driven Mineralization of Paracetamol

Nanomaterials, Год журнала: 2025, Номер 15(7), С. 530 - 530

Опубликована: Март 31, 2025

The increasing presence of pharmaceutical contaminants, such as paracetamol, in water sources necessitates the development efficient and sustainable treatment technologies. This study investigates photocatalytic degradation mineralization paracetamol under visible light using nickel-doped titanium dioxide (Ni–TiO2) catalysts synthesized via sol-gel method. were characterized through Raman spectroscopy, UV–Vis diffuse reflectance spectroscopy (UV–Vis DRS), surface area measurements. Ni doping enhanced absorption TiO2, reducing its band gap from 3.11 eV (undoped) to 2.49 at 0.20 wt.% loading, while analysis confirmed incorporation with anatase predominant phase. Ni(0.1%)-TiO2 catalyst exhibited highest activity, achieving 88% total organic carbon (TOC) removal (5 ppm) after 180 min optimal conditions (catalyst dosage, 3 g L−1). Stability tests demonstrated 84% retained efficiency over five cycles, a kinetic rate constant 0.010 min−1. Hydroxyl radicals identified main reactive species. maintained high performance tap water, 78.8% TOC removal. These findings highlight potential cost-effective, light-active photocatalyst for pollutants, promising scalability industrial applications.

Язык: Английский

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Novel Sesbania wood-based activated carbon for paracetamol removal: integrating batch adsorption, fixed-bed studies, and machine learning

Biomass Conversion and Biorefinery, Год журнала: 2025, Номер unknown

Опубликована: Апрель 18, 2025

Язык: Английский

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Photocatalytic Degradation of Acetaminophen by g-C3N4/CQD/Ag Nanocomposites from Aqueous Media

Journal of Composites Science, Год журнала: 2025, Номер 9(5), С. 197 - 197

Опубликована: Апрель 22, 2025

Ternary g-C3N4/CQD/Ag photocatalysts were synthesized via deposition of carbon quantum dots (CQDs) and silver nanoparticles (Ag) onto graphitic nitride (g-C3N4) for efficient acetaminophen degradation. The nanocomposites exhibited enhanced photoresponse broad-spectrum photocatalytic activity under both UV (254 nm, 250 W) Xenon (>420 500 irradiation. Characterization by XRD, FTIR, SEM, PL, EDX elucidated the material’s composition, structure, morphology, optical properties. Optimized degradation (50 mg/L) was achieved at pH 7 with 0.6 g/L catalyst loading 60 min irradiation, yielding efficiencies 87.5% (UV) 85.3% (Xenon). Radical quenching experiments GC-MS analysis identified hydroxyl radicals as primary reactive species revealed a gradual decrease in intermediate toxicity during mineralization. This study demonstrates superior performance ternary compared to binary systems effective removal.

Язык: Английский

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Simulation and experimentation of iron-doped liquid metal-based gallium oxide photocatalysts for environmental applications harnessing solar energy

Environmental Science and Pollution Research, Год журнала: 2025, Номер unknown

Опубликована: Май 8, 2025

Язык: Английский

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Designing ultrathin single and multilayered Ti3C2TX MXene as photocatalysts for enhanced acetaminophen degradation in Photo-Fenton-like reactions

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 163691 - 163691

Опубликована: Май 1, 2025

Язык: Английский

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Synthesis of porphyrin comprising pyridinium ionic liquid with sulfonic acid moiety for photo-degradation of paracetamol in simulated wastewater

Journal of Water Process Engineering, Год журнала: 2025, Номер 75, С. 108056 - 108056

Опубликована: Июнь 1, 2025

Язык: Английский

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Exploring the photocatalytic efficacy of carbonaceous materials in drug degradation: a contemporary review

Chemical Papers, Год журнала: 2024, Номер 78(9), С. 5169 - 5190

Опубликована: Апрель 17, 2024

Язык: Английский

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Activation of sodium percarbonate by cysteine complexation of Fe(ii) for the degradation of acetaminophen in water

New Journal of Chemistry, Год журнала: 2024, Номер 48(15), С. 6745 - 6757

Опубликована: Янв. 1, 2024

To overcome the limitations of Fe( ii )-activated percarbonate process for ACT removal, this study introduced cysteine as a complexing agent into )/SPC system and enhanced degradation efficiency ACT.

Язык: Английский

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Single atom photocatalytic micropollutants degradation performance: A review

Desalination and Water Treatment, Год журнала: 2024, Номер 320, С. 100656 - 100656

Опубликована: Июль 30, 2024

A single-atom catalyst is a supported material in which the active phase presented as isolated atoms. Single atom photocatalytic degradation of micropollutants has garnered significant attention recent research. However, updated their performance still limited. This review paper presents key aspects related to use SACs micropollutant degradation: The influencing factors like structure, surface area, density, relative humidity, temperature airflow, light intensity and reactants concentrations are also discussed. Further synthesis methods including atomic deposition, ball milling, trapping, pyrolysis, two steps doping, wet impregnation, facile electrostatic adoption updated. Characterization techniques STEM, TEM, FTIR, XAS, XRD, XPS, DFT evaluated relation quality with an emphasis on performances destruction well applications. catalysts endowed uniform, definite metal centers tunable matching options, give them excellent vigor special selectivity for defined In addition, mechanism harvesting, charge transfer separation, applications single micropollutants, photocatalysts support combinations other materials technologies challenges stability recyclability, loading, nature carrier, structure future perspective Finally highlighted conclusion remarks keynote areas.

Язык: Английский

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