Lignin Derivative as Visible‐Light Photo‐Initiating System for the Development of Biocide Materials under Light Irradiation DOI Open Access
Christine Elian,

Fares Mouhoubi,

Régis Moilleron

и другие.

Macromolecular Rapid Communications, Год журнала: 2024, Номер unknown

Опубликована: Дек. 20, 2024

The design of a new visible-light methacrylated-based kraft lignin photosensitizer (MAcL) iodonium salt (Iod) for the free-radical polymerization (FRP) polyethylene glycol dimethacrylate (PEGDMA) under LEDs@405, 455, 470, 505, and 530 nm is reported. As demonstrated by laser flash photolysis (LFP) electron paramagnetic resonance spin-trapping (EPR ST) experiments, combination MAcL with an acceptor trimethylolpropane tris(3-mercaptopropionate) (TT) used as crosslinker, leads to formation highly efficient initiating radicals, i.e., thyil carbon-centred promoting thus FRP PEGDMA. final methacrylate conversions PEGDMA are very high range from 80 95% LED@530 LED@405 nm, respectively. For first time, also biocide agent it produces singlet oxygen when exposed visible light. resulting photoinduced bio-based materials incorporating demonstrate tremendous antibacterial properties against Staphylococcus aureus (S. aureus), inducing 100% bacterial death.

Язык: Английский

Polymer-based antimicrobial strategies for periodontitis DOI Creative Commons
Jiajia Chen, Shujun Dong

Frontiers in Pharmacology, Год журнала: 2025, Номер 15

Опубликована: Янв. 6, 2025

Periodontitis is a chronic inflammatory condition driven by plaque-associated microorganisms, where uncontrolled bacterial invasion and proliferation impair host immune responses, leading to localized periodontal tissue inflammation bone destruction. Conventional therapies face challenges, including incomplete microbial clearance the rise of antibiotic resistance, limiting their precision effectiveness in managing periodontitis. Recently, nanotherapies based on polymeric materials have introduced advanced approaches antimicrobial therapy through diverse mechanisms. This review explored specific mechanisms, emphasizing design polymer-based agents that employ individual or synergistic actions, evaluated innovations limitations current strategies while forecasting future trends development for

Язык: Английский

Процитировано

0

Reprogram Local Electronic Configuration in Multicomponent Covalent–Organic Frameworks for Efficient Hydrogen Peroxide Photoproduction DOI
Zhongwei Ding, Jiani Yang, Zihe Wu

и другие.

Chemistry of Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 19, 2025

Covalent organic frameworks (COFs) have recently demonstrated significant potential for photocatalysis. Optimizing the local electronic environment in COFs has been considered to be critical enhancing photocatalytic activity. Here, we report a one-pot "grafting-to" strategy reprogram configurations of series isoreticular multicomponent by introducing electron-donating or electron-withdrawing groups into pores transform photoinert photoactive and form intramolecular donor–acceptor (D-A) structures. Such D-A structures enhanced overall hydrogen peroxide photoproduction facilitating charge carrier separation optimizing band achieve oxygen reduction reaction water oxidation simultaneously. Notably, one incorporated with 2-aminothiazole exhibits production rate 3701 μmol g–1 h–1 solar-to-chemical conversion efficiency 0.13% without use any sacrificial reagents, it 100% bacterial killing rates remarkable >90% biofilm removal capability. This COF modification strategy, which not reported before, offers unique approach constructing highly active photocatalysts containing great future design antibacterial therapies.

Язык: Английский

Процитировано

0

Terpenes, natural dyes and photochemistry: toward the synthesis of photoactive bio-based materials with biocide properties DOI Creative Commons

Louise Breloy,

Christine Elian,

Vanessa Alphonse

и другие.

RSC Applied Polymers, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 25, 2024

The thiol–ene photochemistry process, combined with terpenes and natural dyes, yields innovative photostimulable bio-based materials antibacterial properties.

Язык: Английский

Процитировано

2

Biomaterials-based phototherapy for bacterial infections DOI Creative Commons

Guangzhi Wu,

Zhuo Xu, Yue Yu

и другие.

Frontiers in Pharmacology, Год журнала: 2024, Номер 15

Опубликована: Дек. 4, 2024

Bacterial infections and antibiotic resistance are global health problems, current treatments for bacterial still rely on the use of antibiotics. Phototherapy based a photosensitizer has high efficiency, broad spectrum, strong selectivity, does not easily induce drug resistance, is expected to become an effective strategy treatment infections, particularly drug-resistant infections. This article reviews antimicrobial strategies phototherapy photosensitizers, including photodynamic therapy (PDT), photothermal (PTT), their combination. These methods have significant application potential in combating multi-drug-resistant biofilm providing alternative traditional antibiotics chemical antibacterial agents.

Язык: Английский

Процитировано

2

Hybrid Hydrogels of Polyacrylamide and Self-assembly Photodynamic Nanoparticles with Diverse Adhesion for Infected Chronic Wound Healing DOI
Tao Kang, Zhaoyuan Guo, Lu Yao

и другие.

Biomacromolecules, Год журнала: 2024, Номер unknown

Опубликована: Окт. 20, 2024

The healing of infected wounds is challenging for patients. In this paper, a hybrid hydrogel with strong tissue adhesion, self-healing, and antibiosis without antibiotics was developed as dressing to promote the chronic wounds. Acrylamide (PAM) polymerized

Язык: Английский

Процитировано

0

Lignin Derivative as Visible‐Light Photo‐Initiating System for the Development of Biocide Materials under Light Irradiation DOI Open Access
Christine Elian,

Fares Mouhoubi,

Régis Moilleron

и другие.

Macromolecular Rapid Communications, Год журнала: 2024, Номер unknown

Опубликована: Дек. 20, 2024

The design of a new visible-light methacrylated-based kraft lignin photosensitizer (MAcL) iodonium salt (Iod) for the free-radical polymerization (FRP) polyethylene glycol dimethacrylate (PEGDMA) under LEDs@405, 455, 470, 505, and 530 nm is reported. As demonstrated by laser flash photolysis (LFP) electron paramagnetic resonance spin-trapping (EPR ST) experiments, combination MAcL with an acceptor trimethylolpropane tris(3-mercaptopropionate) (TT) used as crosslinker, leads to formation highly efficient initiating radicals, i.e., thyil carbon-centred promoting thus FRP PEGDMA. final methacrylate conversions PEGDMA are very high range from 80 95% LED@530 LED@405 nm, respectively. For first time, also biocide agent it produces singlet oxygen when exposed visible light. resulting photoinduced bio-based materials incorporating demonstrate tremendous antibacterial properties against Staphylococcus aureus (S. aureus), inducing 100% bacterial death.

Язык: Английский

Процитировано

0