Materials Today Communications, Год журнала: 2025, Номер unknown, С. 112164 - 112164
Опубликована: Март 1, 2025
Язык: Английский
Chemical Society Reviews, Год журнала: 2023, Номер 53(1), С. 137 - 162
Опубликована: Ноя. 29, 2023
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential life transformations. Nevertheless, enzymes only operate under mild conditions to keep sophisticated structures active, limiting their potential applications. Artificial that recapitulate the catalytic of can not circumvent enzymatic fragility but also bring versatile functions into practice. Among them, metal-organic frameworks (MOFs) featuring diverse site-isolated metal sites supramolecular have emerged as promising candidates for move toward unparalleled properties behaviour enzymes. In this review, we systematically summarize significant advances in MOF-based metalloenzyme mimics a special emphasis on active pocket engineering at atomic level, including primary secondary coordination spheres. Then, deep understanding mechanisms advanced applications are discussed. Finally, perspective emerging frontier research is provided advance bioinspired catalysis.
Язык: Английский
Процитировано
61
TrAC Trends in Analytical Chemistry, Год журнала: 2024, Номер 173, С. 117602 - 117602
Опубликована: Фев. 23, 2024
Язык: Английский
Процитировано
27
Advanced Healthcare Materials, Год журнала: 2024, Номер unknown
Опубликована: Авг. 13, 2024
Abstract As nanoscale materials with the function of catalyzing substrates through enzymatic kinetics, nanozymes are regarded as potential alternatives to natural enzymes. Compared protein‐based enzymes, exhibit attractive characteristics low preparation cost, robust activity, flexible performance adjustment, and versatile functionalization. These advantages endow them wide use from biochemical sensing environmental remediation medical theranostics. Especially in biomedical diagnosis, feature catalytic signal amplification provided by makes emerging labels for detection biomarkers diseases, rapid developments observed recent years. To provide a comprehensive overview progress made this dynamic field, here an diagnosis enabled is provided. This review first summarizes synthesis nanozyme then discusses main strategies applied enhance their activity specificity. Subsequently, representative utilization combined biological elements disease reviewed, including related metabolic, cardiovascular, nervous, digestive diseases well cancers. Finally, some development trends nanozyme‐enabled highlighted, corresponding challenges also pointed out, aiming inspire future efforts further advance promising field.
Язык: Английский
Процитировано
23
TrAC Trends in Analytical Chemistry, Год журнала: 2024, Номер 178, С. 117862 - 117862
Опубликована: Июль 10, 2024
Язык: Английский
Процитировано
21
Chemical Society Reviews, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
The latest advancements in MOF-based three-dimensional macrostructures, encompassing fascinating characteristics, preparation strategies, characterization methods, and environmental applications, are examined.
Язык: Английский
Процитировано
5
Separation and Purification Technology, Год журнала: 2023, Номер 333, С. 125957 - 125957
Опубликована: Дек. 6, 2023
Язык: Английский
Процитировано
32
Nature Communications, Год журнала: 2024, Номер 15(1)
Опубликована: Июнь 21, 2024
Abstract Cellulose fiber-based textiles are ubiquitous in daily life for their processability, biodegradability, and outstanding flexibility. Integrating cellulose with functional coating materials can unlock potential functionalities to engage diverse applications. Metal-organic frameworks (MOFs) ideal candidate such integration, thanks unique merits, as large specific surface area, tunable pore size, species diversity. However, achieving scalable fabrication of MOFs-textiles high mechanical durability remains challenging. Here, we report a facile strategy direct MOF growth on cotton fibers grafted via the diazonium chemistry. The as-prepared ZIF-67-Cotton textile (ZIF-67-CT) exhibits excellent ultraviolet (UV) resistance organic contamination degradation peroxymonosulfate activation. ZIF-67-CT is also used encapsulate essential oils carvacrol enable antibacterial activity against E. coli S. aureus . Additionally, by directly tethering hydrophobic molecular layer onto MOF-coated surface, superhydrophobic achieved self-cleaning, antifouling, oil-water separation performances. More importantly, reported generic applicable other MOFs materials, various large-scale multi-functional be successfully manufactured, resulting vast applications wastewater purification, fragrance industry, outdoor gears.
Язык: Английский
Процитировано
17
Advanced Nanocomposites, Год журнала: 2024, Номер 2, С. 1 - 14
Опубликована: Ноя. 5, 2024
Язык: Английский
Процитировано
14
ACS Applied Materials & Interfaces, Год журнала: 2024, Номер unknown
Опубликована: Дек. 30, 2024
Metal–organic frameworks (MOFs) have emerged as innovative nanozyme mimics, particularly in the area of oxidase catalysis, outperforming traditional MOF-based peroxidase and other nanomaterial-based systems. This review explores various advantages that MOFs offer terms catalytic activity, low-cost, stability, structural versatility. With a primary focus on their application biochemical sensing, oxidases demonstrated remarkable utility, prompting thorough exploration design modification strategies. Moreover, aims to provide comprehensive analysis strategies employed rational MOF structures optimize key parameters such sensitivity, selectivity, stability context sensors. Through an exhaustive examination recent research developments, this article seeks insights into nuanced interplay between performance, shedding light mechanisms underpin effectiveness mimics. Finally, addresses challenges opportunities associated with aiming drive further advancements structure development highly effective sensors for diverse applications.
Язык: Английский
Процитировано
14
Advanced Science, Год журнала: 2024, Номер unknown
Опубликована: Окт. 28, 2024
Abstract Metal–organic frameworks (MOFs) and covalent–organic (COFs)‐based aerogels are garnering significant attention owing to their unique chemical structural properties. These materials harmoniously combine the advantages of MOFs COFs—such as high surface area, customizable porosity, varied functionality—with lightweight structured porosity characteristic aerogels. This combination opens up new avenues for advanced applications in fields where material efficiency enhanced functionality critical. review provides a comparative overview synthetic strategies utilized produce pristine MOF/COF well MOF/COF‐based hybrid aerogels, which functionalized with molecular precursors nanoscale materials. The versatility these positions them promising candidates addressing complex challenges environmental remediation, energy storage conversion, sustainable water‐energy technologies, separations. Furthermore, this study discusses current future prospects related synthesis techniques
Язык: Английский
Процитировано
11