Metalated covalent organic frameworks: from synthetic strategies to diverse applications DOI
Qun Guan, Lele Zhou, Yu‐Bin Dong

и другие.

Chemical Society Reviews, Год журнала: 2022, Номер 51(15), С. 6307 - 6416

Опубликована: Янв. 1, 2022

This review highlights the recent advances of metalated covalent organic frameworks, including synthetic strategies and applications, discusses current challenges future directions.

Язык: Английский

Covalent Organic Frameworks: Design, Synthesis, and Functions DOI
Keyu Geng, Ting He, Ruoyang Liu

и другие.

Chemical Reviews, Год журнала: 2020, Номер 120(16), С. 8814 - 8933

Опубликована: Янв. 22, 2020

Covalent organic frameworks (COFs) are a class of crystalline porous polymers with permanent porosity and highly ordered structures. Unlike other polymers, significant feature COFs is that they structurally predesignable, synthetically controllable, functionally manageable. In principle, the topological design diagram offers geometric guidance for structural tiling extended polygons, polycondensation reactions provide synthetic ways to construct predesigned primary high-order Progress over past decade in chemistry these two aspects undoubtedly established base COF field. By virtue availability units diversity topologies linkages, have emerged as new field materials offer powerful molecular platform complex tailor-made functional development. Here we target comprehensive review field, historic overview survey advances topology reactions, illustrate features diversities, scrutinize development potential various functions through elucidating structure–function correlations based on interactions photons, electrons, holes, spins, ions, molecules, discuss key fundamental challenging issues need be addressed, predict future directions from chemistry, physics, perspectives.

Язык: Английский

Процитировано

2891

Covalent organic frameworks for separation applications DOI
Zhifang Wang,

Sainan Zhang,

Yao Chen

и другие.

Chemical Society Reviews, Год журнала: 2020, Номер 49(3), С. 708 - 735

Опубликована: Янв. 1, 2020

This review article comprehensively summarizes the recent progress in development of covalent organic framework materials for separation applications.

Язык: Английский

Процитировано

1143

Bulk COFs and COF nanosheets for electrochemical energy storage and conversion DOI
Jie Li,

Xuechun Jing,

Qingqing Li

и другие.

Chemical Society Reviews, Год журнала: 2020, Номер 49(11), С. 3565 - 3604

Опубликована: Янв. 1, 2020

The current advances, structure-property relationship and future perspectives in covalent organic frameworks (COFs) their nanosheets for electrochemical energy storage (EES) conversion (EEC) are summarized.

Язык: Английский

Процитировано

881

Design and applications of three dimensional covalent organic frameworks DOI
Xinyu Guan, Fengqian Chen, Qianrong Fang

и другие.

Chemical Society Reviews, Год журнала: 2020, Номер 49(5), С. 1357 - 1384

Опубликована: Янв. 1, 2020

We summarize in this review the current state-of-the-art development of three dimensional covalent organic frameworks.

Язык: Английский

Процитировано

721

Post-synthetic modification of covalent organic frameworks DOI
José L. Segura, Sergio Royuela, Mar Ramos

и другие.

Chemical Society Reviews, Год журнала: 2019, Номер 48(14), С. 3903 - 3945

Опубликована: Янв. 1, 2019

This review is aimed at providing an in-depth understanding of the potential post-synthetic strategies for modification covalent organic frameworks.

Язык: Английский

Процитировано

624

Covalent organic frameworks (COFs) for environmental applications DOI
Jianlong Wang, Shuting Zhuang

Coordination Chemistry Reviews, Год журнала: 2019, Номер 400, С. 213046 - 213046

Опубликована: Сен. 11, 2019

Язык: Английский

Процитировано

534

Opportunities of Covalent Organic Frameworks for Advanced Applications DOI Creative Commons
Yanpei Song, Qi Sun, Briana Aguila

и другие.

Advanced Science, Год журнала: 2018, Номер 6(2)

Опубликована: Ноя. 12, 2018

Abstract Covalent organic frameworks (COFs) are an emerging class of functional nanostructures with intriguing properties, due to their unprecedented combination high crystallinity, tunable pore size, large surface area, and unique molecular architecture. The range properties characterized in COFs has rapidly expanded include those interest for numerous applications ranging from energy environment. Here, a background overview is provided, consisting brief introduction porous materials the design feature COFs. Then, recent advancements as designer platform plethora emphasized together discussions about strategies principles involved. Finally, challenges remaining this type material real outlined.

Язык: Английский

Процитировано

515

Covalent Organic Frameworks: Chemical Approaches to Designer Structures and Built‐In Functions DOI
Xinyi Chen, Keyu Geng, Ruoyang Liu

и другие.

Angewandte Chemie International Edition, Год журнала: 2019, Номер 59(13), С. 5050 - 5091

Опубликована: Май 30, 2019

Abstract A new approach has been developed to design organic polymers using topology diagrams. This strategy enables covalent integration of units into ordered topologies and creates a polymer form, that is, frameworks. is breakthrough in chemistry because it sets molecular platform for synthesizing with predesignable primary high‐order structures, which central aim over century but unattainable traditional principles. field its own features are distinct from conventional polymers. Review summarizes the fundamentals as well major progress by focusing on used including principles, synthetic strategies, control methods. We scrutinize built‐in functions specific structures revealing various interplays mechanisms involved expression function. propose fundamental issues be addressed future directions physics, materials, application perspectives.

Язык: Английский

Процитировано

502

Two-dimensional covalent organic frameworks with hierarchical porosity DOI Open Access
Rong‐Ran Liang,

Shu‐Yan Jiang,

A. Ruhan

и другие.

Chemical Society Reviews, Год журнала: 2020, Номер 49(12), С. 3920 - 3951

Опубликована: Янв. 1, 2020

This review highlights the state-of-the-art progress achieved in two-dimensional covalent organic frameworks (COFs) with hierarchical porosity, an emerging class of COFs constructed by integrating different types pores into one framework.

Язык: Английский

Процитировано

426

Semiconductor/Covalent‐Organic‐Framework Z‐Scheme Heterojunctions for Artificial Photosynthesis DOI
Mi Zhang, Meng Lu, Zhongling Lang

и другие.

Angewandte Chemie International Edition, Год журнала: 2020, Номер 59(16), С. 6500 - 6506

Опубликована: Янв. 28, 2020

A strategy to covalently connect crystalline covalent organic frameworks (COFs) with semiconductors create stable organic-inorganic Z-scheme heterojunctions for artificial photosynthesis is presented. series of COF-semiconductor photocatalysts combining water-oxidation (TiO2 , Bi2 WO6 and α-Fe2 O3 ) CO2 reduction COFs (COF-316/318) was synthesized exhibited high photocatalytic -to-CO conversion efficiencies (up 69.67 μmol g-1 h-1 ), H2 O as the electron donor in gas-solid reduction, without additional photosensitizers sacrificial agents. This first report bonded COF/inorganic-semiconductor systems utilizing applied photosynthesis. Experiments calculations confirmed efficient semiconductor-to-COF transfer by coupling, resulting accumulation cyano/pyridine moieties COF holes semiconductor oxidation, thus mimicking natural

Язык: Английский

Процитировано

417