Chemical Society Reviews, Journal Year: 2022, Volume and Issue: 51(15), P. 6307 - 6416
Published: Jan. 1, 2022
This review highlights the recent advances of metalated covalent organic frameworks, including synthetic strategies and applications, discusses current challenges future directions.
Language: Английский
Chemical Reviews, Journal Year: 2020, Volume and Issue: 120(16), P. 8814 - 8933
Published: Jan. 22, 2020
Covalent organic frameworks (COFs) are a class of crystalline porous polymers with permanent porosity and highly ordered structures. Unlike other polymers, significant feature COFs is that they structurally predesignable, synthetically controllable, functionally manageable. In principle, the topological design diagram offers geometric guidance for structural tiling extended polygons, polycondensation reactions provide synthetic ways to construct predesigned primary high-order Progress over past decade in chemistry these two aspects undoubtedly established base COF field. By virtue availability units diversity topologies linkages, have emerged as new field materials offer powerful molecular platform complex tailor-made functional development. Here we target comprehensive review field, historic overview survey advances topology reactions, illustrate features diversities, scrutinize development potential various functions through elucidating structure–function correlations based on interactions photons, electrons, holes, spins, ions, molecules, discuss key fundamental challenging issues need be addressed, predict future directions from chemistry, physics, perspectives.
Language: Английский
Citations
2904
Chemical Society Reviews, Journal Year: 2020, Volume and Issue: 49(3), P. 708 - 735
Published: Jan. 1, 2020
This review article comprehensively summarizes the recent progress in development of covalent organic framework materials for separation applications.
Language: Английский
Citations
1149
Chemical Society Reviews, Journal Year: 2020, Volume and Issue: 49(11), P. 3565 - 3604
Published: Jan. 1, 2020
The current advances, structure-property relationship and future perspectives in covalent organic frameworks (COFs) their nanosheets for electrochemical energy storage (EES) conversion (EEC) are summarized.
Language: Английский
Citations
885
Chemical Society Reviews, Journal Year: 2020, Volume and Issue: 49(5), P. 1357 - 1384
Published: Jan. 1, 2020
We summarize in this review the current state-of-the-art development of three dimensional covalent organic frameworks.
Language: Английский
Citations
723
Chemical Society Reviews, Journal Year: 2019, Volume and Issue: 48(14), P. 3903 - 3945
Published: Jan. 1, 2019
This review is aimed at providing an in-depth understanding of the potential post-synthetic strategies for modification covalent organic frameworks.
Language: Английский
Citations
626
Coordination Chemistry Reviews, Journal Year: 2019, Volume and Issue: 400, P. 213046 - 213046
Published: Sept. 11, 2019
Language: Английский
Citations
534
Advanced Science, Journal Year: 2018, Volume and Issue: 6(2)
Published: Nov. 12, 2018
Abstract Covalent organic frameworks (COFs) are an emerging class of functional nanostructures with intriguing properties, due to their unprecedented combination high crystallinity, tunable pore size, large surface area, and unique molecular architecture. The range properties characterized in COFs has rapidly expanded include those interest for numerous applications ranging from energy environment. Here, a background overview is provided, consisting brief introduction porous materials the design feature COFs. Then, recent advancements as designer platform plethora emphasized together discussions about strategies principles involved. Finally, challenges remaining this type material real outlined.
Language: Английский
Citations
516
Angewandte Chemie International Edition, Journal Year: 2019, Volume and Issue: 59(13), P. 5050 - 5091
Published: May 30, 2019
Abstract A new approach has been developed to design organic polymers using topology diagrams. This strategy enables covalent integration of units into ordered topologies and creates a polymer form, that is, frameworks. is breakthrough in chemistry because it sets molecular platform for synthesizing with predesignable primary high‐order structures, which central aim over century but unattainable traditional principles. field its own features are distinct from conventional polymers. Review summarizes the fundamentals as well major progress by focusing on used including principles, synthetic strategies, control methods. We scrutinize built‐in functions specific structures revealing various interplays mechanisms involved expression function. propose fundamental issues be addressed future directions physics, materials, application perspectives.
Language: Английский
Citations
502
Chemical Society Reviews, Journal Year: 2020, Volume and Issue: 49(12), P. 3920 - 3951
Published: Jan. 1, 2020
This review highlights the state-of-the-art progress achieved in two-dimensional covalent organic frameworks (COFs) with hierarchical porosity, an emerging class of COFs constructed by integrating different types pores into one framework.
Language: Английский
Citations
427
Angewandte Chemie International Edition, Journal Year: 2020, Volume and Issue: 59(16), P. 6500 - 6506
Published: Jan. 28, 2020
A strategy to covalently connect crystalline covalent organic frameworks (COFs) with semiconductors create stable organic-inorganic Z-scheme heterojunctions for artificial photosynthesis is presented. series of COF-semiconductor photocatalysts combining water-oxidation (TiO2 , Bi2 WO6 and α-Fe2 O3 ) CO2 reduction COFs (COF-316/318) was synthesized exhibited high photocatalytic -to-CO conversion efficiencies (up 69.67 μmol g-1 h-1 ), H2 O as the electron donor in gas-solid reduction, without additional photosensitizers sacrificial agents. This first report bonded COF/inorganic-semiconductor systems utilizing applied photosynthesis. Experiments calculations confirmed efficient semiconductor-to-COF transfer by coupling, resulting accumulation cyano/pyridine moieties COF holes semiconductor oxidation, thus mimicking natural
Language: Английский
Citations
418