Green Chemistry, Год журнала: 2024, Номер 26(6), С. 3072 - 3124
Опубликована: Янв. 1, 2024
Ionic liquids as additives in nanoparticles influence their morphology and enhance bioactivity, highlighting key role sustainable chemistry, a major environmental advance.
Язык: Английский
Chemical Engineering Journal, Год журнала: 2023, Номер 463, С. 142298 - 142298
Опубликована: Март 10, 2023
Язык: Английский
Процитировано
59
Green Chemistry, Год журнала: 2023, Номер 25(4), С. 1237 - 1260
Опубликована: Янв. 1, 2023
The interplay among the properties of catalysts, substrates, products, and ionic liquids (ILs) for a desired selective reaction is presented with selected examples. A guide to select most adequate IL catalytic device proposed.
Язык: Английский
Процитировано
55
ChemSusChem, Год журнала: 2023, Номер 16(20)
Опубликована: Июль 18, 2023
Abstract In the spirit of circular economy and sustainable chemistry, use environmentally friendly chemical products in pharmacy has become a hot topic. recent years, organic solvents have been subject great range restriction policies due to their harmful effects on environment toxicity human health. parallel, deep eutectic (DESs) emerged as suitable greener with beneficial environmental impacts rich palette physicochemical advantages related low cost biocompatibility. Additionally, DESs can enable remarkable solubilizing effect for several active pharmaceutical ingredients (APIs), thus forming therapeutic (TheDESs). this work, special attention is paid DESs, presenting precise definition, classification, methods preparation, characterization. A description natural (NaDESs), i. e., present sources, also reported. Moreover, review article first one detail different approaches judiciously selecting constituents order minimize number experiments. The role biomedical sectors impact development successful therapies are discussed.
Язык: Английский
Процитировано
48
Small, Год журнала: 2024, Номер unknown
Опубликована: Март 7, 2024
Abstract As one of the key components supercapacitors, electrolyte is intensively investigated to promote fast development energy supply system under extremely cold conditions. However, high freezing point and sluggish ion transport kinetics for routine electrolytes hinder application supercapacitors at low temperatures. Resultantly, liquid should be oriented reduce point, accompanied by other superior characteristics, such as large ionic conductivity, viscosity outstanding chemical stability. In this review, intrinsically physical parameters microscopic structure low‐temperature are discussed thoroughly, then previously reported strategies that used address associated issues summarized subsequently from aspects aqueous non‐aqueous (organic electrolyte). addition, some advanced spectroscopy techniques theoretical simulation better decouple solvation reveal link between briefly presented. Finally, further improvement direction put forward provide a reference guidance follow‐up research.
Язык: Английский
Процитировано
22
Antioxidants, Год журнала: 2024, Номер 13(2), С. 239 - 239
Опубликована: Фев. 15, 2024
Carotenoids are ubiquitous and versatile isoprenoid compounds. The intake of foods rich in these pigments is often associated with health benefits, attributable to the provitamin A activity some them different mechanisms. importance carotenoids their derivatives for production health-promotion through diet beyond doubt. In new circular economy paradigm, recovery biorefinery process highly desirable, which greener processes solvents being advocated for, considering many studies conducted at laboratory scale. This review summarizes information on extraction technologies (ultrasound, microwaves, pulsed electric fields, pressurized liquid extraction, sub- supercritical fluid enzyme-assisted extraction) green (ethyl lactate, 2-methyltetrahydrofuran, natural deep eutectic solvents, ionic liquids), potential substitutes more toxic less environmentally friendly solvents. Additionally, it discusses results latest sustainable carotenoids. conclusions drawn from indicate that while promising, scalability real industrial scenarios poses a significant challenge. Furthermore, incorporating life cycle assessment analyses crucial comprehensive evaluation sustainability innovative compared industry-standard methods.
Язык: Английский
Процитировано
19
Current Opinion in Green and Sustainable Chemistry, Год журнала: 2024, Номер 47, С. 100913 - 100913
Опубликована: Март 15, 2024
Язык: Английский
Процитировано
19
npj Materials Sustainability, Год журнала: 2024, Номер 2(1)
Опубликована: Май 15, 2024
Abstract Biomass processing employing ionic liquids is already an established option at the laboratory scale. Ionic can disrupt and deconstruct lignocellulosic biomass network, giving rise to multiple options for valorisation. However, there still much work remaining accomplish scale-up commercialisation of liquid-based processing. Important issues such as liquid cost recyclability, among others, need be carefully addressed. In addition, modify structure properties recovered materials, impacting potential applications. Due complex nature liquids, where combinations anions cations are possible, these should considered each process application, making it difficult generalise all cases. This perspective covers main challenges opportunities in employment processing, both stage valorisation fractions. Among them, we discuss importance solvent recovery costs two critical consider well major role lignin condensation plays hindering ionoSolv different approaches valorise cellulose.
Язык: Английский
Процитировано
19
Analytica—A Journal of Analytical Chemistry and Chemical Analysis, Год журнала: 2025, Номер 6(1), С. 10 - 10
Опубликована: Март 11, 2025
Green analytical chemistry represents a transformative approach to science, emphasizing sustainability and environmental stewardship while maintaining high standards of accuracy precision. This review highlights recent innovations in green chemistry, including the use solvents, such as water, supercritical carbon dioxide, ionic liquids, bio-based alternatives, well energy-efficient techniques like microwave-assisted, ultrasound-assisted, photo-induced processes. Advances instrumentation, miniaturized portable devices, integration automation chemometric tools, have further enhanced efficiency reduced footprint workflows. Despite these advancements, challenges remain, need balance performance with eco-friendliness lack global measure promote sustainable practices consistently. However, future looks promising, emerging technologies artificial intelligence digital tools offering new ways optimize workflows, minimize waste, streamline By focusing on areas, is transforming methodologies into that not only achieve but also align goals. underscores how more than just scientific discipline, pathway for reducing ecological impact processes driving innovation science industry. With continued commitment research, collaboration, adoption cutting-edge technologies, has potential shape greener its diverse applications.
Язык: Английский
Процитировано
3
Bioresource Technology, Год журнала: 2022, Номер 368, С. 128280 - 128280
Опубликована: Ноя. 8, 2022
Язык: Английский
Процитировано
54
International Journal of Molecular Sciences, Год журнала: 2022, Номер 23(19), С. 11401 - 11401
Опубликована: Сен. 27, 2022
The increasing concentration of CO2 in the atmosphere is related to global climate change. Carbon capture, utilization, and storage (CCUS) an important technology reduce emissions deal with development new materials technologies for efficient capture has received attention among researchers. Ionic liquids (ILs), especially functionalized ILs, such unique properties as almost no vapor pressure, thermal- chemical-stability, non-flammability, tunable properties, have been used CCUS great interest. This paper focuses on ILs past decade (2012~2022). Functionalized or task-specific are active sites cations or/and anions. main contents include three parts: cation-functionalized anion-functionalized cation-anion dual-functionalized capture. In addition, classification, structures, synthesis also summarized. Finally, future directions, concerns, prospects discussed. review beneficial researchers obtain overall understanding CO2-philic ILs. work will open a door develop novel IL-based solvents separation other gases, SO2, H2S, NOx, NH3, so on.
Язык: Английский
Процитировано
49