ACS Applied Polymer Materials,
Journal Year:
2024,
Volume and Issue:
6(7), P. 3966 - 3974
Published: April 1, 2024
The
development
of
soft
eutectogels
that
are
highly
transparent,
stretchable,
self-healing,
self-adhesive,
recyclable,
and
can
be
used
for
underwater
sensing
applications
is
desirable.
Here,
with
multiple
functionalities
prepared
by
the
one-step
copolymerization
rigid
polymerizable
ionic
liquids
acrylate
monomers
in
a
hydrophobic
deep
eutectic
solvent
consisting
thymol/coumarin.
Poly(ionic
liquids)/polyacrylates
to
construct
tough
backbone
eutectogel
networks,
whereas
components
introduced
into
polymer
matrix
impart
dynamic
cross-linking
properties.
Overall,
network
has
excellent
hydrophobicity
intermolecular
interactions,
resulting
water
resistance,
mechanical
strength,
self-adhesion
behavior
even
aqueous
environments.
as
an
sensor
good
capability
detect
strain,
touch,
changes
surrounding
environment.
Moreover,
dynamically
cross-linked
easily
recycled
through
solvent.
methodology
proposed
this
study
holds
promise
future
fields
sensors,
wet
adhesives,
flexible
electronics.
Green Chemistry,
Journal Year:
2023,
Volume and Issue:
25(4), P. 1237 - 1260
Published: Jan. 1, 2023
The
interplay
among
the
properties
of
catalysts,
substrates,
products,
and
ionic
liquids
(ILs)
for
a
desired
selective
reaction
is
presented
with
selected
examples.
A
guide
to
select
most
adequate
IL
catalytic
device
proposed.
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: March 7, 2024
Abstract
As
one
of
the
key
components
supercapacitors,
electrolyte
is
intensively
investigated
to
promote
fast
development
energy
supply
system
under
extremely
cold
conditions.
However,
high
freezing
point
and
sluggish
ion
transport
kinetics
for
routine
electrolytes
hinder
application
supercapacitors
at
low
temperatures.
Resultantly,
liquid
should
be
oriented
reduce
point,
accompanied
by
other
superior
characteristics,
such
as
large
ionic
conductivity,
viscosity
outstanding
chemical
stability.
In
this
review,
intrinsically
physical
parameters
microscopic
structure
low‐temperature
are
discussed
thoroughly,
then
previously
reported
strategies
that
used
address
associated
issues
summarized
subsequently
from
aspects
aqueous
non‐aqueous
(organic
electrolyte).
addition,
some
advanced
spectroscopy
techniques
theoretical
simulation
better
decouple
solvation
reveal
link
between
briefly
presented.
Finally,
further
improvement
direction
put
forward
provide
a
reference
guidance
follow‐up
research.
Antioxidants,
Journal Year:
2024,
Volume and Issue:
13(2), P. 239 - 239
Published: Feb. 15, 2024
Carotenoids
are
ubiquitous
and
versatile
isoprenoid
compounds.
The
intake
of
foods
rich
in
these
pigments
is
often
associated
with
health
benefits,
attributable
to
the
provitamin
A
activity
some
them
different
mechanisms.
importance
carotenoids
their
derivatives
for
production
health-promotion
through
diet
beyond
doubt.
In
new
circular
economy
paradigm,
recovery
biorefinery
process
highly
desirable,
which
greener
processes
solvents
being
advocated
for,
considering
many
studies
conducted
at
laboratory
scale.
This
review
summarizes
information
on
extraction
technologies
(ultrasound,
microwaves,
pulsed
electric
fields,
pressurized
liquid
extraction,
sub-
supercritical
fluid
enzyme-assisted
extraction)
green
(ethyl
lactate,
2-methyltetrahydrofuran,
natural
deep
eutectic
solvents,
ionic
liquids),
potential
substitutes
more
toxic
less
environmentally
friendly
solvents.
Additionally,
it
discusses
results
latest
sustainable
carotenoids.
conclusions
drawn
from
indicate
that
while
promising,
scalability
real
industrial
scenarios
poses
a
significant
challenge.
Furthermore,
incorporating
life
cycle
assessment
analyses
crucial
comprehensive
evaluation
sustainability
innovative
compared
industry-standard
methods.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(19), P. 11235 - 11265
Published: Jan. 1, 2024
A
green
solvent
hybrid
system
will
bring
about
sustainable
development
in
the
battery
industry
by
efficiently
and
environmentally
friendly
recycling
of
valuable
resources
contained
waste
batteries.
npj Materials Sustainability,
Journal Year:
2024,
Volume and Issue:
2(1)
Published: May 15, 2024
Abstract
Biomass
processing
employing
ionic
liquids
is
already
an
established
option
at
the
laboratory
scale.
Ionic
can
disrupt
and
deconstruct
lignocellulosic
biomass
network,
giving
rise
to
multiple
options
for
valorisation.
However,
there
still
much
work
remaining
accomplish
scale-up
commercialisation
of
liquid-based
processing.
Important
issues
such
as
liquid
cost
recyclability,
among
others,
need
be
carefully
addressed.
In
addition,
modify
structure
properties
recovered
materials,
impacting
potential
applications.
Due
complex
nature
liquids,
where
combinations
anions
cations
are
possible,
these
should
considered
each
process
application,
making
it
difficult
generalise
all
cases.
This
perspective
covers
main
challenges
opportunities
in
employment
processing,
both
stage
valorisation
fractions.
Among
them,
we
discuss
importance
solvent
recovery
costs
two
critical
consider
well
major
role
lignin
condensation
plays
hindering
ionoSolv
different
approaches
valorise
cellulose.
International Journal of Molecular Sciences,
Journal Year:
2022,
Volume and Issue:
23(19), P. 11401 - 11401
Published: Sept. 27, 2022
The
increasing
concentration
of
CO2
in
the
atmosphere
is
related
to
global
climate
change.
Carbon
capture,
utilization,
and
storage
(CCUS)
an
important
technology
reduce
emissions
deal
with
development
new
materials
technologies
for
efficient
capture
has
received
attention
among
researchers.
Ionic
liquids
(ILs),
especially
functionalized
ILs,
such
unique
properties
as
almost
no
vapor
pressure,
thermal-
chemical-stability,
non-flammability,
tunable
properties,
have
been
used
CCUS
great
interest.
This
paper
focuses
on
ILs
past
decade
(2012~2022).
Functionalized
or
task-specific
are
active
sites
cations
or/and
anions.
main
contents
include
three
parts:
cation-functionalized
anion-functionalized
cation-anion
dual-functionalized
capture.
In
addition,
classification,
structures,
synthesis
also
summarized.
Finally,
future
directions,
concerns,
prospects
discussed.
review
beneficial
researchers
obtain
overall
understanding
CO2-philic
ILs.
work
will
open
a
door
develop
novel
IL-based
solvents
separation
other
gases,
SO2,
H2S,
NOx,
NH3,
so
on.
ChemSusChem,
Journal Year:
2023,
Volume and Issue:
16(20)
Published: July 18, 2023
Abstract
In
the
spirit
of
circular
economy
and
sustainable
chemistry,
use
environmentally
friendly
chemical
products
in
pharmacy
has
become
a
hot
topic.
recent
years,
organic
solvents
have
been
subject
great
range
restriction
policies
due
to
their
harmful
effects
on
environment
toxicity
human
health.
parallel,
deep
eutectic
(DESs)
emerged
as
suitable
greener
with
beneficial
environmental
impacts
rich
palette
physicochemical
advantages
related
low
cost
biocompatibility.
Additionally,
DESs
can
enable
remarkable
solubilizing
effect
for
several
active
pharmaceutical
ingredients
(APIs),
thus
forming
therapeutic
(TheDESs).
this
work,
special
attention
is
paid
DESs,
presenting
precise
definition,
classification,
methods
preparation,
characterization.
A
description
natural
(NaDESs),
i.
e.,
present
sources,
also
reported.
Moreover,
review
article
first
one
detail
different
approaches
judiciously
selecting
constituents
order
minimize
number
experiments.
The
role
biomedical
sectors
impact
development
successful
therapies
are
discussed.
