Synthesis of Terminal Vinyl Phosphine Oxides via Desulfonative C—P Formation from Alkenyl Sulfonium Salts DOI

Jiangzhen An,

Qi‐Yan Lv, Kai Sun

и другие.

Chinese Journal of Organic Chemistry, Год журнала: 2024, Номер 44(12), С. 3747 - 3747

Опубликована: Янв. 1, 2024

Язык: Английский

Potassium-modified carbon nitride photocatalyzed-aminoacylation of N‑sulfonyl ketimines DOI

Cailing Wu,

Shaojie Wu, Qifei Huang

и другие.

Chinese Chemical Letters, Год журнала: 2024, Номер 36(2), С. 110250 - 110250

Опубликована: Июль 17, 2024

Язык: Английский

Процитировано

7
Functionalization of 1,3‐Butadiene Derivatives under Photo/Electrocatalysis DOI

Yinghui Huang,

Linhui Shen,

Chunhua Ma

и другие.

European Journal of Organic Chemistry, Год журнала: 2024, Номер 27(28)

Опубликована: Май 20, 2024

Abstract In recent years, the functionalization of 1,3‐butadiene has become an attractive strategy for constructing allyl compounds with molecular and structural complexity, current research focuses on synthetic chemistry organic synthesis. Compared traditional synthesis method, methods promoted by photochemistry or electrochemistry represent environmentally friendly mild strategy. this review, reactions under photochemical/electrochemical processes in years are reviewed according to classification systems, particular emphasis corresponding reaction mechanism, which lays a foundation further exploration new catalytic methods.

Язык: Английский

Процитировано

5
Photocatalytic synthesis of polyfluoroalkylated dihydropyrazoles and tetrahydropyridazines DOI

Ling-Li Liu,

Chengli Xiang,

Changduo Pan

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(77), С. 10764 - 10767

Опубликована: Янв. 1, 2024

A photocatalytic trifluoromethylation/cyclization reaction of

Язык: Английский

Процитировано

3
Electroreductively driven C–H functionalization of arenes DOI
Pengfei Xie,

Anzai Shi,

Youai Qiu

и другие.

Chem Catalysis, Год журнала: 2025, Номер unknown, С. 101359 - 101359

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
Bichromophoric Ruthenium Complexes for Photocatalyzed Late-Stage Synthesis of Trifluoromethylated Indolizines DOI Creative Commons

Kevin Klaus Stefanoni,

Matthias Schmitz,

Johanna Treuheit

и другие.

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 5, 2025

Indolizines are a promising class of biologically active compounds. However, photocatalytic methods for their selective derivatization scarce in the literature. Herein, mild, simple, and chemoselective protocol synthesis 3-(trifluoromethyl)indolizine has been developed. The desired products were obtained good to excellent yields can be easily on gram scale. By tuning redox properties Ru-based photocatalyst, it is possible achieve competitive further apply optimized conditions broad variety substrates. This method tolerates many functional groups and, therefore, used late-stage functionalization. Our combined theoretical spectroscopic findings revealed that superior dyad-like ruthenium catalyst developed this study completely different electronic nature both key species crucial efficient photoredox catalysis compared commonly homoleptic complexes.

Язык: Английский

Процитировано

0
Nd@g-C3N4 dual-functional photosynthesis and antitumor activities of 3-fluoroalkylated quinoxalin-2(1H)-ones DOI

Qiong-Hui Peng,

Ningbo Li,

Jia-Cheng Hou

и другие.

Chinese Chemical Letters, Год журнала: 2025, Номер unknown, С. 111402 - 111402

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0
CeCl3-Catalyzed C–H Alkylation of N-Sulfonyl Ketimines with Alkanes and Ether via Photoinduced Ligand-to-Metal Charge Transfer DOI
Bin Zhou, Min Dong, Wei Wang

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(24), С. 18337 - 18343

Опубликована: Дек. 9, 2024

A cerium-catalyzed C–H alkylation of N-sulfonyl ketimines with low-cost and readily available alkanes as alkyl sources was developed. This transformation proceeded through the synergy photoinitiated ligand-to-metal charge transfer (LMCT) using a chlorine radical an HAT reagent air green oxidant. series alkylated were synthesized moderate to good yields in highly atom-economic manner under chemical oxidant-free conditions.

Язык: Английский

Процитировано

2
Efficient Trifluoromethylation of Halogenated Hydrocarbons Using Novel [(bpy)Cu(O2CCF2SO2F)2] Reagent DOI Creative Commons

Xiong Wu,

Xin Qiu,

Wenrun Lou

и другие.

Molecules, Год журнала: 2024, Номер 29(12), С. 2849 - 2849

Опубликована: Июнь 14, 2024

This study introduces a novel trifluoromethylating reagent, [(bpy)Cu(O2CCF2SO2F)2], notable for not only its practical synthesis from cost-effective starting materials and scalability but also nonhygroscopic nature. The reagent demonstrates high efficiency in facilitating trifluoromethylation reactions with various halogenated hydrocarbons, yielding products good yields exhibiting broad functional group compatibility. development of [(bpy)Cu(O2CCF2SO2F)2] represents an advancement the field organic synthesis, potentially serving as valuable addition to arsenal existing agents.

Язык: Английский

Процитировано

1
Catalyst-Free Synthesis of Novel α-Trifluoromethylated Tertiary Alcohols Bearing Azaarenes as Potential Antifungal Agents DOI
Nan Yang, Zhuang Wu, Mingxin Wang

и другие.

Journal of Molecular Structure, Год журнала: 2024, Номер unknown, С. 140042 - 140042

Опубликована: Сен. 1, 2024

Язык: Английский

Процитировано

1
Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF3-Enones DOI

Xiao-Ya Yuan,

Zhimin Lü,

Xianqiang Huang

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Дек. 2, 2024

Condition-controlled switchable and divergent transformations of cost-effective 2-bromo-3,3,3-trifluoropropene (BTP) aldehydes were realized using a decatungstate (TBADT)-photocatalyzed strategy. The hydroacylated products, i.e., β,β-Br,CF

Язык: Английский

Процитировано

1