Reaction Mechanisms and Applications of Single Atom Catalysts for Thermal-Catalytic Carbon Dioxide Hydrogenation Toward Oxygenates

ACS Catalysis, Год журнала: 2024, Номер 14(21), С. 16434 - 16458

Опубликована: Окт. 23, 2024

Thermo-catalytic CO2 hydrogenation to high-value oxygenates has been regarded as one of the most powerful strategies that can potentially alleviate excessive emissions. However, due high chemical stability and variability pathways, it is still challenging achieve highly active selective hydrogenation. Single atom catalysts (SACs) with ultrahigh metal utilization efficiency extraordinary electronic features have displayed growing importance for thermo-catalytic multiple developed improve performances. Here, we review breakthroughs in developing SACs efficient toward common (CO, HCOOH, CH3OH, CH3CH2OH) following order: first, an analysis reaction mechanisms thermodynamics challenges reactions; second, a summary SAs designed by dividing them into two categories single- dual-sites; third, discussion support effects focus on approaches regulating strong metal–support interaction (MSI). Summarily, current future perspectives develop higher-performance are presented. We expect this bring more design inspiration trigger innovation catalytic evolution materials eventually benefit achievement carbon-neutrality goal.

Язык: Английский

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Structural Diversity and Tunable Luminescent Properties of Zn(II) Metal–Organic Frameworks with Terephthalate and 4,7-Di(1,2,4-triazol-1-yl)-2,1,3-benzothiadiazole Linkers

Crystal Growth & Design, Год журнала: 2024, Номер unknown

Опубликована: Сен. 5, 2024

Язык: Английский

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Achievements and challenges in cobalt-based catalysts for water electrolysis

Chemical Engineering Journal, Год журнала: 2024, Номер 500, С. 157080 - 157080

Опубликована: Окт. 28, 2024

Язык: Английский

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Catalytic and kinetic isotope effect studies of CO2 reduction on Cu-Metalated UiO-66 Metal-Organic framework

Applied Surface Science, Год журнала: 2025, Номер unknown, С. 162323 - 162323

Опубликована: Янв. 1, 2025

Язык: Английский

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Precise Synthesis of Single Atom Catalysts for Boosting Next‐Generation Advanced Oxidation and Reduction Processes in Sustainable Energy Applications

ChemCatChem, Год журнала: 2024, Номер unknown

Опубликована: Окт. 28, 2024

Abstract Single‐atom catalysts (SACs) demonstrate high selectivity, maximal atom utilization, and unique active site configurations, establishing them as a rapidly expanding research field. Understanding the intrinsic relationship between structure catalytic performance is crucial for effective use of SACs in catalysis. However, providing clear explanation coordination environment structural regulation remains significant challenge next‐generation renewable energy materials, especially advanced oxidation reduction processes critical sustainable applications. This comprehensive review offers an in‐depth overview current progress design SACs, with specific focus on precise synthesis, control, performance. Furthermore, we elucidate reaction mechanisms various systems selective methods used to precisely synthesize enhance reactions sector. Finally, this explores complex challenges investigating developing perspective solutions technologies future overcome these achieve practical

Язык: Английский

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Manganese-based metal-organic frameworks with oxidase properties break the temperature limitation of nano enzymes for glutathione detection

New Journal of Chemistry, Год журнала: 2024, Номер 48(47), С. 19927 - 19935

Опубликована: Янв. 1, 2024

This study presents a manganese-based metal–organic framework (Mn/BTC-MOF) with excellent oxidase-like activity at 0–50 °C, can achieve colorimetric detection of glutathione in serum over wide temperature range.

Язык: Английский

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Development of a novel multiphase Ni–Fe–O–S/NF bifunctional catalyst for efficient overall water splitting

International Journal of Hydrogen Energy, Год журнала: 2024, Номер 101, С. 258 - 268

Опубликована: Дек. 31, 2024

Язык: Английский

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Interplay of Product Selectivity and Isolated Ru-Oxo Sites in the Solvent-Free Oxidization of Benzyl Alcohol

The Journal of Physical Chemistry C, Год журнала: 2024, Номер unknown

Опубликована: Дек. 31, 2024

Язык: Английский

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