Interplay of Product Selectivity and Isolated Ru-Oxo Sites in the Solvent-Free Oxidization of Benzyl Alcohol DOI Creative Commons
Dinh Hung Mac, Katja Neubauer, Hanan Atia

et al.

The Journal of Physical Chemistry C, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 31, 2024

Language: Английский

Achievements and challenges in cobalt-based catalysts for water electrolysis DOI
Mengyu Chen, Jingqi Guan

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 500, P. 157080 - 157080

Published: Oct. 28, 2024

Language: Английский

Citations

9
Reaction Mechanisms and Applications of Single Atom Catalysts for Thermal-Catalytic Carbon Dioxide Hydrogenation Toward Oxygenates DOI
Fei Wang, Yicheng Liu,

Mengke Peng

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(21), P. 16434 - 16458

Published: Oct. 23, 2024

Thermo-catalytic CO2 hydrogenation to high-value oxygenates has been regarded as one of the most powerful strategies that can potentially alleviate excessive emissions. However, due high chemical stability and variability pathways, it is still challenging achieve highly active selective hydrogenation. Single atom catalysts (SACs) with ultrahigh metal utilization efficiency extraordinary electronic features have displayed growing importance for thermo-catalytic multiple developed improve performances. Here, we review breakthroughs in developing SACs efficient toward common (CO, HCOOH, CH3OH, CH3CH2OH) following order: first, an analysis reaction mechanisms thermodynamics challenges reactions; second, a summary SAs designed by dividing them into two categories single- dual-sites; third, discussion support effects focus on approaches regulating strong metal–support interaction (MSI). Summarily, current future perspectives develop higher-performance are presented. We expect this bring more design inspiration trigger innovation catalytic evolution materials eventually benefit achievement carbon-neutrality goal.

Language: Английский

Citations

8
Structural Diversity and Tunable Luminescent Properties of Zn(II) Metal–Organic Frameworks with Terephthalate and 4,7-Di(1,2,4-triazol-1-yl)-2,1,3-benzothiadiazole Linkers DOI
Dmitry I. Pavlov, Alexey A. Ryadun, Vladimir P. Fedin

et al.

Crystal Growth & Design, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 5, 2024

Language: Английский

Citations

7
Catalytic and kinetic isotope effect studies of CO2 reduction on Cu-Metalated UiO-66 Metal-Organic framework DOI

Denis Makhmutov,

Bunyarat Rungtaweevoranit, Ashour A. Ahmed

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162323 - 162323

Published: Jan. 1, 2025

Language: Английский

Citations

0
Precise Synthesis of Single Atom Catalysts for Boosting Next‐Generation Advanced Oxidation and Reduction Processes in Sustainable Energy Applications DOI Open Access

Ata Ur Rehman,

Tianyu Zhao, Sining Yun

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 28, 2024

Abstract Single‐atom catalysts (SACs) demonstrate high selectivity, maximal atom utilization, and unique active site configurations, establishing them as a rapidly expanding research field. Understanding the intrinsic relationship between structure catalytic performance is crucial for effective use of SACs in catalysis. However, providing clear explanation coordination environment structural regulation remains significant challenge next‐generation renewable energy materials, especially advanced oxidation reduction processes critical sustainable applications. This comprehensive review offers an in‐depth overview current progress design SACs, with specific focus on precise synthesis, control, performance. Furthermore, we elucidate reaction mechanisms various systems selective methods used to precisely synthesize enhance reactions sector. Finally, this explores complex challenges investigating developing perspective solutions technologies future overcome these achieve practical

Language: Английский

Citations

1
Manganese-based metal-organic frameworks with oxidase properties break the temperature limitation of nano enzymes for glutathione detection DOI

Xujuan Zhao,

Xiaojie Sun,

Jinzhi Lv

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: 48(47), P. 19927 - 19935

Published: Jan. 1, 2024

This study presents a manganese-based metal–organic framework (Mn/BTC-MOF) with excellent oxidase-like activity at 0–50 °C, can achieve colorimetric detection of glutathione in serum over wide temperature range.

Language: Английский

Citations

1
Development of a novel multiphase Ni–Fe–O–S/NF bifunctional catalyst for efficient overall water splitting DOI

Zhen Pei,

Tengteng Qin,

Wenbo Wang

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 101, P. 258 - 268

Published: Dec. 31, 2024

Language: Английский

Citations

1
Interplay of Product Selectivity and Isolated Ru-Oxo Sites in the Solvent-Free Oxidization of Benzyl Alcohol DOI Creative Commons
Dinh Hung Mac, Katja Neubauer, Hanan Atia

et al.

The Journal of Physical Chemistry C, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 31, 2024

Language: Английский

Citations

0