Chemical Communications,
Год журнала:
2023,
Номер
59(92), С. 13668 - 13678
Опубликована: Янв. 1, 2023
Cages
at
work:
structural
tunability
results
in
tailored
properties,
which
makes
these
systems
suitable
for
countless
applications
sensing
and
separation
processes,
both
solution
the
solid
state.
Sensors,
Год журнала:
2022,
Номер
22(7), С. 2649 - 2649
Опубликована: Март 30, 2022
Optical
chemical
sensors
are
widely
applied
in
many
fields
of
modern
analytical
practice,
due
to
their
simplicity
preparation
and
signal
acquisition,
low
costs,
fast
response
time.
Moreover,
the
construction
most
optical
requires
neither
wire
connections
with
detector
nor
sophisticated
energy-consuming
hardware,
enabling
wireless
sensor
development
for
a
fast,
in-field
online
analysis.
In
this
review,
last
five
years
progress
(from
2017
2021)
field
persistent
organic
pollutants
(POPs)
is
provided.
The
operating
mechanisms,
transduction
principles
types
sensing
materials
employed
single
selective
multisensory
systems
reviewed.
selected
examples
applications
reported
demonstrate
benefits
drawbacks
use
POPs
assessment.
Abstract
Mechanical
stimuli
have
rather
ambiguous
and
less‐specific
features
among
various
physical
stimuli,
but
most
materials
exhibit
a
certain
level
of
responses
upon
mechanical
inputs.
Unexplored
sciences
remain
in
responding
systems
as
one
the
frontiers
science.
Nanoarchitectonics
approaches
for
mechanically
are
discussed
mechano‐nanoarchitectonics
this
review
article.
Recent
on
molecular
with
response
capabilities
first
exemplified
two
viewpoints:
i)
control
supramolecular
assemblies
ii)
evaluation
atom/molecular
structures.
In
following
sections,
special
attentions
interfacial
environments
emphasized.
The
section
entitled
iii)
Control
Molecular
System
at
Dynamic
Interface
describes
coupling
macroscopic
forces
molecular‐level
phenomena.
Delicate
can
be
applied
to
functional
molecules
embedded
air–water
interface
where
operation
machines
tuning
receptors
actions
discussed.
Finally,
important
role
media
further
extended
living
cells
described
iv)
Biosystems.
Pioneering
cell
fate
regulations
liquid–liquid
interfaces
addition
well‐known
mechanobiology.
ACS Omega,
Год журнала:
2022,
Номер
7(17), С. 15082 - 15089
Опубликована: Апрель 25, 2022
Facile
access
to
new
one-walled
meso-substituted
phenylboronic
acid-functionalized
calix[4]pyrrole
(C4P)
has
been
revealed
for
the
first
time,
starting
from
cost-effective
and
easily
accessible
materials.
The
structures
of
both
intermediate
dipyrromethane
(DPM)
targeted
functionalized
C4P
have
confirmed
by
means
1H-NMR,
13C-NMR,
IR,
HRMS
spectral
data.
voltammetric
investigations
films
cast
over
a
glassy
carbon
electrode
(C4P-GCE)
clearly
establish
redox
stability
accessibility
boronic
acid
functional
moiety
present
in
framework.
We
demonstrate
that
presence
unique
functionality
endows
it
with
an
excellent
potential
highly
sensitive
electrochemical
sensing
neurotransmitter
dopamine
(DA).
A
linear
correlation
between
strength
Faradaic
signals
corresponding
electro-oxidation
DA
C4P-GCE
concentration
was
observed
range
as
wide
0.165-2.302
μM.
exceptional
reproducibility
DA,
nanomolar
level
limit
detection
low
15
nM.
Chemical Communications,
Год журнала:
2023,
Номер
59(92), С. 13668 - 13678
Опубликована: Янв. 1, 2023
Cages
at
work:
structural
tunability
results
in
tailored
properties,
which
makes
these
systems
suitable
for
countless
applications
sensing
and
separation
processes,
both
solution
the
solid
state.