Green Chemistry, Год журнала: 2024, Номер 26(11), С. 6666 - 6674
Опубликована: Янв. 1, 2024
The synthesis of enantiopure chiral halogenated aryl alcohols by ketoreductases was conducted in an aqueous micellar solution formed TPGS-750-M, achieving remarkable yields and enantioselectivities under high concentration.
Язык: Английский
Journal of the American Chemical Society, Год журнала: 2023, Номер 145(7), С. 4266 - 4278
Опубликована: Фев. 8, 2023
Savie is a biodegradable surfactant derived from vitamin E and polysarcosine (PSar) developed for use in organic synthesis recyclable water. This includes homogeneous catalysis (including examples employing only ppm levels of catalyst), heterogeneous catalysis, biocatalytic transformations, including multistep chemoenzymatic sequence. Use frequently leads to significantly higher yields than do conventional surfactants, while obviating the need waste-generating solvents.
Язык: Английский
Процитировано
54
Green Chemistry, Год журнала: 2024, Номер 26(11), С. 6289 - 6317
Опубликована: Янв. 1, 2024
Chemistry in water, leveraging its solvent properties, provides a safer and more sustainable alternative to traditional organic methods.
Язык: Английский
Процитировано
23
Journal of Colloid and Interface Science, Год журнала: 2021, Номер 608, С. 424 - 434
Опубликована: Сен. 29, 2021
Язык: Английский
Процитировано
77
Scientific Reports, Год журнала: 2021, Номер 11(1)
Опубликована: Авг. 23, 2021
Abstract Forward osmosis (FO) process has been extensively considered as a potential technology that could minimize the problems of traditional water desalination processes. Finding an appropriate osmotic agent is important concern in FO process. For first time, nonionic surfactant-based draw solution was introduced using self-assemblies Tween 80 and choline chloride. The addition chloride to led micelles formation with average diameter 11.03 nm. 1 H NMR spectra exhibited all groups were interacted by hydrogen bond Van der Waals’ force. influence adding micellization on its activity investigated. Despite less single components, flux 14.29 L m ‒2 h ‒1 obtained 0.15 M 80-choline self-assembly DI feed solution. Moreover, various concentrations NaCl aqueous solutions examined This report proposed possible preparation additive enhanced activities can establish innovative field study
Язык: Английский
Процитировано
66
The Journal of Organic Chemistry, Год журнала: 2022, Номер 88(10), С. 6284 - 6293
Опубликована: Июнь 14, 2022
The use of water in organic synthesis draws attention to its green chemistry features and unique ability unveil unconventional reactivities. Herein, literature about the as a reaction medium under visible-light photocatalytic conditions is summarized order highlight challenges opportunities. Accordingly, this Synopsis has been divided into four different sections focused on (1) role reactions, (2) in-/on-water (3) water-soluble photocatalysts, (4) photomicellar catalytic systems.
Язык: Английский
Процитировано
60
International Journal of Molecular Sciences, Год журнала: 2022, Номер 23(3), С. 1798 - 1798
Опубликована: Фев. 4, 2022
The use of surfactants in polymerization reactions is particularly important, mainly emulsion polymerizations. Further, micelles from biocompatible find pharmaceutical dosage forms. This paper reviews recent developments the synthesis novel gemini and bicephalous surfactants, micelle formation, their applications polymer nanoparticle synthesis, oil recovery, catalysis, corrosion, protein binding, biomedical area, drug delivery.
Язык: Английский
Процитировано
49
Journal of Molecular Liquids, Год журнала: 2024, Номер 400, С. 124559 - 124559
Опубликована: Март 26, 2024
Язык: Английский
Процитировано
10
Advanced Synthesis & Catalysis, Год журнала: 2022, Номер 364(11), С. 1776 - 1797
Опубликована: Апрель 23, 2022
Abstract Replacement of organic solvents, in particular chlorinated, aromatic, and polar aprotic ones, is an emerging issue that can find a solution the development catalytic reactions water. Nature performs multitude chemical transformations water under mild conditions mediated by enzymes. In nanoconfinement effects enzymes ensure high activity impressive stereoselectivities. Micellar catalysis nowadays real alternative approach to traditional media, enabling good conditions, with advantage possible catalyst micellar medium recycling. media emerged also as nano‐environments for stereoselective reactions, many examples metal organo‐catalysts which improvements stereoselectivity were observed respect same reaction homogeneous solvents. More specifically, both catalytically active site micelles provided surfactant contribute asymmetric induction, partially resembling what known terms imparted metallo‐enzymes. magnified image
Язык: Английский
Процитировано
34
Molecules, Год журнала: 2023, Номер 28(12), С. 4809 - 4809
Опубликована: Июнь 16, 2023
Many years ago, twelve principles were defined for carrying out chemical reactions and processes from a green chemistry perspective. It is everyone’s endeavor to take these points into account as far possible when developing new or improving existing ones. Especially in the field of organic synthesis, area research has thus been established: micellar catalysis. This review article addresses question whether catalysis by applying reaction media. The shows that many can be transferred an solvent medium, but surfactant also crucial role solubilizer. Thus, carried much more environmentally friendly manner with less risk. Moreover, surfactants are being reformulated their design, degradation add extra advantages match all chemistry.
Язык: Английский
Процитировано
23
Current Opinion in Colloid & Interface Science, Год журнала: 2023, Номер 65, С. 101691 - 101691
Опубликована: Март 17, 2023
Язык: Английский
Процитировано
20