Recent advances of metal–organic frameworks‐based proton exchange membranes in fuel cell applications DOI Creative Commons
Xiaomin Li, Junkuo Gao

SusMat, Год журнала: 2022, Номер 2(5), С. 504 - 534

Опубликована: Окт. 1, 2022

Abstract In recent years, proton exchange membrane (PEM) fuel cell (FC; PEMFC) has been widely studied and gradually applied to vehicle power supply, portable communication base station backup, emergency so on. Especially in new energy vehicles, PEMFC absolute advantages a broad market. PEM, which is the core component of PEMFC, close correlation between its property performance FC. Therefore, developing excellent PEMs focus researchers. Metal–organic frameworks (MOFs) composed metal ions/clusters organic ligands have attracted extensive attention field conduction. The hybrid membranes formed by MOFs polymers show performances design concepts, great prospects commercial application. This paper summarizes research progress MOFs‐based as hydrogen–oxygen FCs direct methanol FCs, different used substrates are also summed up.

Язык: Английский

First-row transition metal-based materials derived from bimetallic metal–organic frameworks as highly efficient electrocatalysts for electrochemical water splitting DOI

Soheila Sanati,

Ali Morsali, Hermenegildo Garcı́a

и другие.

Energy & Environmental Science, Год журнала: 2022, Номер 15(8), С. 3119 - 3151

Опубликована: Янв. 1, 2022

Electrochemical water splitting is a mature technology for hydrogen generation.

Язык: Английский

Процитировано

243

Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis DOI Creative Commons
Usman Khan,

Adeela Nairan,

Junkuo Gao

и другие.

Small Structures, Год журнала: 2022, Номер 4(6)

Опубликована: Сен. 16, 2022

The 2D nanosheets of metal–organic frameworks (MOFs) have recently emerged as a promising material that makes them valuable in widespread electrocatalytic fields due to their atomic‐level thickness, abundant active sites, and large surface area. Efficient electrocatalysts for hydrogen evolution reaction (HER), oxygen (OER), overall water splitting are highly desired with low overpotentials promote the industrial applications energy conversion devices. MOF nanostructures provide long‐term stability high electrical conductivity enhance catalyst activity durability. This review briefly summarizes synthesis HER/OER/water splitting. More attention is focused on synthetic strategies derivatives. catalytic performance superior properties these materials highlighted. outperformance originates from rational design, myriad thickness. current future challenges this field scientific perspectives overcome It suggested construction can develop state‐of‐the‐art electrocatalyst environmental division.

Язык: Английский

Процитировано

177

Metal–organic frameworks and derived materials as photocatalysts for water splitting and carbon dioxide reduction DOI
Jing Chen, Reza Abazari, Kayode Adesina Adegoke

и другие.

Coordination Chemistry Reviews, Год журнала: 2022, Номер 469, С. 214664 - 214664

Опубликована: Июнь 24, 2022

Язык: Английский

Процитировано

156

Trimetallic metal–organic frameworks and derived materials for environmental remediation and electrochemical energy storage and conversion DOI

Xinzhi Luo,

Reza Abazari, Muhammad Tahir

и другие.

Coordination Chemistry Reviews, Год журнала: 2022, Номер 461, С. 214505 - 214505

Опубликована: Март 18, 2022

Язык: Английский

Процитировано

147

Recent progress on pristine two-dimensional metal–organic frameworks as active components in supercapacitors DOI
Yuxuan Guo, Kuaibing Wang, Ye Hong

и другие.

Dalton Transactions, Год журнала: 2021, Номер 50(33), С. 11331 - 11346

Опубликована: Янв. 1, 2021

Recent progress on 2D conductive MOFs and layered containing pillar-layered nanosheets as electrode materials in SCs is reviewed, including synthetic design strategies, electrochemical performances, working mechanisms.

Язык: Английский

Процитировано

146

Tuning the electronic structure of a metal–organic framework for an efficient oxygen evolution reaction by introducing minor atomically dispersed ruthenium DOI Creative Commons

Yuwen Li,

Yuhang Wu, Tongtong Li

и другие.

Carbon Energy, Год журнала: 2022, Номер 5(2)

Опубликована: Сен. 26, 2022

Abstract The establishment of efficient oxygen evolution electrocatalysts is great value but also challenging. Herein, a durable metal–organic framework (MOF) with minor atomically dispersed ruthenium and an optimized electronic structure constructed as electrocatalyst. Significantly, the obtained NiRu 0.08 ‐MOF doping Ru only needs overpotential 187 mV at 10 mA cm −2 Tafel slop 40 dec −1 in 0.1 M KOH for reaction, can work continuously more than 300 h. Ultrahigh mass activity achieved, reaching 56.7 A g 200 mV, which 36 times higher that commercial RuO 2 . X‐ray adsorption spectroscopy density function theory calculations reveal on metal sites MOFs expected to optimize nickel sites, thus improving conductivity catalyst optimizing energy intermediates, resulting significant optimization electrocatalytic performance. This study could provide new avenue design stable MOF electrocatalysts.

Язык: Английский

Процитировано

132

Iron-based metal–organic frameworks and their derived materials for photocatalytic and photoelectrocatalytic reactions DOI
Yangdan Pan, Reza Abazari,

Beenish Tahir

и другие.

Coordination Chemistry Reviews, Год журнала: 2023, Номер 499, С. 215538 - 215538

Опубликована: Ноя. 1, 2023

Язык: Английский

Процитировано

129

Waste-Derived Catalysts for Water Electrolysis: Circular Economy-Driven Sustainable Green Hydrogen Energy DOI Creative Commons
Zhijie Chen, Sining Yun, Lan Wu

и другие.

Nano-Micro Letters, Год журнала: 2022, Номер 15(1)

Опубликована: Дек. 1, 2022

The sustainable production of green hydrogen via water electrolysis necessitates cost-effective electrocatalysts. By following the circular economy principle, utilization waste-derived catalysts significantly promotes development energy. Currently, diverse have exhibited excellent catalytic performance toward evolution reaction (HER), oxygen (OER), and overall (OWE). Herein, we systematically examine recent achievements in electrocatalysts for electrolysis. general principles design efficient are discussed, followed by illustration current strategies transforming wastes into Then, applications (i.e., carbon-based catalysts, transitional metal-based heterostructure catalysts) HER, OER, OWE reviewed successively. An emphasis is put on correlating catalysts' structure-performance relationship. Also, challenges research directions this booming field finally highlighted. This review would provide useful insights design, synthesis, electrocatalysts, thus accelerate economy-driven energy scheme.

Язык: Английский

Процитировано

122

Third-Order Nonlinear Optical Behavior of an Amide-Tricarboxylate Zinc(II) Metal–Organic Framework with Two-Fold 3D+3D Interpenetration DOI

Reza Abazari,

Elnaz Yazdani, Marzieh Nadafan

и другие.

Inorganic Chemistry, Год журнала: 2021, Номер 60(13), С. 9700 - 9708

Опубликована: Июнь 13, 2021

A new metal–organic framework (MOF), [Zn4(μ4-O)(μ6-L)2(H2O)2]n·nDMF (ZSTU-10), was assembled from zinc(II) nitrate and N,N′,N″-bis(4-carboxylate)trimesicamide linkers fully characterized. Its crystal structure discloses an intricate two-fold 3D+3D interpenetrated MOF driven by the [Zn4(μ4-O)]-based tetragonal secondary building units C3-symmetric tris-amide-tricarboxylate (μ6-L3–). Topological analysis of ZSTU-10 reveals two 3,6-connected nets with rtl (rutile) topology. Z-Scan at 532 nm conducted to study a nonlinear optical (NLO) behavior ZSTU-10. The responses were explored under various laser intensities, revealing notable third-order NLO properties in visible region. large two-photon absorption lower incident intensities highlights fact that can be applied limiting devices as well modulators. Moreover, refractive index (n2) is indicative self-defocusing behavior. This work thus expands family novel materials remarkable properties.

Язык: Английский

Процитировано

120

Cobalt containing bimetallic ZIFs and their derivatives as OER electrocatalysts: A critical review DOI

Asim Shahzad,

Faiza Zulfiqar, Muhammad Arif Nadeem

и другие.

Coordination Chemistry Reviews, Год журнала: 2022, Номер 477, С. 214925 - 214925

Опубликована: Ноя. 25, 2022

Язык: Английский

Процитировано

98