Bimetallic metal–organic frameworks and MOF-derived composites: Recent progress on electro- and photoelectrocatalytic applications

Coordination Chemistry Reviews, Год журнала: 2021, Номер 451, С. 214264 - 214264

Опубликована: Окт. 25, 2021

Язык: Английский

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First-row transition metal-based materials derived from bimetallic metal–organic frameworks as highly efficient electrocatalysts for electrochemical water splitting

Energy & Environmental Science, Год журнала: 2022, Номер 15(8), С. 3119 - 3151

Опубликована: Янв. 1, 2022

Electrochemical water splitting is a mature technology for hydrogen generation.

Язык: Английский

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MIL series of metal organic frameworks (MOFs) as novel adsorbents for heavy metals in water: A review

Journal of Hazardous Materials, Год журнала: 2022, Номер 429, С. 128271 - 128271

Опубликована: Янв. 14, 2022

Язык: Английский

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Metal–organic frameworks and derived materials as photocatalysts for water splitting and carbon dioxide reduction

Coordination Chemistry Reviews, Год журнала: 2022, Номер 469, С. 214664 - 214664

Опубликована: Июнь 24, 2022

Язык: Английский

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Trimetallic metal–organic frameworks and derived materials for environmental remediation and electrochemical energy storage and conversion

Coordination Chemistry Reviews, Год журнала: 2022, Номер 461, С. 214505 - 214505

Опубликована: Март 18, 2022

Язык: Английский

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Metal organic frameworks for antibacterial applications

Chemical Engineering Journal, Год журнала: 2022, Номер 435, С. 134975 - 134975

Опубликована: Фев. 2, 2022

Язык: Английский

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State of the art on the ultrasonic-assisted removal of environmental pollutants using metal-organic frameworks

Journal of Hazardous Materials, Год журнала: 2021, Номер 424, С. 127558 - 127558

Опубликована: Окт. 21, 2021

Язык: Английский

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Mixed Metal Fe₂Ni MIL-88B Metal–Organic Frameworks Decorated on Reduced Graphene Oxide as a Robust and Highly Efficient Electrocatalyst for Alkaline Water Oxidation

Inorganic Chemistry, Год журнала: 2022, Номер 61(8), С. 3396 - 3405

Опубликована: Фев. 14, 2022

The development of cost-effective and efficient oxygen evolution reaction (OER) catalysts has found increasing popularity due to the sluggish kinetics OER, which hampered H2 production by H2O electrolysis. In this study, Fe2Ni MIL-88 (denoted FeNi) was composited reduced graphene oxide (rGO, denoted R). Owing high porosity abundant active sites bimetallic MOF, proper conductivity rGO, synergistic impact Ni Fe, optimal composite (R@FeNi (1:1)) offered remarkable OER activity in alkaline environments. obtained employed led a low overpotential 264 mV at current density 10 mA cm-2 with Tafel slope 62 dec-1. Also, nanorods grown on rGO reduction onset potential OER. These findings exceeded results standard IrO2-based catalysts; they are also comparable or even better than previously reported MOF-based catalysts.

Язык: Английский

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A Dual-Purpose Ce(III)–Organic Framework with Amine Groups and Open Metal Sites: Third-Order Nonlinear Optical Activity and Catalytic CO₂ Fixation

ACS Applied Materials & Interfaces, Год журнала: 2023, Номер 15(31), С. 37300 - 37311

Опубликована: Июль 27, 2023

The present work focuses on the synthesis and properties of a novel multifunctional cerium(III) MOF, [Ce2(data)3(DMF)4]·DMF (data2-: 2,5-diaminoterephthalate), abbreviated as NH2-Ce-MUM-2. Its crystal structure reveals an intricate 3D 4,5-connected framework with xah topology. This MOF features unique properties, such open metal sites, presence free amino groups, high stability. Two main applications NH2-Ce-MUM-2 were investigated: (i) heterogeneous catalyst in CO2 fixation into cyclic carbonates (ii) material third-order nonlinear optical activity. As model reaction, cycloaddition to propylene oxide give corresponding carbonate was explored under mild conditions, at atmospheric pressure carbon dioxide absence cocatalyst added solvent. Various reaction parameters investigated toward optimization exploration substrate scope, revealing up 99% product yields products. Besides, is highly stable, permitting its recyclability reusability further catalytic experiments. significant contributions groups sites within this particularly considered when proposing potential mechanism for reaction. Z-Scan measurements used evaluate (NLO) various laser intensities. A two-photon absorption (TPA) greater incident intensities shows that might be applicable switching devices. self-focusing effects highlighted by index refraction (n2). By reporting characterization along promising NLO behavior, current study introduces additional example growing family metal-organic frameworks.

Язык: Английский

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Design and Advanced Manufacturing of NU‐1000 Metal–Organic Frameworks with Future Perspectives for Environmental and Renewable Energy Applications

Small, Год журнала: 2023, Номер 20(15)

Опубликована: Ноя. 23, 2023

Abstract Metal–organic frameworks (MOFs) represent a relatively new family of materials that attract lots attention thanks to their unique features such as hierarchical porosity, active metal centers, versatility linkers/metal nodes, and large surface area. Among the extended list MOFs, Zr‐based‐MOFs demonstrate comparably superior chemical thermal stabilities, making them ideal candidates for energy environmental applications. As Zr‐MOF, NU‐1000 is first synthesized at Northwestern University. A comprehensive review various approaches synthesis MOFs obtaining properties (e.g., diverse morphologies, area, particular pore size distribution) applications in catalysis (electro‐, photo‐catalysis), CO 2 reduction, batteries, hydrogen storage, gas storage/separation, other fields are presented. The further outlines current challenges development derivatives practical applications, revealing areas future investigation.

Язык: Английский

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