TURKISH JOURNAL OF CHEMISTRY,
Год журнала:
2021,
Номер
45(6)
Опубликована: Сен. 27, 2021
Nanomaterials
have
garnered
the
significant
interest
of
scientists
owing
to
their
technological
as
well
medical
applications.
In
particular,
metal
and
oxide
nanoparticles
gained
prominence
because
enhanced
performance
compared
bulk
counterparts.
Metal-supported
nanomaterials
are
anticipated
make
major
contributions
solving
today's
most
challenging
issues,
like
energy
harvesting
environmental
remediation.
The
incorporation
into
sensors
has
significantly
precision
selectivity.
With
advent
green
chemistry,
synthetic
techniques
been
prioritized
for
synthesis
single
multicomponent
nanomaterials.
current
review,
we
addressed
multidimensional
applications
in
various
sectors,
including
surface
coatings,
biosensing,
remediation,
devices,
construction,
nano
probing,
etc.
This
study
focuses
on
categorization
according
source,
dimensions,
composition,
along
with
exploration
modes.
eco-friendly
cost-effective
greener
route
explored
detail.
Further,
antibacterial
cytotoxic
potential
addressed,
toxicity
analysis
conducted.
signifies
augmented
synthesized
that
can
prove
economically
viable
alternatives
conventional
materials.
Environment International,
Год журнала:
2023,
Номер
178, С. 108106 - 108106
Опубликована: Июль 22, 2023
Concentrations
of
outdoor
ultrafine
particles
(UFP;
<0.1
µm)
and
black
carbon
(BC)
can
vary
greatly
within
cities
long-term
exposures
to
these
pollutants
have
been
associated
with
a
variety
adverse
health
outcomes.This
study
integrated
multiple
approaches
develop
new
models
estimate
within-city
spatial
variations
in
annual
median
(i.e.
average)
UFP
BC
concentrations
as
well
mean
size
Canada's
two
largest
cities,
Montreal
Toronto.We
conducted
year-long
mobile
monitoring
campaigns
each
city
that
included
evenings
weekends.
We
developed
generalized
additive
trained
on
land
use
parameters
deep
Convolutional
Neural
Network
(CNN)
satellite-view
images.
Using
predictions
from
models,
we
final
combined
models.In
Toronto,
the
observed
concentration,
size,
concentration
values
were
16,172pt/cm3,
33.7
nm,
1225
ng/m3,
respectively.
In
Montreal,
14,702pt/cm3,
29.7
1060
For
all
both
proportion
variation
explained
(i.e.,
R2)
was
slightly
greater
(1-2
percentage
points)
for
than
(approximately
10
CNN
models.
The
Toronto
model
R2
test
set
0.73,
0.55,
0.61
concentrations,
0.60,
0.49,
0.60
pollutant,
combined,
CNN,
highly
correlated
other
differences
between
explored
sensitivity
analyses.Predictions
are
available
support
future
epidemiological
research
examining
impacts
UFPs
BC.
Atmospheric Environment X,
Год журнала:
2023,
Номер
19, С. 100221 - 100221
Опубликована: Июль 4, 2023
Identifying
and
quantifying
the
sources
clarifying
impacts
of
ultrafine
particles
(UFP)
in
complicated
urban
environments
are
important
for
particle
pollution
control
UFP-climate
interaction
understanding.
The
previous
studies
have
made
notable
contributions
to
these
aspects
it
is
necessary
review
achievements.
Here,
characteristics
traffic
emissions
new
formation
(NPF)
events/processes
their
effects
on
UFP
summarized
mainly
based
latest
progresses.
constantly
improved
techniques
measuring
played
a
vital
role
knowing
UFP.
Meanwhile,
inventories,
dispersion
models,
receptor
models
generally
perform
better
when
working
together
using
high
resolution
input
corrected
algorithms.
Besides,
between
climate
discussed
by
linking
radiation,
cloud
condensation
nuclei,
deposition,
environmental
conditions
required
nucleation
processes.
Although
UFP,
there
consensuses
that
processes
two
main
interact
via
radiation
nuclei
(CCN),
many
other
crucial
tasks
future
this
work
lists
seven
them.
They
involve,
scientifically,
how
much
such
as
industrial
regional
mix
with
source
primary
pollutants
collaborate
(aerosols)
aerosol-climate
interactions;
engineeringly,
improve
integration
instruments
instrument
customization
services
according
actual
situations.
These
progresses
perspectives
would
help
more
accurately
evaluating
Despite
our
efforts,
knowledge
limited
detailed
solutions
missing
here,
which
need
joint
efforts
from
related
fields.
Environment International,
Год журнала:
2024,
Номер
187, С. 108696 - 108696
Опубликована: Апрель 25, 2024
Ambient
air
ultrafine
particles
(UFP,
with
a
diameter
<100
nm)
have
gained
significant
attention
in
World
Health
Organization
(WHO)
quality
guidelines
and
European
legislation.This
review
explores
UFP
concentrations
particle
number
size
distributions
(PNC-PNSD)
various
transportation
hotspots,
including
road
traffic,
airports,
harbors,
trains,
urban
commuting
modes
(walking,
cycling,
bus,
tram,
subway).The
results
highlight
the
lack
of
information
on
personal
exposure
at
harbors
railway
stations,
inside
airplanes
during
other
modes.The
different
lower
limits
reviewed
measurements
complicate
direct
comparisons
between
them.Emphasizing
use
instruments
detection
≤10
nm,
this
underscores
necessity
following
standardized
measurement
protocols.Road
traffic
sites
are
shown
to
exhibit
highest
PNC
within
cities,
PNSD
driven
by
proximity
weather
conditions.In
closed
environments,
such
as
cars,
buses,
trams,
increased
external
infiltration
for
ventilation
correlates
elevated
shift
toward
smaller
diameters.Airports
particularly
PNCs
near
runways,
raising
potential
concerns
about
occupational
exposure.Recommendations
from
study
include
maintaining
substantial
distance
modes,
integrating
filtration
into
systems,
implementing
lowemission
zones,
advocating
general
reduction
minimize
daily
exposure.Our
findings
provide
important
insights
policy
assessments
underscore
need
additional
research
address
current
knowledge
gaps.
The Science of The Total Environment,
Год журнала:
2023,
Номер
890, С. 164215 - 164215
Опубликована: Май 23, 2023
The
differences
in
the
traffic
fuels
have
been
shown
to
affect
exhaust
emissions
and
their
toxicity.
Especially,
aromatic
content
of
diesel
fuel
is
an
important
factor
considering
emissions,
notably
particulate
matter
(PM)
concentrations.
ultra-fine
particles
(UFP,
with
a
diameter
<100
nm)
are
components
engine
connected
various
health
effects,
such
as
pulmonary
systematic
inflammation,
cardiovascular
disorders.
Studying
toxicity
UFPs
how
different
options
can
be
used
for
mitigating
crucial.
In
present
study,
from
heavy-duty
were
assess
emission
thermophoresis-based
vitro
air-liquid
interface
(ALI)
exposure
system.
aim
study
was
evaluate
potential
effect
20
%
fossil
0
renewable
on
results
show
that
increases
toxicity,
which
seen
increase
genotoxicity,
distinct
inflammatory
responses,
alterations
cell
cycle.
genotoxicity
most
likely
due
PM
phase
exhaust,
exposures
high-efficiency
absorbing
(HEPA)-filtered
resulted
negligible
genotoxicity.
However,
solely
gaseous
still
elicited
immunological
responses.
Overall,
shows
decreasing
could
significant
measure
Environment International,
Год журнала:
2023,
Номер
183, С. 108252 - 108252
Опубликована: Окт. 17, 2023
Understanding
the
atmospheric
processes
involving
carbonaceous
aerosols
(CAs)
is
crucial
for
assessing
air
pollution
impacts
on
human
health
and
climate.
The
sources
formation
mechanisms
of
CAs
are
not
well
understood,
making
it
challenging
to
quantify
in
models.
Studies
suggest
residential
wood
combustion
(RWC)
traffic
significantly
contribute
Europe's
urban
rural
areas.
Here,
we
used
an
chemistry
model
(MONARCH)
three
different
emission
inventories
(two
versions
European-scale
inventory
CAMS-REG_v4
HERMESv3
detailed
national
Spain)
assess
uncertainties
simulation
source
allocation
(from
traffic,
RWC,
shipping,
fires
others)
Northeast
Spain.
For
this,
black
carbon
(BC)
organic
aerosol
(OA)
measurements
performed
at
supersites
representing
environments
(urban,
regional
remote)
were
used.
Our
findings
show
importance
resolution
input
data
accurately
reproducing
BC/OA
observations.
Even
though
emissions
total
particulate
matter
rather
consistent
between
Spain,
found
discrepancies
them
mainly
related
spatiotemporal
disaggregation
(particularly
relevant
RWC)
treatment
condensable
fraction
RWC
(changes
speciation
elemental/organic
carbon).
main
contribution
BC
concentrations
site
accounting
71.1%/65.2%
(January/July)
close
agreement
with
fossil
derived
from
observations
(78.8%/84.2%),
followed
by
(12.8%/3%)
shipping
(5.4%/13.8%).
An
over-representation
(winter)
(summer)
obtained
CAMS-REG_v4.
Noteworthy
arise
OA
results
due
condensables
a
limited
secondary
production
model.
These
offer
insights
into
MONARCH's
effectiveness
simulating
study
highlights
benefits
combining
new
datasets
modeling
techniques
refine
better
understand
mitigate
impacts.
Environmental Pollution,
Год журнала:
2023,
Номер
336, С. 122396 - 122396
Опубликована: Авг. 16, 2023
Ultrafine
particles
(UFP;
particulate
matter
<0.1
μm
in
diameter)
may
be
more
harmful
to
human
health
than
larger
particles,
but
epidemiological
evidence
on
their
effects
is
still
limited.
In
this
study,
we
examined
the
association
between
short-term
exposure
UFP
and
mortality
hospital
admissions
Copenhagen,
Denmark.
Daily
concentrations
of
(measured
as
particle
number
concentration
a
size
range
11-700
nm)
meteorological
variables
were
monitored
at
an
urban
background
station
central
Copenhagen
during
2002-2018.
counts
deaths
from
all
non-accidental
causes,
well
cardiovascular
respiratory
diseases
obtained
Danish
registers.
Mortality
associated
with
interquartile
(IQR)
increase
concurrent
day
up
six
preceding
days
prior
death
or
admission
case-crossover
study
design.
Odds
ratios
(OR)
95%
confidence
intervals
(CI)
per
one
IQR
estimated
after
adjusting
for
temperature
relative
humidity.
We
observed
140,079
total,
236,003
342,074
2002
2018.
Hospital
due
significantly
positively
(OR:
1.04
[95%
CI:
1.01,
1.07],
lag
0-4,
1.02
[1.00,
1.04],
0-1,
respectively).
Among
specific
strongest
associations
found
chronic
obstructive
pulmonary
disease
(COPD)
asthma
two-day
means
(lag
0-1)
1.13
[1.01,
1.26]
1.08
1.16],
respectively,
UFP).
Based
17
years
monitoring
data,
present
novel
findings
showing
that
can
trigger
morbidity
The
COPD
admissions.
Journal of Aerosol Science,
Год журнала:
2023,
Номер
171, С. 106183 - 106183
Опубликована: Апрель 8, 2023
The
Heating,
Ventilation
and
Air
Conditioning
(HVAC)
system
in
an
Operating
Room
(OR)
has
two
main
functions:
evacuate
contaminants
to
guarantee
elevated
Indoor
Quality
(IAQ)
ensure
the
thermal
comfort
of
occupants.
UltraFine
Particles
(UFP)
generated
during
surgical
operation
can
cause
health-related
risks
at
higher
concentrations
if
inhaled
for
a
prolonged
time.
In
this
work,
authors
have
developed
transient
model
simulate
thermofluid
dynamic
conditions,
UFP
transport
inside
OR
equipped
with
Laminar
AirFlow
(LAF)
system.
effects
Change
per
Hour
(ACH)
inlet
area
on
unidirectional
airflow,
concentration
been
studied
here
first
time,
considering
constraints
imposed
by
standards.
An
increase
ACH
above
minimum
value
standards
advantages:
obtaining
both
conditions
staff
very
low
concentrations.
Moreover,
larger
values
airflow
avoid
disruption
caused
plume.
Excessive
do
not
bring
additional
cleanness
OR,
while
increasing
energy
consumption.