Carbon, Год журнала: 2022, Номер 199, С. 87 - 95
Опубликована: Июль 31, 2022
Язык: Английский
Chemical Reviews, Год журнала: 2023, Номер 123(8), С. 5139 - 5219
Опубликована: Апрель 9, 2023
Combustion is a reactive oxidation process that releases energy bound in chemical compounds used as fuels─energy needed for power generation, transportation, heating, and industrial purposes. Because of greenhouse gas local pollutant emissions associated with fossil fuels, combustion science applications are challenged to abandon conventional pathways adapt toward the demand future carbon neutrality. For design efficient, low-emission processes, understanding details relevant transformations essential. Comprehensive knowledge gained from decades fossil-fuel research includes general principles establishing validating reaction mechanisms models, relying on both theory experiments suite analytic monitoring sensing techniques. Such can be advantageously applied extended configure, analyze, control new systems using different, nonfossil, potentially zero-carbon fuels. Understanding impact its links chemistry needs some background. The introduction therefore combines information exemplary cultural technological achievements nature effects emissions. Subsequently, methodology described. A major part devoted followed by discussion selected applications, illustrating future.
Язык: Английский
Процитировано
118
Progress in Energy and Combustion Science, Год журнала: 2023, Номер 96, С. 101076 - 101076
Опубликована: Янв. 28, 2023
Язык: Английский
Процитировано
63
Fuel, Год журнала: 2023, Номер 360, С. 130569 - 130569
Опубликована: Дек. 12, 2023
Язык: Английский
Процитировано
55
Journal of Aerosol Science, Год журнала: 2023, Номер 173, С. 106211 - 106211
Опубликована: Июнь 3, 2023
Combustion and other high-temperature processes can produce solid aerosol nanoparticles with complex morphologies, including fractal-like aggregates of primary particles. Characterizing these as well particle mass, is key to understanding their behavior in natural engineered systems, it provide clues the origin We focus here on characterization soot, although most techniques apply aggregates. A complete description aerosols would include mass morphology every particle. In practice, possible obtain detailed information individual particles from microscopy extracted samples. particular this review, tandem classifier/detector systems determine 2-dimensional mobility distributions that may be interpreted through lens fractal models. Very fast situ light scattering measurements used structure factor, related dimension, aggregate size distributions. These approaches are complementary when there appropriate models connect morphological details optical transport characteristics Over last few decades have become more sophisticated, requiring properties, but also facilitating sophisticated inferences in-situ online measurement techniques.
Язык: Английский
Процитировано
42
Process Safety and Environmental Protection, Год журнала: 2024, Номер 187, С. 332 - 342
Опубликована: Апрель 26, 2024
Язык: Английский
Процитировано
22
Fuel, Год журнала: 2024, Номер 371, С. 132046 - 132046
Опубликована: Июнь 1, 2024
Язык: Английский
Процитировано
21
Proceedings of the Combustion Institute, Год журнала: 2022, Номер 39(1), С. 805 - 823
Опубликована: Дек. 8, 2022
Язык: Английский
Процитировано
39
PNAS Nexus, Год журнала: 2024, Номер 3(2)
Опубликована: Фев. 1, 2024
Nanocluster aerosol (NCA: particles in the size range of 1-3 nm) are a critically important, yet understudied, class atmospheric particles. NCA efficiently deposit human respiratory system and can translocate to vital organs. Due their high surface area-to-mass ratios, associated with heightened propensity for bioactivity toxicity. Despite health relevance NCA, little is known regarding prevalence indoor environments where people spend majority time. In this study, we quantify formation transformation down 1 nm via high-resolution online nanoparticle measurements during propane gas cooking residential building. We observed substantial pool sub-1.5 atmosphere periods, number concentrations often dominated by newly formed NCA. Indoor emission factors reach up ∼10
Язык: Английский
Процитировано
12
ACS Earth and Space Chemistry, Год журнала: 2024, Номер 8(5), С. 798 - 856
Опубликована: Апрель 12, 2024
Acetylene, among the multitude of organic molecules discovered in space, plays a distinct role genesis matter. Characterized by its unique balance stability and reactivity, acetylene is simplest unsaturated molecule known to have triple bond. In addition inherent chemical properties, one most prevalent found across Universe, spanning from icy surfaces planets satellites cold interstellar medium with low temperatures hot circumstellar envelopes where surge several thousand kelvins. These factors collectively position as crucial building block molecular diversification solids present space. This review comprehensively discusses formation expansion carbon skeletons involving acetylene, ranging simple origination first aromatic ring ultimately nanosized particles. Mechanisms pertinent both environments, such envelopes, including clouds planetary atmospheres, are explored. addition, this contemplates synthesis prebiotic molecules. A focus accorded recent advancements future prospects research into catalytic processes molecules, which significant instrument driving evolution complexity Universe. The insights garnered underscore significance astrochemistry potentially contribute our understanding
Язык: Английский
Процитировано
9
The Science of The Total Environment, Год журнала: 2024, Номер 946, С. 174096 - 174096
Опубликована: Июнь 19, 2024
Язык: Английский
Процитировано
8