Toward full ab initio modeling of soot formation in a nanoreactor DOI
Qingzhao Chu, Chenguang Wang, Dongping Chen

et al.

Carbon, Journal Year: 2022, Volume and Issue: 199, P. 87 - 95

Published: July 31, 2022

Language: Английский

Combustion, Chemistry, and Carbon Neutrality DOI Creative Commons
Katharina Kohse‐Höinghaus

Chemical Reviews, Journal Year: 2023, Volume and Issue: 123(8), P. 5139 - 5219

Published: April 9, 2023

Combustion is a reactive oxidation process that releases energy bound in chemical compounds used as fuels─energy needed for power generation, transportation, heating, and industrial purposes. Because of greenhouse gas local pollutant emissions associated with fossil fuels, combustion science applications are challenged to abandon conventional pathways adapt toward the demand future carbon neutrality. For design efficient, low-emission processes, understanding details relevant transformations essential. Comprehensive knowledge gained from decades fossil-fuel research includes general principles establishing validating reaction mechanisms models, relying on both theory experiments suite analytic monitoring sensing techniques. Such can be advantageously applied extended configure, analyze, control new systems using different, nonfossil, potentially zero-carbon fuels. Understanding impact its links chemistry needs some background. The introduction therefore combines information exemplary cultural technological achievements nature effects emissions. Subsequently, methodology described. A major part devoted followed by discussion selected applications, illustrating future.

Language: Английский

Citations

118

Combustion chemistry of aromatic hydrocarbons DOI
Hanfeng Jin, Wenhao Yuan, Wei Li

et al.

Progress in Energy and Combustion Science, Journal Year: 2023, Volume and Issue: 96, P. 101076 - 101076

Published: Jan. 28, 2023

Language: Английский

Citations

63

Effects of ammonia addition on soot formation in hydrocarbon fuels combustion: Challenges and prospects DOI
Huaqiang Chu,

Shunjie Feng,

Run Hong

et al.

Fuel, Journal Year: 2023, Volume and Issue: 360, P. 130569 - 130569

Published: Dec. 12, 2023

Language: Английский

Citations

55

Overview of methods to characterize the mass, size, and morphology of soot DOI Creative Commons
Timothy A. Sipkens, Adam Boies, Joel C. Corbin

et al.

Journal of Aerosol Science, Journal Year: 2023, Volume and Issue: 173, P. 106211 - 106211

Published: June 3, 2023

Combustion and other high-temperature processes can produce solid aerosol nanoparticles with complex morphologies, including fractal-like aggregates of primary particles. Characterizing these as well particle mass, is key to understanding their behavior in natural engineered systems, it provide clues the origin We focus here on characterization soot, although most techniques apply aggregates. A complete description aerosols would include mass morphology every particle. In practice, possible obtain detailed information individual particles from microscopy extracted samples. particular this review, tandem classifier/detector systems determine 2-dimensional mobility distributions that may be interpreted through lens fractal models. Very fast situ light scattering measurements used structure factor, related dimension, aggregate size distributions. These approaches are complementary when there appropriate models connect morphological details optical transport characteristics Over last few decades have become more sophisticated, requiring properties, but also facilitating sophisticated inferences in-situ online measurement techniques.

Language: Английский

Citations

42

Screening nano additives for favorable NOx/smoke emissions trade-off in a CRDI diesel engine fueled by industry leather waste fat biodiesel blend DOI

N. Mohanrajhu,

S. Sekar,

Ravikumar Jayabal

et al.

Process Safety and Environmental Protection, Journal Year: 2024, Volume and Issue: 187, P. 332 - 342

Published: April 26, 2024

Language: Английский

Citations

22

Recent advances in soot formation mechanisms: Oxidation and oxidation-induced fragmentation DOI
Huaqiang Chu,

Run Hong,

Wenlong Dong

et al.

Fuel, Journal Year: 2024, Volume and Issue: 371, P. 132046 - 132046

Published: June 1, 2024

Language: Английский

Citations

21

Modeling soot formation in flames and reactors: Recent progress and current challenges DOI
Murray J. Thomson

Proceedings of the Combustion Institute, Journal Year: 2022, Volume and Issue: 39(1), P. 805 - 823

Published: Dec. 8, 2022

Language: Английский

Citations

39

Dynamics of nanocluster aerosol in the indoor atmosphere during gas cooking DOI Creative Commons
Satya S. Patra, Jinglin Jiang, Xiaosu Ding

et al.

PNAS Nexus, Journal Year: 2024, Volume and Issue: 3(2)

Published: Feb. 1, 2024

Nanocluster aerosol (NCA: particles in the size range of 1-3 nm) are a critically important, yet understudied, class atmospheric particles. NCA efficiently deposit human respiratory system and can translocate to vital organs. Due their high surface area-to-mass ratios, associated with heightened propensity for bioactivity toxicity. Despite health relevance NCA, little is known regarding prevalence indoor environments where people spend majority time. In this study, we quantify formation transformation down 1 nm via high-resolution online nanoparticle measurements during propane gas cooking residential building. We observed substantial pool sub-1.5 atmosphere periods, number concentrations often dominated by newly formed NCA. Indoor emission factors reach up ∼10

Language: Английский

Citations

12

Role of Acetylene in the Chemical Evolution of Carbon Complexity DOI
Evgeniy O. Pentsak, M. S. Murga, Valentine P. Ananikov

et al.

ACS Earth and Space Chemistry, Journal Year: 2024, Volume and Issue: 8(5), P. 798 - 856

Published: April 12, 2024

Acetylene, among the multitude of organic molecules discovered in space, plays a distinct role genesis matter. Characterized by its unique balance stability and reactivity, acetylene is simplest unsaturated molecule known to have triple bond. In addition inherent chemical properties, one most prevalent found across Universe, spanning from icy surfaces planets satellites cold interstellar medium with low temperatures hot circumstellar envelopes where surge several thousand kelvins. These factors collectively position as crucial building block molecular diversification solids present space. This review comprehensively discusses formation expansion carbon skeletons involving acetylene, ranging simple origination first aromatic ring ultimately nanosized particles. Mechanisms pertinent both environments, such envelopes, including clouds planetary atmospheres, are explored. addition, this contemplates synthesis prebiotic molecules. A focus accorded recent advancements future prospects research into catalytic processes molecules, which significant instrument driving evolution complexity Universe. The insights garnered underscore significance astrochemistry potentially contribute our understanding

Language: Английский

Citations

9

Effects of different ammonia energy ratio on soot formation and oxidation in an ammonia diesel dual-fuel engine DOI
Xiaofeng Wang,

Taifeng Shi,

Shouying Jin

et al.

The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 946, P. 174096 - 174096

Published: June 19, 2024

Language: Английский

Citations

8