Chemical Society Reviews, Год журнала: 2020, Номер 49(16), С. 5945 - 6001
Опубликована: Янв. 1, 2020
Diverse functional potential of heterometallic systems based on octacyanidometallates places them at the forefront research into modern molecule-based materials.
Язык: Английский
Nature Communications, Год журнала: 2022, Номер 13(1)
Опубликована: Дек. 24, 2022
Molecular recognition is an attractive approach to designing sensitive and selective sensors for volatile organic compounds (VOCs). Although macrocycles cages have been well-developed recognising organics by their adaptive pockets in liquids, porous solids gas detection require a deliberate design balancing adaptability robustness. Here we report dynamic 3D covalent framework (dynaCOF) constructed from environmentally fluorophore that can undergo concerted structural transitions upon adsorption of vapours. The COF capable rapid reliable various VOCs, even non-polar hydrocarbon under humid conditions. guest inclusion amplifies the host-guest interactions facilitates differentiation vapours polarity sizes/shapes, covalently linked interwoven networks ensure robustness coherency materials. present result paves way multiplex fluorescence sensing VOCs with molecular-specific responses.
Язык: Английский
Процитировано
69
Coordination Chemistry Reviews, Год журнала: 2024, Номер 507, С. 215717 - 215717
Опубликована: Март 5, 2024
Язык: Английский
Процитировано
39
Chemical Reviews, Год журнала: 2024, Номер 124(9), С. 5930 - 6050
Опубликована: Апрель 30, 2024
Since the last century, we have witnessed development of molecular magnetism which deals with magnetic materials based on species, i.e., organic radicals and metal complexes. Among them, broadest attention was devoted to molecule-based ferro-/ferrimagnets, spin transition materials, including those exploring electron transfer, nanomagnets, such as single-molecule magnets (SMMs), qubits, stimuli-responsive materials. Their physical properties open application horizons in sensors, data storage, spintronics, quantum computation. It found that various optical phenomena, thermochromism, photoswitching characteristics, luminescence, nonlinear chiroptical effects, well responsivity external stimuli, can be implemented into Moreover, fruitful interactions these effects provide new cross-effects multifunctionality, enriching applications optical, electronic, devices. This Review aims show scope phenomena generated recent advances areas high-temperature photomagnetism, thermometry utilizing SMMs, addressability magneto-chiral dichroism, opto-magneto-electric multifunctionality. These findings are discussed context types accessible for classes
Язык: Английский
Процитировано
32
Chemical Society Reviews, Год журнала: 2024, Номер 53(13), С. 6992 - 7090
Опубликована: Янв. 1, 2024
Globally, 91% of plant production encounters diverse environmental stresses. Fluorescent chemosensors are effective for monitoring health and environment that promotes the development sustainable agriculture.
Язык: Английский
Процитировано
17
Chemical Society Reviews, Год журнала: 2020, Номер 49(16), С. 5945 - 6001
Опубликована: Янв. 1, 2020
Diverse functional potential of heterometallic systems based on octacyanidometallates places them at the forefront research into modern molecule-based materials.
Язык: Английский
Процитировано
125