Sustainable and scalable one-pot synthesis of diaryliodonium salts
Chemical Communications,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
Two
one-pot
syntheses
of
diaryliodonium
triflates
are
presented,
rendering
the
production
these
electrophilic
arylating
agents
more
sustainable.
Язык: Английский
Transition-Metal-Free C-Diarylations to Reach All-Carbon Quaternary Centers
JACS Au,
Год журнала:
2024,
Номер
4(8), С. 2832 - 2837
Опубликована: Авг. 5, 2024
Herein,
we
disclose
a
convenient
protocol
for
the
α-diarylation
of
carbon
nucleophiles
to
yield
heavily
functionalized
quaternary
products.
Diaryliodonium
salts
are
utilized
transfer
both
aryl
groups
under
transition-metal-free
conditions,
which
enables
an
atom-efficient
and
high-yielding
method
with
broad
functional
group
tolerance.
The
methodology
is
amenable
wide
variety
can
be
in
late-stage
functionalization
complex
arenes.
Furthermore,
it
compatible
new
class
zwitterionic
iodonium
reagents,
gives
access
phenols
Язык: Английский
Synthesis of Diaryl Ethers via Hypervalent Iodine-Mediated C–H Functionalization
Chenghu Hu,
Qi Jia,
Wenjing Bao
и другие.
Organic Letters,
Год журнала:
2024,
Номер
26(37), С. 7864 - 7868
Опубликована: Сен. 9, 2024
A
hypervalent
iodine-reagent-based
C-H
functionalization
strategy
was
utilized
to
synthesize
diaryl
ethers.
This
method
directly
transforms
various
arenes
into
their
corresponding
diaryliodonium
salts,
followed
by
a
C-O
coupling
reaction
produce
structurally
diverse
The
efficacy
of
this
approach
in
the
late-stage
structural
modifications
complex
molecules
demonstrated.
Язык: Английский