Applied Organometallic Chemistry,
Год журнала:
2024,
Номер
39(1)
Опубликована: Окт. 9, 2024
ABSTRACT
A
new
Schiff
base
ligand,
HNMPC
,
was
prepared
and
reacted
with
some
metal
ions,
including
Cu(II),
Ni(II),
Co(II),
Mn(II),
VO(IV).
The
infrared,
electronic,
mass,
electron
spin
resonance,
nuclear
magnetic
thermal
elemental
analysis,
molar
conductance,
susceptibility
measurements
were
used
to
characterize
the
complexes.
ligand
acts
as
a
monoanionic
tridentate
ONO
donor
in
all
complexes,
coordinating
sites
are
C=O
pyridone
C=N,
phenolate
anion.
All
complexes
exhibit
octahedral
configurations,
results
showed
that
ion:ligand
ratio
1:2.
molecular
structural
parameters
of
its
determined
based
on
DFT
level
implemented
Gaussian
09
program
B3LYP/GENECP
method
at
6‐311G(d,p)
basis
set
for
C,
H,
N,
O
atoms
SDD
(Stuttgart/Dresden)
atoms.
theoretical
data
correlated
experimental
results.
Gram‐positive
bacteria,
Gram‐negative
yeast,
fungi
test
current
compounds'
antimicrobial
activity.
Investigating
antitumor
activity
against
HepG2
cell
lines
encouraging
IC
50
values
par
those
cisplatin
.
In
order
determine
affinity
binding
pattern
synthesized
compounds
toward
VEGFR‐2
active
site,
docking
studies
conducted,
data.
Based
obtained
results,
future
work
aimed
synthesize
category
bases
their
derived
from
aminopyridine
derivative
diverse
aldehydes
ketones.
The
development
of
different
concept
approaches
and
user-friendly
carbonyl
surrogates
for
aminocarbonylation
is
highly
desirable.
Herein,
we
report
the
photocatalytic
enaminones
with
easily
available
o-aminobenzamides
CF2Br2
through
an
oxygen
migration-defluorination
strategy.
reaction
features
switchable
transformation
construction
carbamoyl-substituted
enol
products
allows
expedient
synthesis
fully
substituted
maleimides
under
mild
conditions.
Organic Chemistry Frontiers,
Год журнала:
2023,
Номер
11(3), С. 895 - 915
Опубликована: Дек. 20, 2023
Photoinduced
radical–polar
crossover
cyclization
(RPCC)
of
bifunctional
alkenes
is
high
synthetic
utility
to
produce
cyclic
products
with
precise
alkene
design.
This
review
summarizes
the
recent
representative
advances
in
field
RPC.
Organic Letters,
Год журнала:
2024,
Номер
26(12), С. 2511 - 2516
Опубликована: Март 20, 2024
This
work
demonstrates
the
synthesis
of
a
variety
perfluoroalkyl
heterocycles
via
visible-light-driven
radical-polar
crossover
cyclization
strategy.
In
this
process,
single-electron
reduction/SNV-type/cyclization
sequences
follow
radical
addition
reaction
diazoester,
which
differs
from
current
role
diazoesters
as
precursors/acceptors.
transformation
excellent
functional
group
compatibility
and
allows
for
modification
many
bioactive
molecules
with
diazoesters.
Such
could
represent
novel
approach
to
photochemical
diazo
compounds.
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
89(4), С. 2505 - 2515
Опубликована: Фев. 5, 2024
A
novel
iodine-promoted
difunctionalization
of
α-C
sites
in
enaminones
was
demonstrated
as
a
means
synthesizing
variety
fully
substituted
thiazoles
by
constructing
C–C(CO),
C–S,
and
C–N
bonds.
This
transformation
allows
the
realization
unusual
aryl
C2
synthons
simultaneously
thioylation
dicarbonylation
sites.
preliminary
mechanistic
study
performed
indicated
that
cleavage
C═C
bonds
involves
bicyclization/ring-opening
oxidative
coupling
sequence.
Green Chemistry,
Год журнала:
2024,
Номер
26(7), С. 4199 - 4208
Опубликована: Янв. 1, 2024
A
new
photoelectrocatalytic
mode
permits
the
synthesis
of
polycyclic
pyrimidin-4-ones
through
dehydrogenative
cyclization
malonates
with
unactivated
alkenes.
