Environmental Technology & Innovation,
Год журнала:
2022,
Номер
29, С. 102972 - 102972
Опубликована: Ноя. 25, 2022
With
the
advance
of
society
and
industrialization,
a
large
number
organic
inorganic
pollutants
in
water
cause
harm
to
humans
environment.
Therefore,
development
effective
pollutant
removal
methods
materials
is
urgently
needed.
Porous
polymers
(POPs)
are
emerging
porous
formed
by
polymerization
different
structured
building
blocks.
Adjustable
pore
size
structure,
specific
surface
area,
high
porosity
for
POPs
provide
platform
study
water.
The
thermal
stability
insoluble
skeleton
make
them
highly
stable
water,
not
easily
decomposed,
produce
secondary
degradation
products.
Porphyrins
have
conjugation
systems
their
molecular
centers
strongly
coordinated
with
metal
ions,
which
been
widely
studied
applied
recent
years.
Porphyrin
(Py-POPs)
combine
advantages
porphyrins
photosensitivity.
Based
on
above,
researchers
enthusiastically
working
Py-POPs.
In
this
review,
we
summarized
research
progress
Py-POPs
Firstly,
introduced
structures
linkage
bonds
that
up
preparation
Then
application
field
adsorption
green
photocatalytic
was
presented.
Finally,
prospects
challenges
further
were
discussed.
Advanced Functional Materials,
Год журнала:
2020,
Номер
30(27)
Опубликована: Апрель 29, 2020
Abstract
Covalent
organic
frameworks
(COFs)
are
an
emerging
class
of
crystalline
polymers
with
well‐defined
molecular
geometry
and
tunable
porosity.
COFs
formed
via
reversible
condensation
lightweight
building
blocks,
which
dictate
its
in
two
or
three
dimensions.
Among
COFs,
2D
have
garnered
special
attention
due
to
their
unique
structure
composed
two‐dimensionally
extended
sheets
stacked
layers
generating
periodic
columnar
π‐arrays,
functional
pore
space,
ease
synthesis.
These
features
combination
low
density,
high
crystallinity,
large
surface
area,
biodegradability
made
them
excellent
candidate
for
a
plethora
applications
ranging
from
energy
biomedical
sciences.
In
this
article,
the
evolution
is
briefly
discussed
terms
different
types
chemical
linkages,
synthetic
strategies
bulk
nanoscale
tunability
perspective.
Next,
specifically
drug
delivery,
phototherapy,
biosensing,
bioimaging,
biocatalysis,
antibacterial
activity
summarized.
addition,
current
challenges
approaches
designing
advanced
discussed.
Chemical Society Reviews,
Год журнала:
2022,
Номер
51(15), С. 6307 - 6416
Опубликована: Янв. 1, 2022
This
review
highlights
the
recent
advances
of
metalated
covalent
organic
frameworks,
including
synthetic
strategies
and
applications,
discusses
current
challenges
future
directions.
Chemistry - A European Journal,
Год журнала:
2020,
Номер
26(29), С. 6402 - 6422
Опубликована: Март 6, 2020
Metal-organic
framework
(MOF)
and
covalent
organic
(COF)
nanosheets
are
a
new
type
of
two-dimensional
(2D)
materials
with
unique
design
principles
various
synthesis
methods.
They
considered
ideal
electrochemical
devices
due
to
the
ultrathin
thickness,
easily
tunable
molecular
structure,
large
porosity
other
properties.
There
two
common
methods
synthesize
2D
MOF/COF
nanosheets:
bottom-up
top-down.
The
top-down
strategy
mainly
includes
ultrasonic
assisted
exfoliation,
exfoliation
mechanical
exfoliation.
Another
interface
synthesis,
modulation
surfactant-assisted
synthesis.
In
this
Review,
development
in
field
electrochemistry
(supercapacitors,
batteries,
oxygen
reduction,
hydrogen
evolution)
is
introduced,
their
dimensional
advantages
highlighted.
ACS Nano,
Год журнала:
2023,
Номер
17(3), С. 1879 - 1905
Опубликована: Янв. 30, 2023
Covalent
organic
frameworks
(COFs)
are
a
type
of
crystalline
porous
material
with
specific
features
and
interesting
structures,
including
porosity,
large
surface
area,
biocompatibility.
These
enable
COFs
to
be
considered
as
excellent
candidates
for
applications
in
various
fields.
Recently,
have
been
widely
demonstrated
promising
materials
biomedical
because
their
physicochemical
properties
ultrathin
structures.
In
this
review,
we
cover
the
recent
progress
COF
photodynamic
therapy,
gene
delivery,
photothermal
drug
bioimaging,
biosensing,
combined
therapies.
Moreover,
critical
challenges
further
perspectives
regards
future
biology-facing
also
discussed.
Chemistry - A European Journal,
Год журнала:
2019,
Номер
26(25), С. 5583 - 5591
Опубликована: Дек. 27, 2019
As
newly
emerged
crystalline
porous
materials,
covalent
organic
frameworks
(COFs)
possess
fascinating
structures
and
some
specific
features
such
as
modularity,
crystallinity,
porosity,
stability,
versatility,
biocompatibility.
Besides
adsorption/separation,
sensing,
catalysis,
energy
applications,
COFs
have
recently
shown
a
promise
in
biomedical
applications.
This
contribution
provides
an
overview
of
the
recent
developments
COF-based
medicines
cancer
therapeutics,
including
drug
delivery,
photodynamic
therapy
(PDT),
photothermal
(PTT),
combined
therapy.
Furthermore,
major
challenges
developing
trends
this
field
are
also
discussed.
These
summarized
discussed
to
help
encourage
further
contributions
emerging
promising
field.
Chemical Society Reviews,
Год журнала:
2021,
Номер
50(23), С. 12883 - 12896
Опубликована: Янв. 1, 2021
Finding
a
personalized
nano
theranostics
solution,
nanomedicine
for
cancer
diagnosis
and
therapy,
is
among
the
top
challenges
of
current
medicinal
science.
Porous
organic
polymers
(POPs)
are
permanent
porous
materials
prepared
by
linking
relatively
rigid
multidimensional
building
blocks.
POP
nanoparticles
have
remarkable
advantage
owing
to
their
specific
physicochemical
characteristics
such
as
high
surface
area,
convincing
pore
size
engineering,
stimuli-responsive
degradability,
negligible
toxicity,
open
covalent
post-synthesis
modification
possibilities
etc.
POPs
crystalline
non-crystalline
characteristics;
popularly
known
frameworks
(COFs),
shown
potential
application
across
research
areas
in
The
early
development
on
applications
nanoscale
has
tremendous
future
clinical
translation.
This
tutorial
review
highlights
recently
developed
promising
nPOPs
drug
loading,
targeted
delivery,
endogenous
exogenous
release,
imaging
combination
regardless
poorly
properties.
will
provide
platform
translation
solving
fundamental
nanomedicines
loading
efficiency,
size-optimization,
biocompatibility,
dispersibility
cell
uptake
ability.
Sustainability,
Год журнала:
2023,
Номер
15(14), С. 10891 - 10891
Опубликована: Июль 11, 2023
Nanomaterials
have
gained
significant
attention
as
a
remarkable
class
of
materials
due
to
their
unique
properties
and
the
fact
that
they
encompass
wide
range
samples
with
at
least
one
dimension
ranging
from
1
100
nm.
The
deliberate
design
nanoparticles
enables
achievement
extremely
large
surface
areas.
In
field
cost-effective
electrochemical
devices
for
energy
storage
conversion
applications,
nanomaterials
emerged
key
area
research.
Their
exceptional
physical
chemical
led
extensive
investigations
aimed
improving
performance
cost-effectiveness
devices,
including
batteries,
supercapacitors,
fuel
cells.
continuous
development
enhancement
these
high-performance
are
driven
by
demand
enhanced
productivity,
connectivity,
sustainability
reduced
cost.
This
review
focuses
on
electrodes,
storage,
sensors
(ES)
based
nanotechnology.
It
discusses
application
nanotechnology
in
electrochemistry
water
purification
fate
substances
water,
while
also
introducing
green
cost-effective,
high-fidelity
product
creation
through
methods.
study
emphasizes
synthesis
novel
nanomaterials,
such
metal–organic
frameworks
(MOFs),
covalent
organic
(COFs),
MXenes,
applications
devices.
Furthermore,
it
explores
integration
nanostructures
systems
economically
future
along
challenges
faced
nanotechnology-based
industries.
paper
interplay
between
biosensors,
which
play
vital
role
Overall,
this
provides
comprehensive
overview
significance
conversion.
highlights
need
further
research
rapidly
evolving
serves
valuable
resource
researchers
engineers
interested
latest
advancements
