Interfacial catalysis of metal-oxide nanocatalysts in CO2 hydrogenation to value-added C1 chemicals DOI Creative Commons
Ziwei Wang, Zhenhua Zhang

Surface Science and Technology, Год журнала: 2023, Номер 1(1)

Опубликована: Окт. 12, 2023

Abstract Catalytic CO 2 hydrogenation to valuable chemicals is an excellent approach address the increasingly serious “greenhouse effect” caused by emission generated from utilizations of nonrenewable fossil energies, while such a process limited chemical inertia and thermal stability molecule complex routes. In this review, we first summarized recent progresses metal-oxide nanocatalysts considered as category most promising catalysts in value-added C1 including CH 4 /CO, formic acid/formate, methanol. These studies involve with different structural factors affecting interfacial catalysis structures both metals (type, particle size, morphology/crystal plane, bimetal alloy) supports crystal phase, composite) their (strong) metal-support interactions so identify key factor determining reaction activity, product selectivity, catalytic hydrogenation. Finally, further discuss challenging coupling future research opportunities for tunable conversion.

Язык: Английский

Ni Single Atoms Confined in Nitrogen-Doped Carbon Nanotubes for Active and Selective Hydrogenation of CO2 to CO DOI
Dongdong Wang,

Zhenxuan Yuan,

Xi‐Lin Wu

и другие.

ACS Catalysis, Год журнала: 2023, Номер 13(10), С. 7132 - 7138

Опубликована: Май 11, 2023

Developing efficient non-precious-metal catalysts capable of selectively converting CO2 into fuels and chemicals is desirable yet remains a challenge. Ni-based usually exhibit high activity in methanation reactions but low selectivity stability the reverse water-gas shift (RWGS) reaction. Herein, we report Ni single-atom catalyst with Ni–Nx motifs confined N-doped carbon nanotubes as an active, selective, stable for RWGS reaction, achieving almost 100% CO STY 1.88 molCO gNi–1 h–1 at 500 °C atmospheric pressure. In addition to weak adsorption, strong adsorption H2 active site were found be responsible catalytic selectivity.

Язык: Английский

Процитировано

30
Tuning the CO2 Hydrogenation Activity and Selectivity by Highly Dispersed Ni–In Intermetallic Alloy Compounds DOI

Changxuan Zhang,

Peng Li, Zhourong Xiao

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2023, Номер 12(1), С. 166 - 177

Опубликована: Дек. 18, 2023

Reverse water–gas shift (RWGS) reaction is considered as an effective solution for conversion of greenhouse gas the CO2 to CO, but it still suffers from relatively low activity and selectivity at temperatures. Herein, we report catalytic performance mechanism NiInx/SBA-15 with different Ni In (indium) molar ratios RWGS a temperature. The results showed that increment In/Ni ratio in intermetallic alloy compounds (IMCs) inhibits CO* adsorption through "active site isolation" effect, thus improving CO. terms In–Ni IMCs, acts active center isolated by atoms hydrogenation reaction. XRD HRTEM formed IMC were highly dispersed on large surface area SBA-15. It was also demonstrated H2-TPR addition enhanced interaction between support, stability catalyst good anti-sintering. Meanwhile, aggregation charge density obtained additives, verified XPS DFT simulation. After optimizing ratio, NiIn0.5/SBA-15 exhibited 29% 400 °C, 0.1 MPa, 24,000 mL/gcat·h, CO over 99% production rate about 47 mmol/gcat·h, which superior those most reported nickel-based catalysts. At same time, long-time maintained well after 25 h situ DRIFTS reveals change intermediates HCOO* COOH* during activation introduction In, leading rapid desorption avoiding further form CH4, can be CO-TPD. Ni–In IMCs weak capacity are main reason achieving high

Язык: Английский

Процитировано

28
Layered double hydroxides-based metal nanocatalysts: Confinement engineering, microenvironment effect and applications in catalytic conversion of biomass DOI

Jun Wu,

Yuhang Xie, Yong Li

и другие.

Coordination Chemistry Reviews, Год журнала: 2023, Номер 497, С. 215437 - 215437

Опубликована: Сен. 26, 2023

Язык: Английский

Процитировано

27
Recent Advances in Hydrogenation of CO2 to CO with Heterogeneous Catalysts Through the RWGS Reaction DOI
Wenting Zhang, Jiashu Sun, Hongli Wang

и другие.

Chemistry - An Asian Journal, Год журнала: 2024, Номер 19(4)

Опубликована: Янв. 27, 2024

Abstract With the continuous increase in CO 2 emissions, primarily from combustion of coal and oil, ecosystem faces a significant threat. Therefore, as an effective method to minimize issue, Reverse Water Gas Shift (RWGS) reaction which converts towards attracts much attention, is environmentally‐friendly mitigate climate change lessen dependence on fossil fuels. Nevertheless, inherent thermodynamic stability kinetic inertness big challenge under mild conditions. In addition, it remains another fundamental RWGS owing selectivity issue caused by further hydrogenation CH 4 . Up till now, series catalysis systems have been developed for reduction produce CO. Herein, research progress well‐performed heterogeneous catalysts were summarized, including catalyst design, catalytic performance mechanism. This review will provide insights into efficient utilization promote development reaction.

Язык: Английский

Процитировано

16
Experimental and theoretical study of Pd-Pt/In2O3 bimetallic catalysts for enhancing methanol production from CO2 DOI
J.B. Guo, Zhenyu Wang, Tongtong Gao

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 483, С. 149370 - 149370

Опубликована: Фев. 4, 2024

Язык: Английский

Процитировано

14
Oxygen vacancy engineering in MOF-derived AuCu/ZnO bimetallic catalysts for methanol synthesis via CO2 hydrogenation DOI
Guiming Xie,

Xingyang Bai,

Fei Yu

и другие.

Catalysis Today, Год журнала: 2024, Номер 434, С. 114702 - 114702

Опубликована: Апрель 5, 2024

Язык: Английский

Процитировано

12
Comprehensive Insight into External Field‐Driven CO2 Reduction to CO: Recent Progress and Future Prospects DOI Open Access
Zhourong Xiao, Hui Zhang,

Xinyi Tan

и другие.

Advanced Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Март 19, 2025

Abstract Currently, thermal catalysis is the predominant method for achieving reverse water–gas shift (RWGS) reaction reduction of carbon dioxide (CO 2 ) to monoxide (CO), which a crucial intermediate in synthesis other high value‐added chemicals via Fischer–Tropsch synthesis. To extend applicability CO RR) CO, researchers have explored RR that utilizes external fields addition fields. This review commences by providing an overview research background pertinent and then primary mechanisms potential pathways associated with process are summarized. Furthermore, impact various fields, including traditional light photothermal coupling solar thermochemical laser electric photoelectric electromagnetic plasma on investigated. Finally, summary future perspectives as influenced presented. It anticipated this will provide valuable insights focused preparation high‐value‐added through enhanced

Язык: Английский

Процитировано

2
Shape dependency of CO2 hydrogenation on ceria supported singly dispersed Ru catalysts DOI
Z. H. An,

Nan Ma,

Yuanjie Xu

и другие.

Journal of Catalysis, Год журнала: 2023, Номер 429, С. 115245 - 115245

Опубликована: Дек. 5, 2023

Язык: Английский

Процитировано

23
Enhanced catalytic stability and structural evolution of Rh-BN interface in dry reforming of methane under intensified CO2 partial pressure DOI
Yuanjie Xu,

Zemin An,

Xin Yu

и другие.

Journal of Catalysis, Год журнала: 2023, Номер 427, С. 115094 - 115094

Опубликована: Авг. 10, 2023

Язык: Английский

Процитировано

22
Antiover-Reduction of Ni/In2O3 Nanocatalysts by Atomic Layer Deposition of Al2O3 Films for Durable CO2 Hydrogenation to Methanol DOI

Yanmei Cai,

Cun‐biao Lin,

Xingwen Cha

и другие.

ACS Catalysis, Год журнала: 2024, Номер 14(11), С. 8463 - 8479

Опубликована: Май 16, 2024

The supported Ni/In2O3 catalysts are of great interest in CO2 hydrogenation, but the formation In0 or Ni–In alloy phases due to over-reduction would lead rapid catalyst deactivation. Herein, thin Al2O3 films were deposited on surface by atomic layer deposition (ALD) as an antireduction agent, which enables In2O3 maintain a significant abundance active In3+ species even during high-temperature H2 treatment (400 °C, 2 h), thereby effectively resisting deactivation caused In2O3. Various characterization methods confirm antiover-reduction effect ALD-Al2O3 films, namely, inhibiting and In3Ni2 alloys facilitating reoxidation low-valence In form In2O3–x phase presence atmosphere. As treated with at 400 5Al2O3/Ni/In2O3-R400 exhibited STYMeOH 7.39 gMeOH h–1gNi–1 methanol selectivity 64% (reaction conditions: 3 MPa, 300 12,000 mL gcat–1h–1). Particularly, increased 11.5 times compared that Ni/In2O3-R400 without coating (0.59 h–1gNi–1). Density functional theory (DFT) calculations validate effectiveness specific charge transfer tendencies suppressing high-valence species. Through analysis crystal orbital Hamilton population (COHP) projected density states (PDOS) electronic structures adsorbate species, Al2O3/Ni/In2O3 is shown significantly enhance activation further catalytic reactions. Accordingly, this study unveils mechanism In2O3-based provides method regulate their reduction level depositing catalysts.

Язык: Английский

Процитировано

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