Mechanism of sulfur-guided CO2 selective hydrogenation through modulation of surface intermediate over Ni/ZrO2 catalysts DOI
Yunhao Zang, Ziyi Zhang, Yan Wang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148553 - 148553

Published: Jan. 4, 2024

Language: Английский

Tuning the CO2 Hydrogenation Activity and Selectivity by Highly Dispersed Ni–In Intermetallic Alloy Compounds DOI

Changxuan Zhang,

Peng Li, Zhourong Xiao

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 12(1), P. 166 - 177

Published: Dec. 18, 2023

Reverse water–gas shift (RWGS) reaction is considered as an effective solution for conversion of greenhouse gas the CO2 to CO, but it still suffers from relatively low activity and selectivity at temperatures. Herein, we report catalytic performance mechanism NiInx/SBA-15 with different Ni In (indium) molar ratios RWGS a temperature. The results showed that increment In/Ni ratio in intermetallic alloy compounds (IMCs) inhibits CO* adsorption through "active site isolation" effect, thus improving CO. terms In–Ni IMCs, acts active center isolated by atoms hydrogenation reaction. XRD HRTEM formed IMC were highly dispersed on large surface area SBA-15. It was also demonstrated H2-TPR addition enhanced interaction between support, stability catalyst good anti-sintering. Meanwhile, aggregation charge density obtained additives, verified XPS DFT simulation. After optimizing ratio, NiIn0.5/SBA-15 exhibited 29% 400 °C, 0.1 MPa, 24,000 mL/gcat·h, CO over 99% production rate about 47 mmol/gcat·h, which superior those most reported nickel-based catalysts. At same time, long-time maintained well after 25 h situ DRIFTS reveals change intermediates HCOO* COOH* during activation introduction In, leading rapid desorption avoiding further form CH4, can be CO-TPD. Ni–In IMCs weak capacity are main reason achieving high

Language: Английский

Citations

25
Recent Advances in Hydrogenation of CO2 to CO with Heterogeneous Catalysts Through the RWGS Reaction DOI
Wenting Zhang, Jiashu Sun, Hongli Wang

et al.

Chemistry - An Asian Journal, Journal Year: 2024, Volume and Issue: 19(4)

Published: Jan. 27, 2024

Abstract With the continuous increase in CO 2 emissions, primarily from combustion of coal and oil, ecosystem faces a significant threat. Therefore, as an effective method to minimize issue, Reverse Water Gas Shift (RWGS) reaction which converts towards attracts much attention, is environmentally‐friendly mitigate climate change lessen dependence on fossil fuels. Nevertheless, inherent thermodynamic stability kinetic inertness big challenge under mild conditions. In addition, it remains another fundamental RWGS owing selectivity issue caused by further hydrogenation CH 4 . Up till now, series catalysis systems have been developed for reduction produce CO. Herein, research progress well‐performed heterogeneous catalysts were summarized, including catalyst design, catalytic performance mechanism. This review will provide insights into efficient utilization promote development reaction.

Language: Английский

Citations

16
LaCoO3 supported Pt for efficient photo-thermal catalytic reverse water-gas shift via the Mott-Schottky effect DOI
Hui Zhang, Zhourong Xiao, Peng Li

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 350, P. 127998 - 127998

Published: May 19, 2024

Language: Английский

Citations

16
Experimental and theoretical study of Pd-Pt/In2O3 bimetallic catalysts for enhancing methanol production from CO2 DOI
J.B. Guo, Zhenyu Wang, Tongtong Gao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 483, P. 149370 - 149370

Published: Feb. 4, 2024

Language: Английский

Citations

13
Oxygen vacancy engineering in MOF-derived AuCu/ZnO bimetallic catalysts for methanol synthesis via CO2 hydrogenation DOI
Guiming Xie,

Xingyang Bai,

Fei Yu

et al.

Catalysis Today, Journal Year: 2024, Volume and Issue: 434, P. 114702 - 114702

Published: April 5, 2024

Language: Английский

Citations

11
Layered double hydroxides-based metal nanocatalysts: Confinement engineering, microenvironment effect and applications in catalytic conversion of biomass DOI

Jun Wu,

Yuhang Xie, Yong Li

et al.

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 497, P. 215437 - 215437

Published: Sept. 26, 2023

Language: Английский

Citations

21
Shape dependency of CO2 hydrogenation on ceria supported singly dispersed Ru catalysts DOI
Z. H. An,

Nan Ma,

Yuanjie Xu

et al.

Journal of Catalysis, Journal Year: 2023, Volume and Issue: 429, P. 115245 - 115245

Published: Dec. 5, 2023

Language: Английский

Citations

20
Enhanced catalytic stability and structural evolution of Rh-BN interface in dry reforming of methane under intensified CO2 partial pressure DOI
Yuanjie Xu,

Zemin An,

Xin Yu

et al.

Journal of Catalysis, Journal Year: 2023, Volume and Issue: 427, P. 115094 - 115094

Published: Aug. 10, 2023

Language: Английский

Citations

19
Tuning the CO2 hydrogenation path by moderately phosphating the Co-Al catalyst toward methanol synthesis DOI
Heng Zhang,

Donglei Mao,

Jinxin Zhang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 340, P. 123257 - 123257

Published: Sept. 4, 2023

Language: Английский

Citations

17
Oxygen vacancy-boosted thermocatalytic CO2 hydrogenation: Engineering strategies, promoting effects and mediating mechanisms DOI
Guiming Xie, Xiaorui Wang, Xianfeng Li

et al.

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 99, P. 393 - 408

Published: Aug. 8, 2024

Language: Английский

Citations

7