Chemical Engineering Journal, Год журнала: 2021, Номер 430, С. 132733 - 132733
Опубликована: Сен. 30, 2021
Язык: Английский
Chemical Engineering Journal, Год журнала: 2021, Номер 430, С. 132733 - 132733
Опубликована: Сен. 30, 2021
Язык: Английский
SusMat, Год журнала: 2021, Номер 1(1), С. 66 - 87
Опубликована: Март 1, 2021
Abstract The efficient electrocatalysis plays the key role in development of electrochemical energy conversion technologies to alleviate crisis. Given their multiple active sites and large specific surface areas as electrocatalysts, metal‐organic frameworks (MOFs) derivatives have attracted considerable interests recent years. Specially, exploring roles enhanced MOFs is significant for understanding developing new effective electrocatalysts. Recently, vital vacancies has been proven promote electrocatalytic processes (such H 2 or O evolution reactions, reduction N reactions). In order in‐depth effect classification, synthetic strategy, various are reviewed. Also, perspectives on challenges opportunities presented.
Язык: Английский
Процитировано
283Advanced Materials, Год журнала: 2021, Номер 34(22)
Опубликована: Июль 8, 2021
Recently, smart 2D covalent organic frameworks (COFs), combining the advantages of both inherent structure features and functional building blocks, have been demonstrated to show reversible changes in conformation, color, luminescence response external stimuli. This review provides a summary on recent progress COFs that are responsive stimuli such as metal ions, gas molecules, pH values, temperature, electricity, light, etc. Moreover, mechanisms design strategies, along with applications these stimulus-responsive chemical sensors photoelectronic devices also discussed. It is believed this would provide some guidelines for designing novel single-/multistimulus-responsive controllable behaviors advanced applications.
Язык: Английский
Процитировано
219Small Structures, Год журнала: 2022, Номер 4(6)
Опубликована: Сен. 16, 2022
The 2D nanosheets of metal–organic frameworks (MOFs) have recently emerged as a promising material that makes them valuable in widespread electrocatalytic fields due to their atomic‐level thickness, abundant active sites, and large surface area. Efficient electrocatalysts for hydrogen evolution reaction (HER), oxygen (OER), overall water splitting are highly desired with low overpotentials promote the industrial applications energy conversion devices. MOF nanostructures provide long‐term stability high electrical conductivity enhance catalyst activity durability. This review briefly summarizes synthesis HER/OER/water splitting. More attention is focused on synthetic strategies derivatives. catalytic performance superior properties these materials highlighted. outperformance originates from rational design, myriad thickness. current future challenges this field scientific perspectives overcome It suggested construction can develop state‐of‐the‐art electrocatalyst environmental division.
Язык: Английский
Процитировано
177Journal of Power Sources, Год журнала: 2021, Номер 488, С. 229444 - 229444
Опубликована: Янв. 18, 2021
Язык: Английский
Процитировано
176Electrochemistry Communications, Год журнала: 2021, Номер 126, С. 107024 - 107024
Опубликована: Март 30, 2021
Oxygen evolution reaction (OER), hydrogen (HER), oxygen reduction (ORR), nitrogen (NRR), and carbon dioxide (CO2RR) are five major reactions in the progress, conversion, storage of clean energy. Efficient electrocatalysts can be used to decrease overpotential these elevate practical applications energy-related systems. Metal–organic frameworks (MOFs), via modification electrodes, provide new opportunities develop green sustainable energy systems conduct fundamental research on electrocatalytic applications. Benefitting from versatility engineering construction strategies, compositional/structural modification, high electrical conductivity, various high-density active sites, capability as precursors, MOFs derived materials considered efficient electrocatalysts. Based those merits, electrochemical application their for mentioned briefly discussed this mini review. Furthermore, challenges perspectives MOF-based also provided.
Язык: Английский
Процитировано
160Dalton Transactions, Год журнала: 2021, Номер 50(33), С. 11331 - 11346
Опубликована: Янв. 1, 2021
Recent progress on 2D conductive MOFs and layered containing pillar-layered nanosheets as electrode materials in SCs is reviewed, including synthetic design strategies, electrochemical performances, working mechanisms.
Язык: Английский
Процитировано
150Chemical Engineering Journal, Год журнала: 2021, Номер 431, С. 134170 - 134170
Опубликована: Дек. 16, 2021
Язык: Английский
Процитировано
133Small Structures, Год журнала: 2021, Номер 3(5)
Опубликована: Окт. 9, 2021
Iron‐series (Fe, Co, and Ni) containing metal–organic frameworks (MOFs) have gained great concern in supercapacitors (SCs) because of their tailorable architectures, multiple redox‐active sites, intriguing properties. Given the importance porosities MOFs for charge transmission, an essential assessment designs, preparation methods, engineering technologies is strongly required to further explore optimize SCs. Through empowering conductive backbones centers, iron‐series MOF‐based electrodes made outstanding achievements recently. This review aims summarize these core reports on MOFs. Correspondingly, design strategy, reason compositing, strategy introducing heteroatoms, current divergences structural alteration mechanisms are discussed. Potential bottleneck issues coping strategies also perspectively discussed guide future optimization.
Язык: Английский
Процитировано
116Journal of Energy Storage, Год журнала: 2021, Номер 44, С. 103263 - 103263
Опубликована: Окт. 4, 2021
Язык: Английский
Процитировано
110Nanoscale, Год журнала: 2022, Номер 14(5), С. 1679 - 1699
Опубликована: Янв. 1, 2022
The fossil-fuel shortage and severe environmental issues have posed ever-increasing demands on clean renewable energy sources, for which the exploration of electrocatalysts has been a big challenge toward transfer storage.
Язык: Английский
Процитировано
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