Springer eBooks, Год журнала: 2012, Номер unknown, С. 33 - 2028
Опубликована: Янв. 1, 2012
Язык: Английский
Springer eBooks, Год журнала: 2012, Номер unknown, С. 33 - 2028
Опубликована: Янв. 1, 2012
Язык: Английский
Journal of Hazardous Materials, Год журнала: 2021, Номер 424, С. 127713 - 127713
Опубликована: Ноя. 18, 2021
Язык: Английский
Процитировано
68Journal of Bioscience and Bioengineering, Год журнала: 2009, Номер 109(6), С. 576 - 582
Опубликована: Дек. 3, 2009
Язык: Английский
Процитировано
130Advances in applied microbiology, Год журнала: 2009, Номер unknown, С. 65 - 108
Опубликована: Янв. 1, 2009
Язык: Английский
Процитировано
113Environmental Science & Technology, Год журнала: 2013, Номер 47(9), С. 4536 - 4543
Опубликована: Апрель 1, 2013
In the present study, a novel and efficient technology based on use of an oxidative enzyme was developed to perform continuous removal estrogenic compounds from polluted wastewaters. A 2 L enzymatic membrane reactor (EMR) successfully operated for 100 h with minimal requirements laccase transformation estrone (E1), 17β-estradiol (E2), 17α-ethinylestradiol (EE2)from both buffer solution real wastewater (filtered secondary effluent). When experiments were performed at high low concentrations target compounds, 4 mg/L μg/L, not only yields (80-100%) but also outstanding reduction estrogenicity (about 84-95%) attained. EMR applied treatment municipal wastewaters environmental different (0.29-1.52 ng/L), excellent results achieved indicating efficiency potential system. second goal this study relied identification products elucidate catalytic mechanism estrogens' by laccase. The formation dimers trimers E1, E2, EE2, as well decomposition E2 into E1 laccase-catalyzed treatment, has been demonstrated liquid chromatography atmospheric pressure chemical ionization (LC-APCI) analysis confirmed determination accurate masses through electrospray time-of-flight mass spectrometry (LC-ESI-TOF). Dimeric EE2 found even when operating concentrations. Moreover, reaction pathways proposed.
Язык: Английский
Процитировано
100Springer eBooks, Год журнала: 2012, Номер unknown, С. 33 - 2028
Опубликована: Янв. 1, 2012
Язык: Английский
Процитировано
88