ACS Sustainable Chemistry & Engineering,
Год журнала:
2017,
Номер
5(3), С. 2562 - 2577
Опубликована: Янв. 10, 2017
In
this
study,
BiVO4
was
prepared
by
a
hydrothermal
synthesis
route
in
the
presence
of
sodium
dodecyl
sulfate
using
aqueous
NH3
as
precipitant.
g-C3N4
combustion
method
melamine.
order
to
develop
highly
efficient
photocatalyst,
heterojunction
catalyst
based
on
and
prepared.
Different
amounts
were
mixed
annealed
obtain
photocatalysts.
FeVO4
LaVO4
also
for
comparative
catalytic
investigation.
Catalysts
characterized
series
complementary
combinations
powder
X-ray
diffraction,
thermogravimetric
analysis,
elemental
N2
adsorption–desorption,
scanning
electron
microscopy,
transmission
temperature-programmed
desorption
CO2,
diffuse
reflectance
ultraviolet
visible
spectroscopy,
photoelectron
photoluminescence
photoelectrochemical
studies.
investigated
light
driven
oxidation
benzyl
alcohol,
amine,
aniline
with
O2.
propose
electrons,
holes,
radicals
mediated
reaction
pathways,
reactions
performed
an
electron/hole/radical
scavenger.
Further,
confirm
various
products
formed
during
photocatalytic
aniline,
several
model
carried
out.
Based
results
obtained,
mechanism
structure–activity
relationship
established.
ACS Applied Polymer Materials,
Год журнала:
2019,
Номер
1(4), С. 593 - 611
Опубликована: Фев. 20, 2019
The
field
of
3D
printing
is
continuing
its
rapid
development
in
both
academic
and
industrial
research
environments.
technologies
has
opened
new
implementations
prototyping,
tooling,
dentistry,
microfluidics,
biomedical
devices,
tissue
engineering,
drug
delivery,
etc.
Among
different
techniques,
photopolymerization-based
process
(such
as
stereolithography
digital
light
processing)
offers
flexibility
over
the
final
properties
printed
materials
optical,
chemical,
mechanical
properties)
using
versatile
polymer
chemistry.
strategy
behind
photopolymerization
based
on
monomers/oligomers
liquid
state
(in
presence
photoinitiators)
that
can
be
photopolymerized
(via
radical
or
cationic
mechanism)
upon
exposure
to
source
wavelengths
(depending
photoinitiator
system).
An
overview
recent
evolutions
highlights
novel
printable
photopolymers
provided
herein.
Challenges
limit
use
conventional
(i.e.,
initiation
under
UV
light)
together
with
prospective
solutions
such
incorporation
photosensitive
initiators
red-shifted
absorptions
are
also
discussed
detail.
This
review
spotlights
progress
controlled
living
techniques
reversible
addition–fragmentation
chain-transfer
polymerization)
printing,
which
will
pave
way
for
widespread
growth
generations
features
possibility
postprinting
modifications.
Chemical Society Reviews,
Год журнала:
2018,
Номер
47(15), С. 5786 - 5865
Опубликована: Янв. 1, 2018
This
review
provides
an
overview
of
the
use
electrochemistry
as
appealing
platform
for
expediting
carbon–hydrogen
functionalization
and
carbon–nitrogen
bond
formation.
Journal of the American Chemical Society,
Год журнала:
2018,
Номер
140(45), С. 15353 - 15365
Опубликована: Окт. 2, 2018
The
targeted
choice
of
specific
photocatalysts
has
been
shown
to
play
a
critical
role
for
the
successful
realization
challenging
photoredox
catalytic
transformations.
Herein,
we
demonstrate
implementation
rational
design
strategy
series
deliberate
structural
manipulations
cyanoarene-based,
purely
organic
donor-acceptor
photocatalysts,
using
1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene
(4CzIPN)
as
starting
point.
Systematic
modifications
both
donor
substituents
well
acceptors'
molecular
core
allowed
us
identify
strongly
oxidizing
reducing
catalysts
(e.g.,
an
unprecedented
detriflation
unactivated
naphthol
triflate),
which
additionally
offer
remarkably
balanced
redox
potentials
with
predictable
trends.
Especially
halogen
arene
substitutions
are
instrumental
our
alterations
catalysts'
properties.
Based
on
their
preeminent
electrochemical
and
photophysical
characteristics,
all
novel,
were
evaluated
in
three
challenging,
mechanistically
distinct
classes
benchmark
reactions
(either
requiring
balanced,
highly
or
properties)
enormous
potential
customizable
that
outperform
complement
prevailing
typical
best
photocatalysts.
Chemical Society Reviews,
Год журнала:
2018,
Номер
47(13), С. 4710 - 4728
Опубликована: Янв. 1, 2018
In
combination
with
porosity
and
tunability,
light
harvesting,
energy
transfer,
photocatalysis,
are
facets
crucial
for
engineering
of
MOF-based
sensors.
Chemical Reviews,
Год журнала:
2021,
Номер
122(2), С. 2752 - 2906
Опубликована: Авг. 10, 2021
Photoinduced
chemical
transformations
have
received
in
recent
years
a
tremendous
amount
of
attention,
providing
plethora
opportunities
to
synthetic
organic
chemists.
However,
performing
photochemical
transformation
can
be
quite
challenge
because
various
issues
related
the
delivery
photons.
These
challenges
barred
widespread
adoption
steps
industry.
past
decade,
several
technological
innovations
led
more
reproducible,
selective,
and
scalable
photoinduced
reactions.
Herein,
we
provide
comprehensive
overview
these
exciting
advances,
including
flow
chemistry,
high-throughput
experimentation,
reactor
design
scale-up,
combination
photo-
electro-chemistry.
Angewandte Chemie International Edition,
Год журнала:
2018,
Номер
58(16), С. 5170 - 5189
Опубликована: Авг. 1, 2018
The
application
of
photochemistry
to
polymer
and
material
science
has
led
the
development
complex
yet
efficient
systems
for
polymerization,
post-functionalization,
advanced
materials
production.
Using
light
activate
chemical
reaction
pathways
in
these
not
only
leads
exquisite
control
over
dynamics,
but
also
allows
synthetic
protocols
be
easily
achieved.
Compared
polymerization
mediated
by
thermal,
chemical,
or
electrochemical
means,
photoinduced
can
potentially
offer
more
versatile
methods
macromolecular
synthesis.
We
highlight
utility
as
an
energy
source
mediating
photopolymerization,
present
some
promising
examples
which
are
advancing
production
through
their
exploitation
photochemistry.
Macromolecules,
Год журнала:
2017,
Номер
50(18), С. 6979 - 6997
Опубликована: Сен. 17, 2017
The
ideal
of
living
polymerization
has
defined
research
in
polymer
chemistry
over
the
past
50
years.
In
this
Perspective,
we
present
case
that
concept
enabled
treatment
polymers
as
organic
molecules,
rather
than
impure
mixtures
species,
and
allowed
translation
methods
developed
by
synthetic
chemists
into
ever
more
accessible
and/or
controlled
methods.
concurrent
development
rapid
analytical
for
screening
new
characteristics,
chiefly
size
exclusion
chromatography,
greatly
aided
expansion
Journal of the American Chemical Society,
Год журнала:
2016,
Номер
138(35), С. 11399 - 11407
Опубликована: Авг. 24, 2016
N-Aryl
phenoxazines
have
been
synthesized
and
introduced
as
strongly
reducing
metal-free
photoredox
catalysts
in
organocatalyzed
atom
transfer
radical
polymerization
for
the
synthesis
of
well-defined
polymers.
Experiments
confirmed
quantum
chemical
predictions
that,
like
their
dihydrophenazine
analogs,
photoexcited
states
phenoxazine
are
achieve
superior
performance
when
they
possess
charge
character.
We
compare
to
previously
reported
dihydrophenazines
phenothiazines
gain
insight
into
these
establish
principles
catalyst
design.
A
key
finding
reveals
that
maintenance
a
planar
conformation
during
catalytic
cycle
encourages
macromolecules.
Using
principles,
we
realized
core
substituted
visible
light
performed
UV-absorbing
well
organic
photocatalysts
polymerization.
this
irradiating
with
white
LEDs
resulted
production
polymers
targeted
molecular
weights
through
achieving
quantitative
initiator
efficiencies,
which
dispersities
ranging
from
1.13
1.31.
