Chemistry - A European Journal,
Год журнала:
2021,
Номер
27(60), С. 14931 - 14935
Опубликована: Авг. 27, 2021
An
electrochemical
three
component
cascade
phosphorylation
reaction
of
various
heteroatoms-containing
nucleophiles
including
carbazoles,
indoles,
phenols,
alcohols,
and
thiols
with
Ph2
PH
has
been
established.
Electricity
is
used
as
the
"traceless"
oxidant
water
air
are
utilized
"green"
oxygen
source.
All
kinds
structurally
diverse
organophosphorus
compounds
P(O)-N/P(O)-O/P(O)-S
bonds
assembled
in
moderate
to
excellent
yields
(three
categories
products,
50
examples,
up
97
%
yield).
A
tentative
free
radical
course
put
forward
rationalize
procedure.
Chemical Science,
Год журнала:
2022,
Номер
13(22), С. 6519 - 6524
Опубликована: Янв. 1, 2022
We
describe
a
simple
and
efficient
visible-light-induced
C–P
bond
forming
reaction
for
the
synthesis
of
P-chiral
heteroaryl
phosphine
oxides
in
moderate
to
high
yields
with
excellent
ee
values
(97–99%
ee).
Green Chemistry,
Год журнала:
2023,
Номер
25(11), С. 4528 - 4535
Опубликована: Янв. 1, 2023
A
photocatalytic
phosphorylation
of
heteroatom
nucleophiles
has
been
achieved
via
the
direct
coupling
phosphorus-centered
radical
cations
with
nucleophiles.
The Journal of Organic Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 22, 2025
An
external
reductant-free
and
acid-free
synthesis
of
phosphonothioates
from
odorless
sodium
sulfinates
induced
by
CCl4
(1.0
equiv)
under
mild
conditions
has
been
achieved.
This
transformation
provides
an
efficient
synthetic
approach
to
in
up
98%
yield
with
good
functional
group
compatibility.
In
addition,
unexpected
CCl4-induced
sulfoxides
sulfones
using
DMSO
as
the
solvent
developed.
Molecules,
Год журнала:
2020,
Номер
25(16), С. 3684 - 3684
Опубликована: Авг. 13, 2020
This
review
covers
the
main
synthetic
routes
to
and
corresponding
mechanisms
of
phosphoramidate
formation.
The
can
be
separated
into
six
categories:
salt
elimination,
oxidative
cross-coupling,
azide,
reduction,
hydrophosphinylation,
phosphoramidate-aldehyde-dienophile
(PAD).
Examples
some
important
compounds
synthesized
through
these
are
provided.
As
an
class
organophosphorus
compounds,
applications
also
briefly
introduced.
The Journal of Organic Chemistry,
Год журнала:
2022,
Номер
87(5), С. 3254 - 3264
Опубликована: Янв. 24, 2022
A
facile
and
efficient
method
for
the
synthesis
of
primary
phosphinamides
from
Ar2P(O)-H
reagents
with
stable
readily
available
ammonium
carbonate
as
an
ammonia
source
is
disclosed
herein
first
time.
This
ethyl
bromoacetate-mediated
amination
proceeds
smoothly
under
mild
simple
conditions,
without
any
metal
catalyst
or
oxidant.
Moreover,
this
also
appropriate
reaction
a
variety
amines,
alcohols,
phenols
to
construct
P-N
P-O
bonds,
features
handy
operation,
good
functional
group
tolerance,
broad
substrate
scope.
The Journal of Organic Chemistry,
Год журнала:
2022,
Номер
87(9), С. 6224 - 6236
Опубликована: Апрель 20, 2022
An
efficient
copper-catalyzed
aerobic
oxidative
cross-dehydrogenative
coupling
reaction
for
the
synthesis
of
multisubstituted
phosphorylhydrazides
from
N,N-disubstituted
hydrazines
and
hydrogen
phosphoryl
compounds
is
accomplished.
The
proceeds
under
mild
conditions
without
addition
any
external
oxidants
bases.
This
work
reported
here
represents
a
direct
P(═O)-N-N
bond
formation
with
advantages
being
operationally
simple,
good
functional
group
tolerance,
high
atom
step
economy.
Furthermore,
selected
exhibit
potential
inhibitory
activity
against
tumor
cells,
which
can
be
used
in
field
screening
anticancer
agents
as
new
chemical
entities.
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
89(5), С. 3259 - 3270
Опубликована: Фев. 21, 2024
The
NaOAc-assisted
aerobic
oxidation
reaction
of
pentacoordinate
hydrospirophosphoranes
and
dichalcogenyl
compounds
with
open
air
as
a
green
oxidant
has
been
developed
under
mild
conditions.
A
series
novel
spirophosphoranes
P–Se/P–S
bonds
were
synthesized
in
excellent
yields.
mechanism
was
determined
by
31P
nuclear
magnetic
resonance
tracing
experiments,
high-resolution
mass
spectrometry
X-ray
diffraction
analysis.
method
features
broad
substrate
scope,
good
functional
group
tolerance,
high
degree
atomic
utilization
is
meaningful
for
the
synthesis
bioactive
chalcogenphosphate
chalcogen
phosphorus
moieties.
Organic Letters,
Год журнала:
2024,
Номер
26(12), С. 2435 - 2439
Опубликована: Март 19, 2024
A
photocatalytic
cross-dehydrogenative
coupling
of
diarylphosphine
oxides
with
alcohols
and
phenols
has
been
developed.
Using
organic
dye
Rose
Bengal
as
the
photocatalyst
air
oxidant,
reaction
proceeded
smoothly
at
room
temperature.
Both
were
feasible,
affording
various
organophosphinates
in
high
yields.
The
absence
a
halogenating
reagent,
transition-metal
catalyst,
green
mild
conditions
make
this
strategy
environmentally
benign
sustainable.
Mechanistic
studies
indicated
that
is
enabled
by
cooperation
photoredox
catalysis
photosensitization.
