Supramolecular Materials, Год журнала: 2025, Номер unknown, С. 100104 - 100104
Опубликована: Апрель 1, 2025
Язык: Английский
Dyes and Pigments, Год журнала: 2024, Номер 223, С. 111958 - 111958
Опубликована: Янв. 11, 2024
Язык: Английский
Процитировано
25
Chemical Society Reviews, Год журнала: 2022, Номер 51(22), С. 9262 - 9339
Опубликована: Янв. 1, 2022
This review summarises advances in chemistry of tetrapyrrole sandwiches with rare earth elements and highlights the current state their use single-molecule magnetism, organic field-effect transistors, conducting materials nonlinear optics.
Язык: Английский
Процитировано
51
Coordination Chemistry Reviews, Год журнала: 2022, Номер 474, С. 214866 - 214866
Опубликована: Окт. 8, 2022
Язык: Английский
Процитировано
45
Advanced Optical Materials, Год журнала: 2022, Номер 11(11)
Опубликована: Ноя. 20, 2022
Abstract Recently, in vivo optical imaging the second‐near‐infrared window (NIR‐II, 1000–1700 nm) that allows high spatiotemporal resolution and depth due to reduced photon scattering weak auto‐fluorescence has drawn more attention. Among various NIR‐II probes, lanthanide‐doped nanoparticles show several great advantages including abundant energy levels transitions for multi‐emissions, ultra‐stable emissions long‐term detection, long luminescence lifetime background‐free imaging. These merits have inspired researchers make efforts develop superior bio‐imaging bio‐sensing. In this review, luminescent absorption spectra of lanthanide ions are outlined, recent advances designing nanocrystals with optimized quantum yields summarized. Then their significant concerns sensing assembly disassembly, clearance, responsiveness lanthanide‐based discussed. Major challenges future opportunities using finally proposed direct new solutions interdisciplinary research.
Язык: Английский
Процитировано
43
Coordination Chemistry Reviews, Год журнала: 2023, Номер 499, С. 215486 - 215486
Опубликована: Окт. 27, 2023
Язык: Английский
Процитировано
27
Chemical Science, Год журнала: 2023, Номер 14(23), С. 6457 - 6466
Опубликована: Янв. 1, 2023
A photo-responsive full-color lanthanide supramolecular switch was constructed from a synthetic 2,6-pyridine dicarboxylic acid (DPA)-modified pillar[5]arene (H) complexing with ion (Ln3+ = Tb3+ and Eu3+) dicationic diarylethene derivative (G1) through noncovalent assembly. Benefiting the strong complexation between DPA Ln3+ 3 : 1 stoichiometric ratio, complex H/Ln3+ presented an emerging emission in aqueous organic phase. Subsequently, network polymer formed by further encapsulating G1via hydrophobic cavity of pillar[5]arene, which greatly contributed to increased intensity lifetime, also resulted formation light switch. Moreover, luminescence, especially white emission, achieved (CIE: 0.31, 0.32) dichloromethane 0.33) solutions adjustment different ratios Eu3+. Notably, photo-reversible luminescence properties assembly were tuned via alternant UV/vis irradiation due conformation-dependent photochromic energy transfer open/closed-ring diarylethene. Ultimately, prepared successfully applied anti-counterfeiting use intelligent multicolored writing inks, presents new opportunities for design advanced stimuli-responsive on-demand color tuning luminescent materials.
Язык: Английский
Процитировано
24
The Journal of Physical Chemistry C, Год журнала: 2024, Номер 128(12), С. 4882 - 4890
Опубликована: Март 15, 2024
Single molecule magnets (SMMs) constitute a pivotal class of nanoscale molecular with promising potential across various domains such as high-density information storage, quantum computing, and spin electron devices. Among these, lanthanide-based SMMs have garnered significant attention in recent research due to their distinctive magnetic coordination properties, offering prospects for substantial advancements storage technologies. Over the past three decades, considerable efforts been directed toward developing novel characterized by anisotropy barrier blocking temperature, leading strides field. This perspective delves into latest developments structure performance lanthanide SMMs, providing valuable insights optimizing functionality. The roles ligands central atoms modulating are emphasized alongside strategies augment explore surface applications. Additionally, this explores fusion theoretical machine learning methodologies identify highly anisotropic thereby outlining roadmap functionality SMMs.
Язык: Английский
Процитировано
10
Green Chemistry, Год журнала: 2022, Номер 24(24), С. 9402 - 9427
Опубликована: Янв. 1, 2022
The review provides information on the latest methods for synthesis of MOFs in line with green chemistry principles an industrial scale.
Язык: Английский
Процитировано
37
Coordination Chemistry Reviews, Год журнала: 2022, Номер 472, С. 214795 - 214795
Опубликована: Авг. 29, 2022
Язык: Английский
Процитировано
36
Theranostics, Год журнала: 2023, Номер 13(15), С. 5501 - 5544
Опубликована: Янв. 1, 2023
Photodynamic Therapy (PDT) is an approved treatment modality, which presently receiving great attention due to its limited invasiveness, high selectivity and susceptibility drug resistance.Another related research area currently expanding rapidly the development of novel theranostic agents based on combination PDT with different imaging technologies, allows for both therapy diagnosis.This can help address issues suboptimal biodistribution through regional imaging, while therapeutic enable effective personalized therapy.In this review, we describe compounds, whose structures combine photosensitizers probes -including examples near-infrared optical magnetic resonance (MRI) nuclear (PET or SPECT), generating candidates.We have intentionally focused our already been investigated preclinically in vivo order demonstrate potential such clinical applications.
Язык: Английский
Процитировано
18