FirePhysChem,
Год журнала:
2022,
Номер
3(1), С. 78 - 87
Опубликована: Сен. 20, 2022
In
recent
years,
the
development
of
novel
advanced
energetic
materials
has
significantly
shifted
toward
nitrogen
heterocyclic
derivatives,
which
demonstrate
a
great
potential
for
multipurpose
application
patterns.
Among
known
heterocycles
tetrazine
ring
is
well-known
structural
scaffold
used
in
preparation
various
high-energy
materials.
The
majority
energy-rich
substances
incorporating
subunit
exhibit
high
thermal
stability,
good
detonation
performance
and
low
sensitivity
to
mechanical
stimuli
defines
their
practical
usability.
this
review,
main
achievements
on
synthesis
tetrazine-based
reported
last
decade
are
summarized.
Potential
applications
presented
compounds
especially
emphasized.
Chemical Reviews,
Год журнала:
2022,
Номер
122(21), С. 16110 - 16293
Опубликована: Сен. 16, 2022
In
the
present
review,
we
discuss
recent
progress
in
field
of
C–Z
bond
formation
reactions
(Z
=
S,
Se,
Te)
catalyzed
by
transition
metals.
Two
complementary
methodologies
are
considered─catalytic
cross-coupling
and
catalytic
addition
reactions.
The
development
advanced
systems
is
aimed
at
improved
catalyst
efficiency,
reduced
loading,
better
cost
environmental
concerns,
higher
selectivity
yields.
important
rise
research
efforts
sustainability
green
chemistry
areas
critically
assessed.
paramount
role
mechanistic
studies
a
new
generation
addressed,
key
achievements,
problems,
challenges
summarized
for
this
field.
Russian Chemical Reviews,
Год журнала:
2024,
Номер
93(7), С. RCR5125 - RCR5125
Опубликована: Июль 1, 2024
The
chemistry
of
heterocyclic
compounds
has
traditionally
been
and
remains
a
bright
area
chemical
science
in
Russia.
This
is
due
to
the
fact
that
many
heterocycles
find
widest
application.
These
are
key
structural
fragments
most
drugs,
plant
protection
agents.
Many
natural
also
derivatives
heterocycles.
At
present,
more
than
half
hundreds
millions
known
collective
review
devoted
achievements
Russian
chemists
this
field
over
last
15–20
years.
presents
leading
heterocyclists
representing
both
RAS
institutes
university
science.
It
worth
noting
wide
scope
review,
terms
geography
author
teams,
covering
whole
our
large
country,
diversity
research
areas.
Practically
all
major
types
represented
review.
special
attention
focused
on
practical
applications
design
new
drugs
biologically
active
compounds,
high-energy
molecules,
materials
for
organic
electronics
photovoltaics,
ligands
coordination
chemistry,
other
rapidly
developing
advances
would
not
be
possible
without
development
fundamental
transformations
chemistry.<br>
Bibliography
—
2237
references.
Journal of Heterocyclic Chemistry,
Год журнала:
2022,
Номер
60(4), С. 537 - 565
Опубликована: Окт. 13, 2022
Abstract
Among
different
heterocyclic
compounds,
isoxazole
and
their
analogues
are
very
important
classes
of
compounds
as
they
display
an
extensive
range
biological
actions.
This
makes
such
scaffolds
structures
in
the
field
medicinal
chemistry.
From
literature
assessment,
is
clinically
proven
to
be
effective
anti‐bacterial,
anti‐fungal,
anti‐inflammatory,
anti‐cancer,
anti‐tubercular,
anti‐neoplastic
agent.
The
derivatives
which
exhibits
adjustment
structure
have
shown
a
high
degree
variety
properties
evident
them
beneficial
progress
novel
bioactive
drugs
show
enhanced
effectiveness
along
with
minor
harmfulness.
Structural
aspects
having
aromaticity
weaker
nitrogen‐oxygen
bonding
provide
potential
site
for
ring
cleavage.
Thus,
this
system
allows
easier
modifications
substituents
consequently
make
useful
intermediates
various
synthetic
routes
compounds.
Hence,
synthesis
evaluation
isoxazole‐containing
molecules
wider
therapeutic
consequences
always
topic
interest
chemists.
light
comprehensive
research
on
isoxazole,
it
thought
worthwhile
review
pathways
broad
spectrum
Green Chemistry,
Год журнала:
2023,
Номер
25(8), С. 3111 - 3116
Опубликована: Янв. 1, 2023
A
general
visible
light-promoted
and
electron–donor–acceptor
complex-enabled
cascade
reaction
of
alkynes
to
produce
functionalized
sulfur-containing
heterocycles
under
photocatalyst-,
base-,
oxidant-
metal-free
conditions
was
developed.
The Open Medicinal Chemistry Journal,
Год журнала:
2020,
Номер
14(1), С. 49 - 64
Опубликована: Сен. 14, 2020
Nitrogen
sulphur
containing
heterocycles
have
specific
properties
due
to
which
they
can
be
used
as
a
potential
material
in
different
type
of
industries
such
medicinal/pharmaceutical,
paint,
packing
and
textile,
required
for
various
chemical,
physical
operations
their
use
products.
Especially
dyes,
agrochemicals,
medicine,
etc
.
make
them
more
significant.
In
present
days,
Nitrogen-Sulfur
are
repeatedly
attracting
the
interest
chemists
exceptional
bioactive
behavior.
The
study
is
review
work
carried
out
by
chemist
discovery
new,
effective,
medicinally
important
heterocyclic
compounds.
basically
focused
on
nitrogen-sulfur
therapeutic
interest,
especially
with
thiazole,
thiazine,
pyrimidine,
morpholine
piperazine
heterosystems,
benzothiazines,
pyrazole-benzothiazines,
morpholine-benzothiazines,
piperazine-benzothiazines
pyrimidine-benzothiazoles,
mainly
unique
structural
features,
enable
exhibit
number
biological
pharmacological
activities.
Due
novel
mode
action,
broad
spectrum
activity,
lesser
toxicity
towards
mammalian
cells,
suitable
profiles
humans
triggered
Sulphur
designing
synthesizing
derivatives
better
properties.
overall
objective
discuss
importance
biodynamic
structurally
diverse
interest:
morpholine,
piperazine,
pyrozole,
benothiazoles,
pyrimidobenzothiazoles,
4H-1,4-benzothiazines,
pyrazolyl-benzothiazines,
morpholinyl-benzothiazines
piperazinylbenzothiazines
order
access
commercial
molecules
search
future.
