Hydrology and earth system sciences,
Journal Year:
2021,
Volume and Issue:
25(9), P. 5133 - 5151
Published: Sept. 22, 2021
Abstract.
Understanding
the
controls
on
event-driven
dissolved
organic
carbon
(DOC)
export
is
crucial
as
DOC
an
important
link
between
terrestrial
and
aquatic
cycles.
We
hypothesized
that
topography
a
key
driver
of
in
headwater
catchments
because
it
influences
hydrological
connectivity,
which
can
inhibit
or
facilitate
mobilization.
To
test
this
hypothesis,
we
studied
mechanisms
controlling
mobilization
Große
Ohe
catchment,
forested
mid-elevation
mountainous
region
southeastern
Germany.
Discharge
stream
concentrations
were
measured
at
interval
15
min
using
situ
UV-Vis
(ultraviolet–visible)
spectrometry
from
June
2018
until
October
2020
two
topographically
contrasting
subcatchments
same
stream.
At
upper
location
(888
m
above
sea
level,
a.s.l.),
drains
steep
hillslopes,
whereas,
lower
(771
larger
area,
including
flat
wide
riparian
zone.
focus
four
events
with
antecedent
wetness
conditions
event
size.
During
events,
in-stream
increased
up
to
19
mg
L−1
comparison
2–3
during
baseflow.
The
concentration–discharge
relationships
exhibited
pronounced
but
almost
exclusively
counterclockwise
hysteresis
loops
generally
wider
catchment
than
due
delayed
zone
released
considerable
amounts
DOC,
led
load
7.4
kg
h−1.
total
wetness.
found
disproportionally
high
contribution
following
long
dry
period.
attribute
low
connectivity
drought,
inhibited
mobilization,
especially
beginning
events.
Our
data
show
not
only
size
also
strongly
influence
leading
varying
subcatchments,
depending
topography.
As
frequency
prolonged
drought
periods
predicted
increase,
relative
different
may
change
future
when
will
be
reduced
more
often.
Science,
Journal Year:
2019,
Volume and Issue:
365(6459)
Published: Sept. 19, 2019
River
ecosystems
are
highly
biodiverse,
influence
global
biogeochemical
cycles,
and
provide
valued
services.
However,
humans
increasingly
degrading
fluvial
by
altering
their
streamflows.
Effective
river
restoration
requires
advancing
our
mechanistic
understanding
of
how
flow
regimes
affect
biota
ecosystem
processes.
Here,
we
review
emerging
advances
in
hydroecology
relevant
to
this
goal.
Spatiotemporal
variation
exerts
direct
indirect
control
on
the
composition,
structure,
dynamics
communities
at
local
regional
scales.
Streamflows
also
processes,
such
as
nutrient
uptake
transformation,
organic
matter
processing,
metabolism.
We
deepening
biological
not
just
static
patterns,
affected
stream
research
nexus
flow-biota-ecosystem
processes
is
an
early
stage.
illustrate
frontier
with
evidence
from
altered
regulated
rivers
urban
streams.
identify
challenges
that
should
be
prioritized
advance
process-based
restoration.
Reviews of Geophysics,
Journal Year:
2017,
Volume and Issue:
55(2), P. 560 - 585
Published: May 31, 2017
Abstract
Terrestrial
carbon
export
via
inland
aquatic
systems
is
a
key
process
in
the
global
cycle.
It
includes
loss
of
to
atmosphere
outgassing
from
rivers,
lakes,
or
reservoirs
and
fixation
water
column
as
well
sediments.
This
review
focuses
on
headwater
streams
that
are
important
because
their
stream
biogeochemistry
directly
reflects
input
soils
groundwaters.
Major
drivers
dioxide
partial
pressures
(
p
CO
2
)
mechanisms
terrestrial
dissolved
inorganic,
organic
particulate
(DIC,
DOC,
POC)
influxes
summarized
this
work.
Our
analysis
indicates
river
average
3100
ppmV
more
often
exceeded
by
contributions
small
when
compared
rivers
with
larger
catchments
(>
500
km
).
Because
large
proportion
networks
96%
total
number
streams),
headwaters
contribute
large—but
still
poorly
quantified—amounts
atmosphere.
Conservative
estimates
imply
globally
36%
(i.e.,
0.93
Pg
C
yr
−1
originate
headwaters.
We
also
discuss
challenges
determination
sources,
concentrations,
fluxes.
To
overcome
uncertainties
sources
its
scale,
new
investigations
needed
should
include
groundwater
data.
Such
studies
would
benefit
applications
integral
isotope
approaches
multiscale
geophysical
imaging
techniques.
Geophysical Research Letters,
Journal Year:
2018,
Volume and Issue:
45(21)
Published: Oct. 25, 2018
Abstract
Although
the
flux
of
dissolved
organic
carbon
(DOC)
through
freshwaters
is
nearly
equivalent
to
net
uptake
all
terrestrial
ecosystems,
uncertainty
remains
about
how
source
processes
(carbon
production
and
location)
transport
(hydrologic
connectivity
routing)
interact
determine
DOC
across
flow
conditions
ecoregions.
This
limits
our
ability
predict
fluvial
responses
changes
in
climate
land
use.
We
used
concentration
discharge
patterns
with
ensemble
modeling
techniques
quantify
behavior
for
1,006
U.S.
watersheds
spanning
diverse
cover
conditions.
found
that
was
transport‐limited
(concentration
increased
discharge)
80%
this
spanned
ecoregions
watershed
sizes.
The
generality
limitation
demonstrates
coupling
models
widely
available
properties
could
allow
be
efficiently
integrated
into
landscape
Earth
system
models.
Water Resources Research,
Journal Year:
2017,
Volume and Issue:
53(3), P. 1864 - 1878
Published: Feb. 11, 2017
Abstract
We
use
high‐resolution
tracer
data
from
an
experimental
site
to
test
theoretical
approaches
that
integrate
catchment‐scale
flow
and
transport
processes
in
a
unified
framework
centered
on
selective
age
sampling
by
streamflow
evapotranspiration
fluxes.
Transport
operating
at
the
catchment
scale
are
reflected
evolving
residence
time
distribution
of
water
storage
selection
operated
out‐fluxes.
Such
described
here
through
StorAge
Selection
(SAS)
functions
parameterized
as
power
laws
normalized
rank
storage.
computed
appropriate
solution
master
equation
defining
formally
evolution
travel
times.
By
representing
way
which
generates
outflows
composed
different
ages,
main
mechanism
regulating
composition
runoff
is
clearly
identified
detailed
comparison
with
empirical
sets
possible.
Properly
calibrated
numerical
tools
provide
simulations
convincingly
reproduce
complex
measured
signals
daily
deuterium
content
stream
waters
during
wet
dry
periods.
Results
for
under
consideration
consistent
other
recent
studies
indicating
tendency
natural
catchments
preferentially
release
younger
available
water.
The
study
shows
law
SAS
prove
powerful
tool
explain
also
has
potential
less
intensively
monitored
sites.
Water Resources Research,
Journal Year:
2019,
Volume and Issue:
55(5), P. 4233 - 4251
Published: April 15, 2019
Abstract
Understanding
concentration‐discharge
(C‐Q)
relationships
are
essential
for
predicting
chemical
weathering
and
biogeochemical
cycling
under
changing
climate
anthropogenic
conditions.
Contrasting
C‐Q
have
been
observed
widely,
yet
a
mechanistic
framework
that
can
interpret
diverse
patterns
remains
elusive.
This
work
hypothesizes
seemingly
disparate
driven
by
switching
dominance
of
end‐member
source
waters
their
contrasts
arising
from
subsurface
heterogeneity.
We
use
data
Coal
Creek,
high‐elevation
mountainous
catchment
in
Colorado,
recently
developed
watershed
reactive
transport
model
(BioRT‐Flux‐PIHM).
Sensitivity
analysis
Monte‐Carlo
simulations
(500
cases)
show
reaction
kinetics
thermodynamics
distribution
materials
across
depths
govern
the
chemistry
gradients
shallow
soil
water
deeper
groundwater
entering
stream.
The
alternating
organic‐poor
geo‐solute‐rich
dry
conditions
organic‐rich
geo‐solute‐poor
during
spring
melt
leads
to
flushing
pattern
dissolved
organic
carbon
dilution
geogenic
solutes
(e.g.,
Na,
Ca,
Mg).
In
addition,
extent
concentration
regulates
power
law
slopes
(
b
)
via
general
equation
.
At
low
ratios
versus
concentrations
(C
ratio
=
C
sw
/C
gw
<
0.6),
occurs;
at
high
>
1.8),
arises;
chemostasis
occurs
between.
quantitatively
interprets
values
11
(dissolved
carbon,
P,
NO
3
−
,
K,
Si,
Mg,
Al,
Mn,
Fe)
three
catchments
(Coal
Shale
Hills,
Plynlimon)
differing
climate,
geologic,
land
cover
indicates
potentially
broad
regulation
heterogeneity
determining
wide
applications
this
quantifying
values,
which
implications
transformation
scale.
Water Resources Research,
Journal Year:
2017,
Volume and Issue:
53(7), P. 5998 - 6017
Published: July 1, 2017
Abstract
The
relative
importance
of
catchment's
water
provenance
and
flow
paths
varies
in
space
time,
complicating
the
conceptualization
rainfall‐runoff
responses.
We
assessed
temporal
dynamics
source
areas,
paths,
age
by
End
Member
Mixing
Analysis
(EMMA),
hydrograph
separation,
Inverse
Transit
Time
Proxies
(ITTPs)
estimation
within
a
headwater
catchment
Ecuadorian
Andes.
Twenty‐two
solutes,
stable
isotopes,
pH,
electrical
conductivity
from
stream
12
potential
sources
were
analyzed.
Four
end‐members
required
to
satisfactorily
represent
hydrological
system,
i.e.,
rainfall,
spring
water,
bottom
layers
Histosols
Andosols.
Water
near
riparian
zone
was
highest
contributor
runoff
throughout
year
(39%
for
drier
season,
45%
wetter
season),
highlighting
that
is
stored
zone.
Spring
contributions
streamflow
tripled
during
as
evidenced
geochemical
signatures
are
consistent
with
deeper
rather
than
shallow
interflow
through
Rainfall
exhibited
low
seasonal
variation
this
contribution.
Hydrograph
separation
revealed
94%
84%
preevent
seasons,
respectively.
From
low‐flow
high‐flow
conditions,
all
increased
their
contribution
except
water.
decreased
periods,
when
contributing
area
expands.
multimethod
multitracer
approach
enabled
closely
study
interchanging
processes
an
interannual
perspective.
Water Resources Research,
Journal Year:
2017,
Volume and Issue:
53(12), P. 10201 - 10216
Published: Nov. 21, 2017
Abstract
The
myriad
hydrologic
and
biogeochemical
processes
taking
place
in
watersheds
occurring
across
space
time
are
integrated
reflected
the
quantity
quality
of
water
streams
rivers.
Collection
high‐frequency
data
with
sensors
surface
waters
provides
new
opportunities
to
disentangle
these
quantify
sources
transport
solutes
coupled
groundwater‐surface
system.
A
approach
for
separating
streamflow
hydrograph
into
three
components
was
developed
nitrate
estimate
time‐variable
loads
from
chemically
dilute
quick
flow,
concentrated
slowflow
groundwater
end‐member
pathways
periods
up
2
years
a
groundwater‐dominated
quick‐flow‐dominated
stream
central
Wisconsin,
using
only
in‐stream
data.
flow
end‐members
were
distinguished
specific
conductance
Results
indicate
that
contributed
less
than
5%
load
at
both
sites,
whereas
89
±
8%
groundwater,
84
25%
flow.
Concentrated
concentrations
varied
seasonally
peak
winter
2–3
times
greater
minimum
during
growing
season.
Application
this
an
opportunity
assess
vulnerability
nonpoint
source
loading
expected
responses
current
or
changing
conditions
practices
watersheds.
Water Resources Research,
Journal Year:
2018,
Volume and Issue:
54(3), P. 2466 - 2479
Published: March 1, 2018
Abstract
A
state‐of‐the‐art
network
of
water
quality
sensors
was
established
in
2012
to
gather
year‐round
high
temporal
frequency
hydrochemical
data
streams
and
rivers
throughout
the
state
New
Hampshire.
This
spatially
extensive
includes
eight
headwater
stream
two
main
stem
river
monitoring
sites,
spanning
a
variety
orders
land
uses.
Here
we
evaluate
performance
nitrate,
fluorescent
dissolved
organic
matter
(fDOM),
turbidity
included
sensor
network.
Nitrate
were
first
evaluated
laboratory
for
interference
by
different
forms
carbon
(DOC),
then
accuracy
field
across
range
conditions.
Turbidity
assessed
their
effectiveness
as
proxy
concentrations
total
suspended
solids
(TSS)
particulate
C
N,
fDOM
matter.
Overall
platform
also
examined
estimating
percentage
loss
due
failures
or
related
malfunctions.
Although
trials
show
that
DOC
can
affect
optical
nitrate
measurements,
our
validations
with
grab
samples
showed
provide
reliable
measurement
NO
3
wide
Results
is
good
concentration
(
r
2
=
0.82)
but
less
effective
nitrogen
0.41).
measurements
from
correlated
well
TSS
0.78),
PC
0.53),
PN
0.51).