ACS Nano,
Journal Year:
2023,
Volume and Issue:
17(10), P. 8866 - 8898
Published: May 1, 2023
The
emergence
and
development
of
thick
electrodes
provide
an
efficient
way
for
the
high-energy-density
supercapacitor
design.
Wood
is
a
kind
biomass
material
with
porous
hierarchical
structure,
which
has
characteristics
straight
channel,
uniform
pore
good
mechanical
strength,
easy
processing.
wood-inspired
low-tortuosity
vertically
aligned
channel
architecture
are
highly
suitable
construction
electrochemical
supcapacitor
high
energy
densities.
This
review
summarizes
design
concepts
processing
parameters
electrode
supercapacitors
inspired
by
natural
woods,
including
wood-based
structural
regulation,
electric
double
layer
capacitances
(EDLCs)/pseudocapacitance
construction,
electrical
conductivity
optimization.
In
addition,
optimization
strategies
preparing
wood-like
structures
(e.g.,
3D
printing,
freeze-drying,
aligned-low
tortuosity
channels)
also
discussed
in
detail.
Further,
this
presents
current
challenges
future
trends
structures.
As
guideline,
brilliant
blueprint
will
promote
sustainable
structure
broaden
application
scopes.
Chemical Society Reviews,
Journal Year:
2020,
Volume and Issue:
49(18), P. 6666 - 6693
Published: Jan. 1, 2020
MXenes
refer
to
a
family
of
2D
transition
metal
carbides/nitrides
that
are
rich
in
chemistry.
The
first
member
the
family,
Ti3C2Tx,
was
reported
2011.
Since
then
have
opened
up
an
exciting
new
field
inorganic
functional
materials
by
virtue
their
intrinsic
electronic
conductivity,
superior
hydrophilicity,
surface
chemistry
and
layered
structure,
as
evidenced
fact
number
papers
on
has
increased
exponentially.
unique
properties
ease
processing
positioned
them
promising
for
variety
applications
including
energy
storage,
especially
supercapacitors.
In
this
review,
we
aim
summarize
current
advances
MXene
research
We
begin
reviewing
various
fabrication
routes
influence
structure
MXenes.
properties,
stability,
species
introduced.
focus
turns
capacitive
energy-storage
mechanisms
factors
determining
electrochemical
behavior
performance
Besides,
types
MXene-based
supercapacitors
summarized
highlight
significance
constructing
storage
devices.
Finally,
challenges
prospects
booming
proposed
promote
further
development
Advanced Functional Materials,
Journal Year:
2021,
Volume and Issue:
31(22)
Published: March 8, 2021
Abstract
In
recent
decades,
flexible
and
wearable
devices
have
been
extensively
investigated
due
to
their
promising
applications
in
portable
mobile
electronics
human
motion
monitoring.
MXene,
a
novel
growing
family
of
2D
nanomaterials,
demonstrates
superiorities
such
as
outstanding
electrical
conductivity,
abundant
terminal
groups,
unique
layered‐structure,
large
surface
area,
hydrophilicity,
making
it
be
potential
candidate
material
for
devices.
Numerous
pioneering
works
are
devoted
develop
MXene‐based
composites
with
various
functions
designed
structures.
Therefore,
the
latest
progress
is
summarized
this
review,
focusing
on
preparation
strategies,
working
mechanisms,
performances,
sensors,
supercapacitors,
electromagnetic
interference
shielding
materials.
Moreover,
current
challenges
future
outlooks
also
discussed.
ACS Nano,
Journal Year:
2021,
Volume and Issue:
16(1), P. 1150 - 1159
Published: Dec. 27, 2021
Two-dimensional
materials,
especially
the
newly
emerging
MXene,
have
attracted
numerous
interests
in
fields
of
energy
conversion/storage
and
electromagnetic
shielding/absorption.
However,
inherently
inevitable
aggregation
absence
magnetic
loss
MXene
considerably
limit
its
absorption
application.
The
introduction
component
favorable
structural
engineering
are
alternatives
to
improve
microwave
(MA)
performance.
Herein,
we
report
a
spheroidization
strategy
assemble
double-shell
MXene@Ni
microspheres,
where
commonly
lamellar
reshaped
into
three-dimensional
microspheres
that
provide
substrate
for
oriented
growth
Ni
nanospikes.
Whereas
this
feature
offers
massive
accessible
active
surfaces
effectively
promote
dielectric
ability,
nanospikes
enables
additional
capacity.
Benefiting
from
these
merits,
synthesized
3D
exhibit
superior
MA
performance
with
minimum
reflection
value
-59.6
dB
at
an
ultrathin
thickness
(∼1.5
mm)
effective
bandwidth
4.48
GHz.
Moreover,
electron
holography
results
reveal
high-density
anisotropy
magnetism
plays
important
role
improvement
performance,
which
provides
insight
design
MXene-based
materials
as
high-efficient
absorbers.
Materials Today,
Journal Year:
2021,
Volume and Issue:
48, P. 214 - 240
Published: March 18, 2021
Since
the
discovery
of
two-dimensional
(2D)
transition
metal
carbides
and
nitrides,
known
as
MXenes,
research
on
these
wonder
2D
inorganic
compounds
has
become
increasingly
intensified
with
their
members
quickly
expanding.
MXenes'
state-of-the-art
applications
are
heavily
dependent
processing
strategies
manufacturing
methods.
Nevertheless,
solution
MXenes
not
been
comprehensively
reviewed.
This
review
summarizes
progress
regarding
over
past
decade
well
outlines
key
perspectives
for
future
scalable
strategies.
Etching
MAX
phases
delamination
MXene
briefly
introduced.
Rheological
properties
dispersions
wetting
inks,
which
crucial
achievement
high-resolution
printing
homogeneous
coating,
discussed
in
detail.
We
have
ink
formulation
fine-tuning
to
match
that
targeted
substrates
yield
efficient
yet
high-quality
printed/coated
films/structures.
As
such,
we
demonstrate
a
"map
guidelines"
solution-based
toward
high-performance
applications,
such
electrochemical
energy
storage,
conductive
electrodes,
electromagnetic
interference
shielding,
so
on.
Advanced Functional Materials,
Journal Year:
2021,
Volume and Issue:
31(21)
Published: March 5, 2021
Abstract
Lithium–sulfur
(Li–S)
batteries
with
a
theoretical
energy
density
of
2567
Wh
kg
−1
are
very
promising
next‐generation
storage
systems,
but
suffer
from
the
insulativity
sulfur
and
Li
2
S,
shuttle
effect
due
to
dissolution
migration
polysulfides,
lithium
dendrite
issue.
MXenes,
family
2D
transition
metal
carbides/nitrides,
which
have
metallic
conductivity,
structural
variety,
strong
chemical
adsorption
ability
effective
catalytic
for
fast
kinetics,
inducing
uniform
growth
Li,
exhibit
potential
high‐performance
Li–S
batteries.
In
this
review,
recent
progress
achievements
MXene‐based
summarized,
including
use
MXenes
in
cathode,
interlayer
between
cathode
separator,
anode.
The
architecture
construction
modification
as
well
hybridization
other
materials
demonstrated.
enhancement
on
electrochemical
performance
related
mechanisms
composites
discussed.
Finally,
challenges
perspectives
battery
application
also
given.
Nano-Micro Letters,
Journal Year:
2021,
Volume and Issue:
13(1)
Published: Oct. 11, 2021
Abstract
The
3D
hollow
hierarchical
architectures
tend
to
be
designed
for
inhibiting
stack
of
MXene
flakes
obtain
satisfactory
lightweight,
high-efficient
and
broadband
absorbers.
Herein,
the
NiCo
compound@MXene
networks
were
prepared
by
etching
ZIF
67
template
subsequently
anchoring
Ti
3
C
2
T
x
nanosheets
through
electrostatic
self-assembly.
electromagnetic
parameters
microwave
absorption
property
can
distinctly
or
slightly
regulated
adjusting
filler
loading
decoration
nanoflakes.
Based
on
synergistic
effects
multi-components
special
well-constructed
structure,
layered
double
hydroxides@Ti
(LDHT-9)
absorber
remarkably
achieves
unexpected
effective
bandwidth
(EAB)
6.72
GHz
with
a
thickness
2.10
mm,
covering
entire
Ku-band.
After
calcination,
transition
metal
oxide@Ti
(TMOT-21)
near
percolation
threshold
possesses
minimum
reflection
loss
(RL
min
)
value
−
67.22
dB
at
1.70
mm
within
only
5
wt%.
This
work
enlightens
simple
strategy
constructing
MXene-based
composites
achieve
absorbents
lightweight
tunable
EAB."Image
missing"
Advanced Functional Materials,
Journal Year:
2021,
Volume and Issue:
31(20)
Published: March 12, 2021
Abstract
2D
MXene
materials
have
attracted
intensive
attention
in
energy
storage
application.
However,
usually
undergoes
serious
face‐to‐face
restacking
and
inferior
stability,
significantly
preventing
its
further
commercial
Herein,
to
suppress
the
oxidation
self‐restacking
of
MXene,
an
efficient
fast
self‐assembly
route
prepare
a
3D
porous
oxidation‐resistant
MXene/graphene
(PMG)
composite
with
assistance
situ
sacrificial
metallic
zinc
template
is
demonstrated.
The
self‐assembled
architecture
can
effectively
prevent
layers
no
evident
variation
electrical
conductivity
air
at
room
temperature
after
two
months,
guaranteeing
outstanding
abundant
electrochemical
active
sites
accessible
electrolyte
ions.
Consequently,
PMG‐5
electrode
possesses
striking
specific
capacitance
393
F
g
−1
,
superb
rate
performance
(32.7%
10
V
s
),
cycling
stability.
Furthermore,
as‐assembled
asymmetric
supercapacitor
pronounced
density
50.8
Wh
kg
remarkable
stability
4.3%
deterioration
000
cycles.
This
work
paves
new
avenue
solve
long‐standing
significant
challenges
future.
