
Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 521, P. 216167 - 216167
Published: Aug. 29, 2024
Language: Английский
Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 521, P. 216167 - 216167
Published: Aug. 29, 2024
Language: Английский
Composites Part A Applied Science and Manufacturing, Journal Year: 2022, Volume and Issue: 165, P. 107362 - 107362
Published: Dec. 9, 2022
Language: Английский
Citations
249Materials Today, Journal Year: 2021, Volume and Issue: 50, P. 276 - 302
Published: June 17, 2021
Language: Английский
Citations
246Chemical Reviews, Journal Year: 2021, Volume and Issue: 122(1), P. 442 - 564
Published: Dec. 1, 2021
Synthetic chemists have developed robust methods to synthesize discrete molecules, linear and branched polymers, disordered cross-linked networks. However, two-dimensional polymers (2DPs) prepared from designed monomers been long missing these capabilities, both as objects of chemical synthesis in nature. Recently, new polymerization strategies characterization enabled the unambiguous realization covalently linked macromolecular sheets. Here we review 2DPs 2D methods. Three predominant emerged date, which produce either monolayers or multilayer assemblies. We discuss fundamental understanding scope each approaches, including: bond-forming reactions used, synthetic diversity prepared, their stacking behaviors, nanoscale mesoscale structures, macroscale morphologies. Additionally, describe analytical tools currently available characterize various isolated forms. Finally, emergent 2DP properties potential applications planar macromolecules. Throughout, highlight achievements identify opportunities for continued study.
Language: Английский
Citations
224Chemical Society Reviews, Journal Year: 2021, Volume and Issue: 50(20), P. 11381 - 11485
Published: Jan. 1, 2021
To date, nanotechnology has increasingly been identified as a promising and efficient means to address number of challenges associated with public health. In the past decade, two-dimensional (2D) biomaterials, unique nanoplatform planar topology, have attracted explosive interest in various fields such biomedicine due their morphology, physicochemical properties biological effect. Motivated by progress graphene biomedicine, dozens types ultrathin 2D biomaterials found versatile bio-applications, including biosensing, biomedical imaging, delivery therapeutic agents, cancer theranostics, tissue engineering, well others. The effective utilization stems from in-depth knowledge structure-property-bioactivity-biosafety-application-performance relationships. A comprehensive summary for is still lacking. this review, we aim concentrate on state-of-the-art particular focus applications. particular, discuss design, fabrication functionalization used diverse applications based up-to-date progress. Furthermore, interactions between systems spatial-temporal scale are highlighted, which will deepen understanding underlying action mechanism aiding design improved functionalities. Finally, taking bench-to-bedside focus, conclude review proposing current crucial issues/challenges presenting future development directions advance clinical translation these emerging biomaterials.
Language: Английский
Citations
206ACS Nano, Journal Year: 2023, Volume and Issue: 17(3), P. 1879 - 1905
Published: Jan. 30, 2023
Covalent organic frameworks (COFs) are a type of crystalline porous material with specific features and interesting structures, including porosity, large surface area, biocompatibility. These enable COFs to be considered as excellent candidates for applications in various fields. Recently, have been widely demonstrated promising materials biomedical because their physicochemical properties ultrathin structures. In this review, we cover the recent progress COF photodynamic therapy, gene delivery, photothermal drug bioimaging, biosensing, combined therapies. Moreover, critical challenges further perspectives regards future biology-facing also discussed.
Language: Английский
Citations
185Chemical Society Reviews, Journal Year: 2022, Volume and Issue: 51(4), P. 1377 - 1414
Published: Jan. 1, 2022
This review summarizes and discusses the recent progress in porous organic polymers for diverse biomedical applications such as drug delivery, biomacromolecule immobilization, phototherapy, biosensing, bioimaging, antibacterial applications.
Language: Английский
Citations
172Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 483, P. 215097 - 215097
Published: March 6, 2023
Language: Английский
Citations
160Advanced Materials, Journal Year: 2022, Volume and Issue: 34(17)
Published: Jan. 20, 2022
Abstract Covalent organic frameworks (COFs), an emerging class of crystalline polymers with highly oriented structures and permanent porosity, can adopt 2D or 3D architectures depending on the different topological diagrams monomers. Notably, COFs have particularly gained much attention due to extraordinary merits their extended in‐plane π‐conjugation topologically ordered columnar π‐arrays. These properties together high crystallinity, large surface area, tunable porosity distinguish as ideal candidate for fabrication functional materials. Herein, this review surveys recent research advances in special emphasis preparation COF powders, single crystals, thin films, well advanced optical, electrical, magnetic functionalities. Some challenging issues potential outlook are also provided promoting development terms structure, synthesis,
Language: Английский
Citations
159Advanced Healthcare Materials, Journal Year: 2021, Volume and Issue: 10(6)
Published: Jan. 21, 2021
Abstract Covalent organic frameworks (COFs) are porous polymeric materials that composed of elements and linked together by the thermodynamically stable covalent bonds. The applications COFs in energy sector drug delivery afforded because desirable properties COFs, such as high stability, low density, large surface area, multidimensionality, porosity, high‐ordered crystalline structure expanded. In this review reviewed, from perspective different types reported methods for their synthesis, potential biomedical field. main goal is to introduce a biomaterial identify specific advantages can be exploited specialized applications, immune engineering.
Language: Английский
Citations
147ACS Nano, Journal Year: 2023, Volume and Issue: 17(11), P. 9694 - 9747
Published: May 23, 2023
Two-dimensional (2D) material research is rapidly evolving to broaden the spectrum of emergent 2D systems. Here, we review recent advances in theory, synthesis, characterization, device, and quantum physics materials their heterostructures. First, shed insight into modeling defects intercalants, focusing on formation pathways strategic functionalities. We also machine learning for synthesis sensing applications materials. In addition, highlight important development processing, characterization various (e.g., MXnenes, magnetic compounds, epitaxial layers, low-symmetry crystals, etc.) discuss oxidation strain gradient engineering Next, optical phonon properties controlled by inhomogeneity give examples multidimensional imaging biosensing equipped with analysis based platforms. then provide updates mix-dimensional heterostructures using building blocks next-generation logic/memory devices anomalous Hall high-quality topological insulators, followed small twist-angle homojunctions exciting transport. Finally, perspectives future work several topics mentioned this review.
Language: Английский
Citations
145