A
knitted
aryl
network
polymer
(KAP)
containing
triptycene
and
triphenylphosphine
was
synthesized
by
a
simple
Friedel–Crafts
reaction.
The
(Tp_PPh3)
exhibits
good
physicochemical
stability
with
high
BET
surface
area
(>960
m2/g).
groups
were
incorporated
in
order
to
anchor
palladium
species
on
the
pristine
KAP
backbone
(Tp_PPh3).
Consequently,
metalation
of
Tp_PPh3
yielded
Pd@Tp_PPh3,
which
showed
catalytic
behavior
Suzuki–Miyaura
cross-coupling
reactions
yield
targeted
products
an
aerobic
environment,
using
water
ethanol
as
green
solvents.
This
polymer-based
heterogeneous
catalyst
is
air/moisture
stable
can
be
easily
dispersed
reused
for
several
cycles
without
any
significant
loss
activity.
Even
at
low
loadings
(13.8
wt
%),
Pd@Tp_PPh3
catalyzed
rapid
conversions.
equally
useful
gram-scale
reactions.
strategy
avoids
aggregation
precipitation
Pd
simultaneously
ensures
more
sustainable
use
Suzuki
application
may
extended
other
Pd-catalyzed
Materials Advances,
Journal Year:
2021,
Volume and Issue:
3(2), P. 707 - 733
Published: Nov. 23, 2021
In
this
review,
we
discuss
the
progress
in
preparation
methods
and
diverse
applications
for
covalent
triazine
frameworks,
hypercrosslinked
polymers,
organic
conjugated
microporous
polymers.
Magnetochemistry,
Journal Year:
2023,
Volume and Issue:
9(4), P. 110 - 110
Published: April 20, 2023
Catalysts
play
a
critical
role
in
producing
most
industrial
chemicals
and
are
essential
to
environmental
remediation.
Under
the
demands
of
sustainable
development,
environment
protection,
cost-related
factors,
it
has
been
suggested
that
catalysts
sufficiently
separable
conveniently
recyclable
catalysis
process.
Magnetite
(Fe3O4)
nanomaterials
provide
possible
way
achieve
this
goal,
due
their
magnetism,
chemical
stability,
low
toxicity,
economic
viability,
etc.
Therefore,
Fe3O4-based
materials
emerging
as
an
important
solid
support
load
heterogeneous
immobilize
homogeneous
catalysts.
Moreover,
addition
magnetic
character
will
not
only
make
recovery
much
easier
but
also
possibly
endow
with
desirable
properties,
such
magnetothermal
conversion,
Lewis
acid,
mimetic
enzyme
activity,
Fenton
activity.
The
following
review
comprises
short
survey
recent
reports
catalytic
applications
materials.
It
contains
seven
sections,
introduction
into
theme,
remediation,
electrocatalysis,
organic
synthesis,
synthesis
biodiesel,
cancer
treatment,
conclusions
about
reported
research
perspectives
for
future
developments.
Elucidation
functions
mechanisms
Fe3O4
nanoparticles
(NPs)
these
may
benefit
acquisition
robust
affordable
protocols,
leading
good
activity
enhanced
recoverability.
Polymers,
Journal Year:
2022,
Volume and Issue:
14(2), P. 351 - 351
Published: Jan. 17, 2022
The
search
for
higher-quality
nanomaterials
medicinal
applications
continues.
There
are
similarities
between
electrospun
fibers
and
natural
tissues.
This
property
has
enabled
to
make
significant
progress
in
medical
applications.
However,
limited
tissue
scaffolding
When
nanoparticles
nanofibers
combined,
the
composite
material
can
perform
more
functions,
such
as
photothermal,
magnetic
response,
biosensing,
antibacterial,
drug
delivery
biosensing.
To
prepare
nanofiber
nanoparticle
hybrids
(NNHs),
there
two
primary
ways.
electrospinning
technology
was
used
produce
NNHs
a
single
step.
An
alternate
way
is
use
self-assembly
technique
create
fibers.
paper
describes
creation
of
from
routinely
biocompatible
polymer
composites.
Single-step
procedures
methodologies
discuss
preparation
NNHs.
It
combines
recent
research
discoveries
focus
on
application
release,
engineering
last
years.
Green Chemistry,
Journal Year:
2024,
Volume and Issue:
26(5), P. 2476 - 2504
Published: Jan. 1, 2024
Hypercrosslinked
polymers
and
the
resultant
carbon
materials
are
promising
platforms
for
CO
2
capture
conversion,
because
of
their
high
specific
surface
areas,
modifiable
accessible
functionalities.
Journal of Materials Chemistry B,
Journal Year:
2024,
Volume and Issue:
12(8), P. 2054 - 2069
Published: Jan. 1, 2024
Microporous
organic
polymers
(MOPs)
and
metal
oxide
hybrid
composites
are
considered
valuable
coating
materials
because
of
their
versatility
derived
from
the
synergistic
combination
MOPs'
inherent
dispersibility
distinctive
properties
oxides.
In
this
study,
we
present
synthesis
sea-urchin-like
MOPs
hybridised
with
silver
nanoparticles
(Ag
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 12, 2024
Abstract
Hybrid
capacitive
deionization
(HCDI)
emerges
as
a
burgeoning
electrochemical
desalination
technology
due
to
the
utilization
of
profitable
pseudocapacitive
reactions.
Although
tunable
organic
compounds
are
potential
faradaic
electrode
materials,
their
insufficient
active
sites
and
high
water‐solubility
restrict
practical
HCDI
applications.
Herein,
polymer
(PNDS)
is
proposed
with
diverse
redox‐active
for
deionization.
The
pronounced
molecular
aromaticity
strong
π‐electron
delocalization
not
only
endow
PNDS
framework
rigidity,
but
refine
its
electronic
structure
bolster
redox
activity
electron
affinity.
As
an
material,
demonstrates
substantial
capacitance
390
F
g
−1
sustains
long‐term
stability
at
96.3%
after
5000
cycles,
surpassing
reported
Na
+
‐capturing
electrodes.
In‐operando
monitoring
techniques
theoretical
calculations
reveal
efficient
capture
C═N
C═O
within
during
repeated
electrosorption
processes.
conceptual
demonstration,
high‐performance
device
equipped
exhibits
impressive
salt
removal
capacity
(66.4
mg
),
rapid
rate
(2.2
min
)
stable
regeneration
property.
More
importantly,
integrated
system
engineered
rapidly
repeatedly
treat
saltwater
resources
human
consumption
agricultural
irrigation,
highlighting
promising
prospects
high‐efficiency
