Enhancing electromagnetic wave absorption with core‐shell structured SiO2@MXene@MoS2 nanospheres DOI Creative Commons

Xuewen Jiang,

Qian Wang,

Limeng Song

et al.

Carbon Energy, Journal Year: 2024, Volume and Issue: 6(8)

Published: Feb. 15, 2024

Abstract Material composition and structural design are important factors influencing the electromagnetic wave (EMW) absorption performance of materials. To alleviate impedance mismatch attributed to high dielectric constant Ti 3 C 2 T x MXene, we have successfully synthesized core‐shell structured SiO @MXene@MoS nanospheres. This architecture, comprising as core, MXene intermediate layer, MoS outer shell, is achieved through an electrostatic self‐assembly method combined with a hydrothermal process. complex structure not only provides variety loss mechanisms that effectively dissipate energy but also prevents self‐aggregation nanosheets. Notably, synergistic combination highly conductive enables suitable composites, ensuring optimal matching. Therefore, nanospheres exhibit excellent EMW performance, featuring remarkable minimum reflection (RL min ) −52.11 dB (2.4 mm). It noteworthy these achieve ultra‐wide effective bandwidth (EAB) 6.72 GHz. work novel approach for designing synthesizing high‐performance absorbers characterized by “wide strong loss.”

Language: Английский

Green EMI shielding: Dielectric/magnetic “genes” and design philosophy DOI

Xi-Xi Wang,

Qi Zheng,

Yuan-Jin Zheng

et al.

Carbon, Journal Year: 2023, Volume and Issue: 206, P. 124 - 141

Published: Feb. 9, 2023

Language: Английский

Citations

179

Carbon‐Based Radar Absorbing Materials toward Stealth Technologies DOI Creative Commons

Seong‐Hwang Kim,

Seul‐Yi Lee, Yali Zhang

et al.

Advanced Science, Journal Year: 2023, Volume and Issue: 10(32)

Published: Sept. 21, 2023

Abstract Stealth technology is used to enhance the survival of military equipment in field surveillance, as it utilizes a combination techniques render itself undetectable by enemy radar systems. Radar absorbing materials (RAMs) are specialized reduce reflection (or absorption) signals provide stealth capability, which core component passive countermeasures applications. The properties RAMs can be optimized adjusting their composition, microstructure, and surface geometry. Carbon‐based present promising approach for fabrication ultrathin, versatile, high‐performance due large specific area, lightweight, excellent dielectric properties, high electrical conductivity, stability under harsh conditions. This review begins with brief history an introduction electromagnetic waves, systems, materials. followed discussion recent research progress carbon‐based RAMs, including carbon blacks, fibers, nanotubes, graphite, graphene, MXene, along in‐depth examination principles strategies on attenuation characteristics. Hope this will offer fresh perspectives design thereby fostering deeper fundamental understanding promoting practical

Language: Английский

Citations

177

Synergistic Dielectric–Magnetic Enhancement via Phase‐Evolution Engineering and Dynamic Magnetic Resonance DOI
Panbo Liu, Guozheng Zhang,

Hanxiao Xu

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(13)

Published: Jan. 29, 2023

Abstract Dielectric polarization and magnetic resonance associated with intrinsic constituent extrinsic structure are two kinds of fundamental attenuation mechanisms for microwave absorbers, but remain extremely challenging in revealing the composition‐morphology‐performance correlation. Herein, hierarchical MXene/metal‐organic framework derivatives coherent boundaries units below critical grain size constructed to realize synergistic dielectric–magnetic enhancement by phase‐evolution engineering dynamic resonance. Specifically, induced inseparable interfaces, diverse incompatible phases, defects/vacancies contribute dielectric polarization, while closely distributed simultaneously nanoscale multi‐domain coupling long‐range interaction. As results, promise an exceptional reflection loss −59.5 dB effective absorption bandwidth 6.1 GHz. Both experimental results theoretical calculations indicate that maximize capability demonstrate a versatile methodology manipulating attenuation. More importantly, proposed interaction theories innovatively offer mechanism within size.

Language: Английский

Citations

174

Synthesis of CuCo2S4@Expanded Graphite with crystal/amorphous heterointerface and defects for electromagnetic wave absorption DOI Creative Commons

Zhimeng Tang,

Lei Xu,

Cheng Xie

et al.

Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)

Published: Sept. 23, 2023

The remarkable advantages of heterointerface and defect engineering their unique electromagnetic characteristics inject infinite vitality into the design advanced carbon-matrix wave absorbers. However, understanding interface dipole effects based on microscopic macroscopic perspectives, rather than semi-empirical rules, can facilitate heterointerfaces defects to adjust impedance matching absorption material, which is currently lacking. Herein, CuCo2S4@Expanded Graphite heterostructure with multiple cation are reported, morphology, interfaces component regulated by varying concentration metal ions. results show that 3D flower-honeycomb crystal-crystal/amorphous abundant effectively conductive polarization losses, achieve balance carbon materials, improve wave. For sample CEG-6, effective Ku band RLmin -72.28 dB bandwidth 4.14 GHz realized at 1.4 mm, while filler loading only 7.0 wt. %. This article reports establishment potential relationship between heterointerfaces, defects, materials.

Language: Английский

Citations

165

CrN attached multi-component carbon nanotube composites with superior electromagnetic wave absorption performance DOI

Lifu Sun,

Qianqian Zhu, Zirui Jia

et al.

Carbon, Journal Year: 2023, Volume and Issue: 208, P. 1 - 9

Published: March 9, 2023

Language: Английский

Citations

129

Hollow Gradient-Structured Iron-Anchored Carbon Nanospheres for Enhanced Electromagnetic Wave Absorption DOI Creative Commons

Cao Wu,

Jing Wang, Xiaohang Zhang

et al.

Nano-Micro Letters, Journal Year: 2022, Volume and Issue: 15(1)

Published: Dec. 6, 2022

In the present paper, a microwave absorber with nanoscale gradient structure was proposed for enhancing electromagnetic absorption performance. The inorganic–organic competitive coating strategy employed, which can effectively adjust thermodynamic and kinetic reactions of iron ions during solvothermal process. As result, Fe nanoparticles be gradually decreased from inner side to surface across hollow carbon shell. results reveal that it offers an outstanding reflection loss value in combination broadband wave flexible adjustment ability, is superior other relative graded distribution structures satisfied requirements lightweight equipment. addition, this work elucidates intrinsic regulation mechanism multiscale hybrid absorber. excellent impedance matching moderate dielectric parameters are exhibited dominative factors promotion performance optimized materials. This prepare gradient-distributed absorbing materials initiates new way designing fabricating property practical applications.

Language: Английский

Citations

112

Metal–Organic Gel Leading to Customized Magnetic-Coupling Engineering in Carbon Aerogels for Excellent Radar Stealth and Thermal Insulation Performances DOI Creative Commons
Xin Li,

Ruizhe Hu,

Zhiqiang Xiong

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 16(1)

Published: Dec. 4, 2023

Metal-organic gel (MOG) derived composites are promising multi-functional materials due to their alterable composition, identifiable chemical homogeneity, tunable shape, and porous structure. Herein, stable metal-organic hydrogels prepared by regulating the complexation effect, solution polarity curing speed. Meanwhile, collagen peptide is used facilitate fabrication of a aerogel with excellent physical properties as well homogeneous dispersion magnetic particles during calcination. Subsequently, two kinds heterometallic coupling systems obtained through application Kirkendall effect. FeCo/nitrogen-doped carbon (NC) demonstrates an ultra-strong microwave absorption - 85 dB at ultra-low loading 5%. After reducing time taken atom shifting, FeCo/Fe

Language: Английский

Citations

103

MnO2 Intercalation-Guided impedance tuning of Carbon/Polypyrrole double conductive layers for electromagnetic wave absorption DOI
Lipeng Wu, Han Gao, Ronghui Guo

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 460, P. 141749 - 141749

Published: Feb. 7, 2023

Language: Английский

Citations

98

Flexible Nanocomposite Conductors for Electromagnetic Interference Shielding DOI Creative Commons
Ze Nan, Wei Wei, Zhenhua Lin

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: July 7, 2023

Highlights Convincing candidates of flexible (stretchable/compressible) electromagnetic interference shielding nanocomposites are discussed in detail from the views fabrication, mechanical elasticity and performance. Detailed summary relationship between deformation materials The future directions challenges developing (particularly elastic) highlighted. Abstract With extensive use electronic communication technology integrated circuit systems wearable devices, (EMI) has increased dramatically. shortcomings conventional rigid EMI include high brittleness, poor comfort, unsuitability for conforming deformable applications. Hitherto, have attracted enormous interest due to their excellent deformability. However, current present low stability resilience, relatively performance, limited multifunctionality. Herein, advances low-dimensional nanomaterials-based elastomers outlined a selection most remarkable examples is discussed. And corresponding modification strategies deformability performance summarized. Finally, expectations this quickly increasing sector discussed, as well challenges.

Language: Английский

Citations

97

Structure–Activity Relationship in Microstructure Design for Electromagnetic Wave Absorption Applications DOI Creative Commons

Jiani Du,

Li Tian,

Zhengkang Xu

et al.

Small Structures, Journal Year: 2023, Volume and Issue: 4(11)

Published: Aug. 8, 2023

Microwave absorbing materials (MAMs) are that effectively absorb incident electromagnetic (EM) wave energy, reducing reflection and scattering. They play a crucial role in enhancing electronic reliability, healthcare, defense security. However, traditional MAMs like ferrites, magnetic metals, polymers possess certain limitations, including low impedance matching, narrow absorption bandwidth, poor chemical stability, high filling ratio, which hinder their further development. To address the requirements of lightweight, wideband, high‐efficiency absorption, precise structural design has emerged as captivating research focus. Additionally, comprehending structure – property relationships between these unique microstructures EM response loss mechanisms still poses significant challenges. Herein, comprehensive review is presented with varied designs encompassing various scales, providing detailed introduction relationship potential corresponding characteristics mechanisms. Moreover, theoretical calculation models, characterization, analysis methods discussed. Finally, article proposes challenges prospects for development absorbers.

Language: Английский

Citations

93