Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 667, P. 166 - 174
Published: April 15, 2024
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 667, P. 166 - 174
Published: April 15, 2024
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 685, P. 196 - 204
Published: Jan. 10, 2025
Language: Английский
Citations
1Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 4, 2025
Abstract Metal oxyhydroxides (MOOHs) as the active phase of transition metal‐oxide (TMOs) electrodes in oxygen evolution reaction (OER) are limited by unsatisfactory electrochemical activity and stability during high‐current conditions. Herein, heterostructure high‐valent IrO x (Ir n+ , n>4) combined with FeNi 3 OOH via asymmetric electron transport is deliberately designed on carbon cloth (IrO ‐FeNi OOH/CC) a promising OER electrocatalyst for industrial deployments. Experimental DFT calculations reveal that transfer from Ir to low‐spin orbital Fe/Ni sites bridged O 2− (Ir─O─Ni/Fe bonds) at interfaces induces formation species. This process tailors d‐band center sites, thereby reducing energy barrier rate‐determining step * OER. The elevated enables OOH/CC achieve an ultra‐low overpotential 241 mV 200 mA cm −2 along remarkable 160 h under large current conditions (outperforming commercial 2 /CC). work offers basis rationally designing analyzing potential role precious‐metal‐based electrocatalysts related processes.
Language: Английский
Citations
1International Journal of Hydrogen Energy, Journal Year: 2023, Volume and Issue: 48(57), P. 21723 - 21734
Published: March 23, 2023
Language: Английский
Citations
18Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 479, P. 147723 - 147723
Published: Nov. 30, 2023
Language: Английский
Citations
17Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 667, P. 166 - 174
Published: April 15, 2024
Language: Английский
Citations
8