Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 498, P. 155276 - 155276
Published: Aug. 31, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 498, P. 155276 - 155276
Published: Aug. 31, 2024
Language: Английский
Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(8), P. 3997 - 4007
Published: Feb. 17, 2024
The electrochemical extraction of lithium (Li) from aqueous sources using means is a promising direct Li technology. However, to this date, most studies are confined Li-rich brine, neglecting the practical and existing Li-lean resources, with their overall behaviors currently not fully understood. More still, effect elevated sodium (Na) concentrations typically found in water on unclear. Hence, work, we first understand ultradilute solutions spinel manganese oxide as model electrode. We discovered that depends highly concentration cell operation current density. Then, switched our focus low Na ratio solutions, revealing can dominate electrostatic screening layer, reducing ion concentration. Based these understandings, rationally employed pulsed restructure electrode surface distribute surface-adsorbed species, which efficiently achieves high selectivity even extremely initial Li/Na up 1:20,000.
Language: Английский
Citations
18Materials Horizons, Journal Year: 2024, Volume and Issue: 11(12), P. 2974 - 2985
Published: Jan. 1, 2024
A 2D redox-active pyrazine-based COF was solvent-free anchored on graphene for heterointerface regulation, displaying exciting energy storage and desalination performances.
Language: Английский
Citations
18Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 12, 2024
Abstract Hybrid capacitive deionization (HCDI) emerges as a burgeoning electrochemical desalination technology due to the utilization of profitable pseudocapacitive reactions. Although tunable organic compounds are potential faradaic electrode materials, their insufficient active sites and high water‐solubility restrict practical HCDI applications. Herein, polymer (PNDS) is proposed with diverse redox‐active for deionization. The pronounced molecular aromaticity strong π‐electron delocalization not only endow PNDS framework rigidity, but refine its electronic structure bolster redox activity electron affinity. As an material, demonstrates substantial capacitance 390 F g −1 sustains long‐term stability at 96.3% after 5000 cycles, surpassing reported Na + ‐capturing electrodes. In‐operando monitoring techniques theoretical calculations reveal efficient capture C═N C═O within during repeated electrosorption processes. conceptual demonstration, high‐performance device equipped exhibits impressive salt removal capacity (66.4 mg ), rapid rate (2.2 min ) stable regeneration property. More importantly, integrated system engineered rapidly repeatedly treat saltwater resources human consumption agricultural irrigation, highlighting promising prospects high‐efficiency
Language: Английский
Citations
18Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 336, P. 126300 - 126300
Published: Jan. 7, 2024
Language: Английский
Citations
17ACS Nano, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 4, 2025
Capacitive deionization (CDI) is a green and promising technology for seawater desalination, with its capacity industrial application being severely hindered by efficient electrode materials. Layered molybdenum disulfide (MoS2) has garnered significant attention CDI applications, while performance hampered weak surface hydrophilicity, high interfacial resistance, sluggish electron transport. Herein, we introduce an intercalation dual-engineering strategy covalently functionalizing the hydrophilic pyridine groups within 1T-MoS2 layer (Py-MoS2); electron-rich interface expanded interlayer spacing been achieved synergistically. A state-of-the-art desalination of 43.92 mg g-1 exceptional cycling stability have achieved, surpassing all reported existing MoS2-based electrodes. Comprehensive characterization theoretical modeling reveal that engineered enhance ion affinity via coordination, accelerate charge transfer, expand ion-accessible sites MoS2 through intercalation-induced structural modulation. These synergistic effects dramatically boost adsorption kinetics, mass transfer efficiency, salt uptake Py-MoS2 application. Our work presents to promote 2D materials, paving new insights next-generation high-performance development.
Language: Английский
Citations
4Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162289 - 162289
Published: Jan. 1, 2025
Language: Английский
Citations
2Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 478, P. 147270 - 147270
Published: Nov. 16, 2023
Language: Английский
Citations
36Desalination, Journal Year: 2023, Volume and Issue: 571, P. 117107 - 117107
Published: Oct. 29, 2023
Language: Английский
Citations
30Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 332, P. 125797 - 125797
Published: Nov. 20, 2023
Language: Английский
Citations
29Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 480, P. 147986 - 147986
Published: Dec. 13, 2023
Language: Английский
Citations
24