Induced Anionic Functional Group Orientation‐Assisted Stable Electrode‐Electrolyte Interphases for Highly Reversible Zinc Anodes DOI
Jingyi Wang, Yi Yu, Ruwei Chen

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(25)

Published: April 26, 2024

Abstract Dendrite growth and other side‐reaction problems of zinc anodes in aqueous zinc‐ion batteries heavily affect their cycling lifespan Coulombic efficiency, which can be effectively alleviated by the application polymer‐based functional protection layer on anode. However, utilization rate groups is difficult to improve without destroying polymer chain. Here, a simple well‐established strategy proposed controlling orientation (─SO 3 H) assist optimization anodes. Depending electrostatic effect, surface‐enriched ─SO H increase ionic conductivity homogenize Zn 2+ flux while inhibiting anionic permeation. This approach avoids destruction backbone over‐sulfonation amplifies effect groups. Therefore, modified sulfonated polyether ether ketone (H‐SPEEK) coating‐optimized anode capable longtime stable plating/stripping, moreover an enhanced steadiness under high current densities also detected series with different cathode materials, achieved inclusion H‐SPEEK coating causing any harmful effects electrolyte cathode. work provides easy efficient further optimize plating/stripping cations metal electrodes, sheds lights scale‐up high‐performance battery technology.

Language: Английский

Recent progress on general wearable electrical heating textiles enabled by functional fibers DOI

Faqiang Wang,

Yiming Liu, Jianyong Yu

et al.

Nano Energy, Journal Year: 2024, Volume and Issue: 124, P. 109497 - 109497

Published: March 16, 2024

Language: Английский

Citations

31
Enabling and Boosting Preferential Epitaxial Zinc Growth via Multi‐Interface Regulation for Stable and Dendrite‐Free Zinc Metal Batteries DOI
Yangyang Wang,

Tiantian Ren,

Zeping Wang

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(26)

Published: April 21, 2024

Abstract The practical application of aqueous Zn‐metal anodes (AZMAs) is mainly impeded by the short cycling life and unsatisfactory reversibility springing from notorious Zn dendrite growth detrimental water‐induced parasitic reactions at anode‐electrolyte interface. To tackle these challenges, a multifunctional interface Sn‐modified Ti 3 C 2 Cl MXene (denoted as Sn‐MXene) with high zincophilic hydrophobic properties rationally designed via 1‐step strategy novel molten salt etching to achieve dendrite‐free deposition. Experimental results theoretical calculations reveal that Sn nanoparticles can induce strongly surface 2+ adsorption, significantly decreases energy (002) plane, guiding zinc‐preferred orientation along plane in electroplating process. Moreover, ‐Cl terminations protective for anode regulate Zn‐ion solvation structure mitigate H O‐decomposition‐induced side reactions, guarantee steady stream flux. Encouragingly, benefiting Sn‐MXene layer, reaction‐free an excellent lifespan achieved, which further applied full battery (Sn‐MXene‐Zn// α ‐MnO ) long‐term span over 800 cycles under 1 A g –1 capacity retention 96%.

Language: Английский

Citations

29
Non‐Metal Ion Storage in Zinc‐Organic Batteries DOI Creative Commons
Ziyang Song, Ling Miao, Yaokang Lv

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(19)

Published: March 13, 2024

Abstract Zinc‐organic batteries (ZOBs) are receiving widespread attention as up‐and‐coming energy‐storage systems due to their sustainability, operational safety and low cost. Charge carrier is one of the critical factors affecting redox kinetics electrochemical performances ZOBs. Compared with conventional large‐sized sluggish Zn 2+ storage, non‐metallic charge carriers small hydrated size light weight show accelerated interfacial dehydration fast reaction kinetics, enabling superior metrics for Thus, it valuable ongoing works build better ZOBs ion storage. In this review, versatile cationic (H + , NH 4 ) anionic (Cl − OH CF 3 SO 2− first categorized a brief comparison respective physicochemical properties chemical interactions redox‐active organic materials. Furthermore, work highlights implementation effectiveness ions in ZOBs, giving insights into impact types on (capacity, rate capability, operation voltage, cycle life) cathodes. Finally, challenges perspectives non‐metal‐ion‐based outlined guild future development next‐generation energy communities.

Language: Английский

Citations

28
Uncovering Se, P co-doping effect in MnO2 toward high-performance aqueous zinc-ion batteries DOI

Kaixuan Ma,

Suyu Ge,

Ruru Fu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 484, P. 149525 - 149525

Published: Feb. 12, 2024

Language: Английский

Citations

25
In-situ constructed interface buffer layer enabled highly reversible Zn Deposition/Stripping for long-lifespan aqueous zinc metal anodes DOI
Zhou Li, Weibin Zhou, Hongrui Wang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 492, P. 152324 - 152324

Published: May 17, 2024

Language: Английский

Citations

21
Biomass Chitin Nanofiber Separators Proactively Stabilizing Zinc Anodes for Dendrite‐Free Aqueous Zinc‐Ion Batteries DOI

Qunhao Wang,

Jiangqi Zhao, Jian Zhang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: July 5, 2024

Abstract Aqueous zinc‐ion batteries (ZIBs) have generated extensive research attention for stationary energy storage, due to their advantaged superiority in terms of inherent safety, low cost, and eco‐friendliness. However, uncontrollable dendrite growth side reactions the Zn anode affect cycle life ZIBs. Conventional separators are almost ineffective inhibiting these issues. Herein, a chitin nanofiber membrane separator is developed tackle issues via simple, low‐cost, scalable strategy. The obtained exhibits abundant zincophilic functional groups, homogeneous nanopores, excellent mechanical properties, which facilitate desolvation hydrated 2+ ions, improve transference number, homogenize ion flux, simultaneously. Moreover, can also reduce deposition barrier, accelerate kinetics. Therefore, dendrites harmful effectively synchronously suppressed, enabling assembled ZIBs with an ultralong good rate capability. Impressively, Zn‐MnO 2 pouch cell stability safety under various external damages. above highlights mark significant step toward practical application

Language: Английский

Citations

21
Enhancing Zinc Anode Stability with Gallium Ion‐Induced Electrostatic Shielding and Oriented Plating DOI
Jin Cao, Yan Jin, Haiyang Wu

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 16, 2024

Abstract The cost‐effectiveness and environmental benefits of aqueous zinc‐ion batteries (ZIBs) have attracted considerable attention. However, practical applications are hindered by side processes including dendritic growth hydrogen evolution corrosion. Herein, gallium ions (Ga 3+ ) been chosen as a multifunctional electrolyte additive to improve the reversibility (ZIBs). Remarkably, Ga adhere anode surface, establishing dynamic electrostatic shielding layer that modulates Zn 2+ deposition prevents reactions. Typically, preferentially adsorb onto (002) (110) planes Zn, facilitating preferential on (100) plane, resulting in dendrites‐free zinc anode. Consequently, Zn||Zn symmetrical cell with ‐modified demonstrates prolonged lifespan 4000 h, while Zn||Ti asymmetric exhibits an impressive coulombic efficiency 99.12% for stripping plating at 2 mA cm −2 . Additionally, Zn||VO maintains high capacity retention after 1500 cycles 5 A g −1 This work presents additive, development durable effect plane electroplating, ensuring free from dendrite formation. Such discoveries form basis future investigations into novel materials propel advancements metal battery technology.

Language: Английский

Citations

21
Blocking the Dendrite‐Growth of Zn Anode by Constructing Ti4O7 Interfacial Layer in Aqueous Zinc‐Ion Batteries DOI
Yang Song, Yongduo Liu,

Shijian Luo

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(25)

Published: Feb. 9, 2024

Abstract Zinc metal is a promising choice as high‐capacity and cost‐effective anode for aqueous zinc‐based batteries. However, it faces challenges related to low cycling stability poor reversibility due parasitic reactions the growth of zinc dendrites. In this study, solution proposed by introducing conductive Ti 4 O 7 layer on enhance electrode stability. The serves dual purpose, effectively preventing spontaneous corrosion in electrolyte, thereby inhibiting hydrogen evolution reaction generation byproducts. Simultaneously, promotes Zn nucleation ensures uniform electric field distribution, resulting homogeneous plating stripping compared using bare anode. Consequently, ‐coated experiences significant reduction over‐potential, demonstrating long‐term dendrite‐free behavior. This outcome polarization potential high zinc‐ion work underscores oxides development stable electrodes.

Language: Английский

Citations

20
Channel engineering strategy of precisely modified MOF/nanofiber composite separator for advanced aqueous zinc ion batteries DOI
Chunyu Liu, Yidi Wang, Hongqi Liu

et al.

Composites Part B Engineering, Journal Year: 2024, Volume and Issue: 272, P. 111227 - 111227

Published: Jan. 11, 2024

Language: Английский

Citations

17
Outer Sphere Electron Transfer Enabling High-Voltage Aqueous Electrolytes DOI
Fan Zhang, Ting Liao, Hong Peng

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(15), P. 10812 - 10821

Published: March 11, 2024

Aqueous electrolytes with a low voltage window (1.23 V) and prone side reactions, such as hydrogen evolution reaction cathode dissolution, compromise the advantages of high safety cost aqueous metal-ion batteries. Herein, introducing catechol (CAT) into electrolyte, an outer sphere electron transfer mechanism is initiated to inhibit water reactivity, achieving electrochemical 3.24 V. In typical Zn-ion battery, electrons jump from CAT Zn2+-H2O at geometrically favorable situation between solvation molecules without breaking or forming chemical bonds that inner transfers. The excited state π–π stacking further leads occurring electrolyte/electrode interface. This high-voltage electrolyte allows operating two times higher than usual provides almost highest energy density power for V2O5-based full Zn//Zn symmetric battery delivers 4000 h lifespan, Zn//V2O5 achieves ∼380 W kg–1 92% capacity retention after 3000 cycles 1 A g–1 2.4 V output voltage. strategy paves way designing electrolytes.

Language: Английский

Citations

17