Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(25)
Published: April 26, 2024
Abstract
Dendrite
growth
and
other
side‐reaction
problems
of
zinc
anodes
in
aqueous
zinc‐ion
batteries
heavily
affect
their
cycling
lifespan
Coulombic
efficiency,
which
can
be
effectively
alleviated
by
the
application
polymer‐based
functional
protection
layer
on
anode.
However,
utilization
rate
groups
is
difficult
to
improve
without
destroying
polymer
chain.
Here,
a
simple
well‐established
strategy
proposed
controlling
orientation
(─SO
3
H)
assist
optimization
anodes.
Depending
electrostatic
effect,
surface‐enriched
─SO
H
increase
ionic
conductivity
homogenize
Zn
2+
flux
while
inhibiting
anionic
permeation.
This
approach
avoids
destruction
backbone
over‐sulfonation
amplifies
effect
groups.
Therefore,
modified
sulfonated
polyether
ether
ketone
(H‐SPEEK)
coating‐optimized
anode
capable
longtime
stable
plating/stripping,
moreover
an
enhanced
steadiness
under
high
current
densities
also
detected
series
with
different
cathode
materials,
achieved
inclusion
H‐SPEEK
coating
causing
any
harmful
effects
electrolyte
cathode.
work
provides
easy
efficient
further
optimize
plating/stripping
cations
metal
electrodes,
sheds
lights
scale‐up
high‐performance
battery
technology.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 20, 2024
Aqueous
zinc
ion
batteries
(AZIBs)
are
experiencing
rapid
development
due
to
their
high
theoretical
capacity,
abundant
resources,
and
intrinsic
safety.
However,
the
progress
of
AZIBs
is
hindered
by
uncontrollable
parasitic
reactions
excessive
dendrite
growth,
which
compromise
durability
effective
utilization
metal
anodes.
To
address
these
challenges,
study
has
constructed
a
3D
crosslinked
macromolecular
network
composed
ion-bonded
potato
starch
(StZ)
as
an
interface
layer
on
Zn
foil
(StZ-Zn)
inhibit
hydrogen
evolution,
regulate
Advanced Energy Materials,
Journal Year:
2023,
Volume and Issue:
13(44)
Published: Oct. 11, 2023
Abstract
Zinc‐ion
batteries
with
chalcogen‐based
(S,
Se,
Te)
cathodes
have
emerged
as
a
promising
candidate
for
utility‐scale
energy
storage
systems
and
portable
electronics,
which
attracted
rapid
attention
offer
tremendous
opportunities
owing
to
their
excellent
density,
on
top
of
the
advantages
aqueous
Zn
including
cost‐effectiveness,
inherent
safety,
eco‐friendliness.
Here,
comprehensive
overview
basic
mechanism
zinc–chalcogen
great
intrinsic
issues
is
provided.
More
detailed
recent
progress
summarized
existing
challenges
strategies
are
provided
well.
First,
four
specific
types
presented,
including:
zinc–sulfur,
zinc–selenium,
zinc–selenium
sulfide,
zinc–tellurium
batteries.
Second,
remaining
within
in
material
preparation,
physicochemical
properties,
battery
performance
discussed.
Meanwhile,
series
constructive
comprehensively
put
forward
optimizing
electrochemical
performance.
Finally,
future
research
perspectives
proposed
exploration
innovation
next‐generation
green
zinc
applications.
Sustainable Energy & Fuels,
Journal Year:
2023,
Volume and Issue:
7(16), P. 3776 - 3795
Published: Jan. 1, 2023
This
review
presents
a
comprehensive
summary
of
recent
developments
in
zinc-ion
hybrid
capacitors
with
particular
emphasis
on
several
materials
and
design
strategies
developed
for
zinc
metal
anodes,
cathodes,
electrolytes.
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(25)
Published: April 26, 2024
Abstract
Dendrite
growth
and
other
side‐reaction
problems
of
zinc
anodes
in
aqueous
zinc‐ion
batteries
heavily
affect
their
cycling
lifespan
Coulombic
efficiency,
which
can
be
effectively
alleviated
by
the
application
polymer‐based
functional
protection
layer
on
anode.
However,
utilization
rate
groups
is
difficult
to
improve
without
destroying
polymer
chain.
Here,
a
simple
well‐established
strategy
proposed
controlling
orientation
(─SO
3
H)
assist
optimization
anodes.
Depending
electrostatic
effect,
surface‐enriched
─SO
H
increase
ionic
conductivity
homogenize
Zn
2+
flux
while
inhibiting
anionic
permeation.
This
approach
avoids
destruction
backbone
over‐sulfonation
amplifies
effect
groups.
Therefore,
modified
sulfonated
polyether
ether
ketone
(H‐SPEEK)
coating‐optimized
anode
capable
longtime
stable
plating/stripping,
moreover
an
enhanced
steadiness
under
high
current
densities
also
detected
series
with
different
cathode
materials,
achieved
inclusion
H‐SPEEK
coating
causing
any
harmful
effects
electrolyte
cathode.
work
provides
easy
efficient
further
optimize
plating/stripping
cations
metal
electrodes,
sheds
lights
scale‐up
high‐performance
battery
technology.
