Synthesis and electrochemical application of two-dimensional manganese-based materials DOI
Jing Hu, Panpan Tao,

Wenyu Fan

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(15), P. 4528 - 4551

Published: Jan. 1, 2024

Our review comprehensively covers the recent advancements in synthetic methods of manganese-based 2D nanomaterials, their electrochemical applications, and dives deep into mechanisms, challenges, future prospects.

Language: Английский

Oxygen radical coupling on short-range ordered V sites for enhanced oxygen evolution reaction activity DOI
Xiaoxiao Li, Yu Yan, Yuan Yao

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: 694, P. 162829 - 162829

Published: Feb. 28, 2025

Language: Английский

Citations

1
Noble Metal Phosphides: Robust Electrocatalysts toward Hydrogen Evolution Reaction DOI

Bingrong Guo,

Xinxin Wen,

Xu Li

et al.

Small Methods, Journal Year: 2023, Volume and Issue: unknown

Published: Dec. 31, 2023

Abstract Facing with serious carbon emission issues, the production of green H 2 from electrocatalytic hydrogen evolution reaction (HER) has received extensive research interest. Almost all kinds noble metal phosphides (NMPs) consisting Pt‐group elements (i.e., Ru, Rh, Pd, Os, Ir and Pt) are highly active pH‐universal electrocatalysts toward HER. In this review, recent progress NMP‐based HER is summarized. It further take typical examples for discussing important impact factors on performance NMPs, including crystalline phase, morphology, element doping. Moreover, synthesis application hybrid catalysts NMPs other materials such as transition phosphides, oxides, sulfides phosphates, metals also reviewed. Reducing use key idea electrocatalysts, while expanded functionality structure‐performance relationship noticed in part. At last, potential opportunities challenges kind catalyst discussed.

Language: Английский

Citations

21
Metal-Oxides- and Metal-Oxyhydroxides-Based Nanocomposites for Water Splitting: An Overview DOI Creative Commons

Tse-Wei Chen,

Shen‐Ming Chen, Ganesan Anushya

et al.

Nanomaterials, Journal Year: 2023, Volume and Issue: 13(13), P. 2012 - 2012

Published: July 5, 2023

Water electrolysis is an important alternative technology for large-scale hydrogen production to facilitate the development of green energy technology. As such, many efforts have been devoted over past three decades producing novel electrocatalysis with strong electrochemical (EC) performance using inexpensive electrocatalysts. Transition metal oxyhydroxide (OxH)-based electrocatalysts received substantial interest, and prominent results achieved evolution reaction (HER) under alkaline conditions. Herein, extensive research focusing on discussion OxH-based comprehensively highlighted. The general forms water-splitting mechanism are described provide a profound understanding mechanism, their scaling relation activities OxH electrode materials given. This paper summarizes current developments EC transition OxHs, rare polymers, MXene-supported Additionally, outline suggested HER, OER, processes electrocatalysts, primary applications, existing problems, prospects discussed. Furthermore, this review article discusses sources from proton electron transfer processes. highlighted interest boost synergetic effects improve economy use hydrogen, which one best ways fulfill global requirements address environmental crises. also provides useful information regarding electrodes hierarchical nanostructure reaction. Finally, challenges perspectives future elaborated.

Language: Английский

Citations

18
Achieving High‐Performance Electrocatalytic Water Oxidation on Ni(OH)2 with Optimized Intermediate Binding Energy Enabled by S‐Doping and CeO2‐Interfacing DOI Creative Commons
Xiang Chen, Xinyue Xu, Yuwen Cheng

et al.

Small, Journal Year: 2023, Volume and Issue: 20(8)

Published: Oct. 10, 2023

Abstract The adsorption energy of the reaction intermediates has a crucial influence on electrocatalytic activity. Ni‐based materials possess high oxygen evolution (OER) performance in alkaline, however too strong binding *OH and barrier rate‐determining step (RDS) severely limit their OER Herein, facile strategy is shown to fabricate novel vertical nanorod‐like arrays hybrid structure with interface contact S‐doped Ni(OH) 2 CeO situ grown Ni foam (S‐Ni(OH) /CeO /NF) through one‐pot route. alcohol molecules oxidation experiments theoretical calculations demonstrate that S‐doping ‐interfacing significantly modulate energies toward optimal value reduce RDS, contributing remarkable activity for S‐Ni(OH) /NF an ultralow overpotential 196 mV at 10 mA cm −2 long‐term durability over 150 h OER. This work offers efficient doping interfacing tune obtaining high‐performance electrocatalysts.

Language: Английский

Citations

17
Accelerating structure reconstruction to form NiOOH in metal–organic frameworks (MOFs) for boosting the oxygen evolution reaction DOI

Ruiyao Hou,

Xiaoxia Yang,

Linghui Su

et al.

Nanoscale, Journal Year: 2023, Volume and Issue: 15(46), P. 18858 - 18863

Published: Jan. 1, 2023

A localized structure disordering strategy was developed to accelerate the reconstruction of Ni-MOFs generate OER active NiOOH, resulting in excellent activity that exceeds most MOF-based catalysts reported previously.

Language: Английский

Citations

17
Electronic modulation of FeOOH coupled NiFe-LDH for highly efficient alkaline water oxidation at high current density DOI
Mengling Zhang,

Boxue Wang,

Huachuan Sun

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 60, P. 1215 - 1223

Published: Feb. 26, 2024

Language: Английский

Citations

7
Dual‐Mode Imaging of Dynamic Interaction between Bubbles and Single Nanoplates during the Electrocatalytic Hydrogen Evolution Process DOI

Xin Zhao,

Houkai Chen,

Yu Cui

et al.

Small, Journal Year: 2024, Volume and Issue: 20(33)

Published: March 29, 2024

Gas bubble formation at electrochemical interfaces can significantly affect the efficiency and durability of electrocatalysts. However, obtaining comprehensive details on evolution dynamics, particularly their dynamic interaction with high-performance structured electrocatalysts, poses a considerable challenge. Herein, dual-mode interference/total internal reflection fluorescence microscopy is introduced, which allows for simultaneous capture pathway bubbles 3D motion nanoplate providing high-resolution accurate spatiotemporal information. During hydrogen reaction, dynamics generation interactions single electrocatalysts interface are observed. The results unveiled that, under constant potential, initially manifest as fast-moving nanobubbles, transforming into stationary microbubbles subsequently. morphology nanoplates regulates trajectories these moving nanobubbles while pinned induce be employed to scrutinize numerous multiphase high resolution, facilitate rational design

Language: Английский

Citations

7
Crystalline metal phosphide-coated amorphous iron oxide-hydroxide (FeOOH) with oxygen vacancies as highly active and stable oxygen evolution catalyst in alkaline seawater at high current density DOI
Wei Yan,

Zhuang Shi,

Feng Hao

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 667, P. 362 - 370

Published: April 15, 2024

Language: Английский

Citations

7
Fe site regulation and activity deciphering by selective phase transformation in the confined FeNi nanoparticles for oxygen evolution reaction DOI

Zhouyang Ma,

Jiawei Wu,

Fuling Yang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 491, P. 152113 - 152113

Published: May 10, 2024

Language: Английский

Citations

7
Ultrathin heteroatom-doped CeO2 nanosheet assemblies for durable oxygen evolution: Oxygen vacancy engineering to trigger deprotonation DOI
Kunkun Nie,

Yanling Yuan,

Xiaoyan Qu

et al.

Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 656, P. 168 - 176

Published: Nov. 20, 2023

Language: Английский

Citations

14