Closed‐Loop Recyclable Silica‐Based Nanocomposites with Multifunctional Properties and Versatile Processability DOI Creative Commons
Yi Hou, Guangda Zhu, Samantha O. Catt

et al.

Advanced Science, Journal Year: 2023, Volume and Issue: 10(35)

Published: Oct. 16, 2023

Abstract Most plastics originate from limited petroleum reserves and cannot be effectively recycled at the end of their life cycle, making them a significant threat to environment human health. Closed‐loop chemical recycling, by depolymerizing into monomers that can repolymerized, offers promising solution for recycling otherwise wasted plastics. However, most current chemically recyclable polymers may only prepared gram scale, depolymerization typically requires harsh conditions high energy consumption. Herein, it reports less petroleum‐dependent closed‐loop silica‐based nanocomposites on large scale have fully reversible polymerization/depolymerization capability room temperature, based catalysis free aminopropyl groups with assistance diethylamine or ethylenediamine. The show glass‐like hardness yet plastic‐like light weight toughness, exhibiting highest specific mechanical strength superior even common materials such as poly(methyl methacrylate), glass, ZrO 2 ceramic, well demonstrating multifunctionality anti‐fouling, low thermal conductivity, flame retardancy. Meanwhile, these easily processed various scalable manufacturing methods, compression molding 3D printing. These are expected provide an alternative petroleum‐based contribute economy.

Language: Английский

Insights into the Effect of Segment Rearrangement Induced by Dynamic Disulfide Bond on UV Aging Resistance of UV-induced Self-compensated Epoxy Crosslinked Network DOI
Mingli Wang, Ziyu Liu, Tiancheng Wang

et al.

Polymer Degradation and Stability, Journal Year: 2025, Volume and Issue: unknown, P. 111352 - 111352

Published: March 1, 2025

Language: Английский

Citations

0

Structured Locomotive Magnetic Soft Robots DOI Creative Commons
Wenbo Liu,

Youzhou Yang,

Lingmin Liu

et al.

Published: March 31, 2025

ABSTRACT Locomotive magnetic soft robots have found broad applications in a variety of research fields, such as surgical instrumentation, drug delivery and physical rehabilitation, owing to their rapid responses, ease‐of‐control excellent deformability. Many previous reviews well addressed the material designs fabrication methods branches robots. Apart from above, structural engineering also plays vital role locomotion capabilities operational contexts. Therefore, this review focuses on structure‐induced modes robots, classifies them into one‐dimensional (1D), two‐dimensional (2D), three‐dimensional (3D) fluid‐type, according structure features. Particularly, specific enabled by are summarized detail, revealing closely correlated structure‐locomotion‐functionality relations. This concisely summarizes components polymeric matrices used for locomotive introduces mainstream methods, molding, additive manufacturing micro‐assembly. Finally, facing challenges relevant field discussed future prospects provided.

Language: Английский

Citations

0

Self‐Healing, Recyclable, Biodegradable, Electrically Conductive Vitrimer Coating for Soft Robotics DOI Creative Commons
Giulia Spallanzani, Maedeh Najafi, Muhammad Zahid

et al.

Advanced Sustainable Systems, Journal Year: 2023, Volume and Issue: 7(12)

Published: Sept. 10, 2023

Abstract Sensors and transducers enable the robots’ movements interactions with humans environment. Particularly, tactile motion sensors, even those inspired by human skin, often miss many of its essential features. Indeed, materials that constitute such sensors are rigid lack self‐healing biodegradability. Furthermore, large‐scale diffusion these technologies propelled robots spread in aspects lives, from industrial to household settings, contributes heavily electronic robotic waste problem. Recycling strategies for robotics thus pivotal future development. This work proposes self‐healable, recyclable, biodegradable electrically conductive coatings. These coatings based on inks combine graphene nanoplatelets carbon nanofibers a soft vitrimer binder realized spray coating. The use ensures satisfying adhesion diverse substrates, flexibility, conformability, self‐healing, recyclability material is sustainable alternative standard flexible electronics robotics. tests live monitoring SoftHand3, grasping system worldwide diffused robots, have yielded promising results. ingredients possibility recycling makes it an appealing face sustainability issue today's

Language: Английский

Citations

9

Water‐Induced Shape‐Locking Magnetic Robots DOI Creative Commons
He Lou, Yibin Wang,

Yifeng Sheng

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: unknown

Published: July 29, 2024

Untethered magnetic soft robots capable of performing adaptive locomotion and shape reconfiguration open up possibilities for various applications owing to their flexibility. However, are typically composed materials with fixed modulus, making them unable exert or withstand substantial forces, which limits the exploration new functionalities. Here, water-induced, shape-locking magnetically controlled change water-induced introduced. The phase separation enables these undergo a modulus transition from 1.78 MPa in dry state 410 after hydration. Moreover, body material's inherent self-healing property direct assembly morphing structures complicated magnetization profiles. These can be delivered through actuation perform programmed tasks including supporting, blocking, grasping by on-demand deformation subsequent stiffening. water-stiffening stent is developed, its precise delivery demonstrated vascular phantom. combination untethered delivery, change, stiffening properties makes proposed promising biomedical applications.

Language: Английский

Citations

3

Closed‐Loop Recyclable Silica‐Based Nanocomposites with Multifunctional Properties and Versatile Processability DOI Creative Commons
Yi Hou, Guangda Zhu, Samantha O. Catt

et al.

Advanced Science, Journal Year: 2023, Volume and Issue: 10(35)

Published: Oct. 16, 2023

Abstract Most plastics originate from limited petroleum reserves and cannot be effectively recycled at the end of their life cycle, making them a significant threat to environment human health. Closed‐loop chemical recycling, by depolymerizing into monomers that can repolymerized, offers promising solution for recycling otherwise wasted plastics. However, most current chemically recyclable polymers may only prepared gram scale, depolymerization typically requires harsh conditions high energy consumption. Herein, it reports less petroleum‐dependent closed‐loop silica‐based nanocomposites on large scale have fully reversible polymerization/depolymerization capability room temperature, based catalysis free aminopropyl groups with assistance diethylamine or ethylenediamine. The show glass‐like hardness yet plastic‐like light weight toughness, exhibiting highest specific mechanical strength superior even common materials such as poly(methyl methacrylate), glass, ZrO 2 ceramic, well demonstrating multifunctionality anti‐fouling, low thermal conductivity, flame retardancy. Meanwhile, these easily processed various scalable manufacturing methods, compression molding 3D printing. These are expected provide an alternative petroleum‐based contribute economy.

Language: Английский

Citations

7