ACS Energy Letters,
Journal Year:
2024,
Volume and Issue:
unknown, P. 484 - 495
Published: Dec. 27, 2024
Photochromism
(PC)
involves
profound
and
complex
optoelectronic
processes
the
interplay
of
color
centers
host
matrix.
To
date,
achieving
a
fast
PC
response
speed
remains
challenge.
Here,
new
"twin-perovskite"
niobate
ceramic,
Ba8Ti3Nb4O24:
Pr3+
(BTN:Pr3+),
exhibiting
remarkable
time
down
to
20
ms
record
contrast
42.3%
among
niobate-based
materials,
is
identified.
Experimental
theoretical
approaches
reveal
key
role
oxygen
vacancy
in
reaction.
It
proposed
that
related
short
spent
redistributing
charge
carriers
due
single
type
center
quick
transport
within
densely
packed
crystal
framework
featuring
face-sharing
twin-plane
structure.
Finally,
we
present
demo
experiments
real-time
write-display
information
repeatable
manner
demonstrate
bit-by-bit
optical
storage
at
high
write
speeds
could
be
read
dual
modes.
Advanced Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 16, 2025
Abstract
Upconversion
nanoparticles
(UCNPs),
incorporating
lanthanide
(Ln)
dopants,
can
convert
low‐energy
near‐infrared
photons
into
higher‐energy
visible
or
ultraviolet
light
through
nonlinear
energy
transfer
processes.
This
distinctive
feature
has
attracted
considerable
attention
in
both
fundamental
research
and
advanced
optoelectronics.
Challenges
such
as
low
energy‐conversion
efficiency
nonradiative
losses
limit
the
performance
of
UCNP‐based
optoelectronic
devices.
Recent
advancements
including
optimized
core–shell
structures,
tailed
Ln‐doping
concentration,
surface
modifications
show
significant
promise
for
improving
stability.
In
addition,
combining
UCNPs
with
functional
materials
broaden
their
applications
improve
device
performance,
paving
way
innovation
next‐generation
paper
first
categorizes
elaborates
on
various
upconversion
mechanisms
UCNPs,
focusing
strategies
to
boost
prolong
luminescence.
Subsequently,
an
in‐depth
discussion
that
enhance
expand
functionality
is
provided.
Furthermore,
a
wide
range
devices
explored,
multiple
emerging
neuromorphic
computing
are
highlighted.
Finally,
existing
challenges
potential
solutions
involved
developing
practical
considered,
well
outlook
future
technologies
Analytical Chemistry,
Journal Year:
2024,
Volume and Issue:
96(29), P. 12139 - 12146
Published: July 11, 2024
Precise
modulation
of
host-guest
interactions
between
programmable
Ln-MOFs
(lanthanide
metal-organic
frameworks)
and
phosphate
analytes
holds
immense
promise
for
enabling
novel
functionalities
in
biosensing.
However,
the
intricate
relationship
these
structures
remains
largely
elusive.
Understanding
this
correlation
is
crucial
advancing
rational
design
fluorescent
biosensor
technology.
Presently,
there
exists
a
large
research
gap
concerning
utilization
Ln-MOFsto
monitor
conversion
ATP
to
ADP,
which
poses
limitation
kinase
detection.
In
work,
we
delve
into
potential
amplify
fluorescence
response
during
kinase-mediated
ATP-to-ADP
conversion.
Six
Eu-MOFs
were
synthesized
Eu-TPTC
([1,1':4',1″]-terphenyl-3,3'',5,5''-tetracarboxylic
acid)
was
selected
as
ratiometric
probe,
most
suitable
high-precision
detection
creatine
activity
through
differential
from
ADP.
The
molecular
-level
mechanism
confirmed
by
density
functional
theory.
Furthermore,
simple
paper
chip-based
platform
constructed
realize
fast
(20
min)
sensitive
(limit
0.34
U/L)
biological
samples.
Ln-MOF-phosphate
offer
promising
avenues
assays
hold
precise
customization
analytical
chemistry.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(35), P. 16418 - 16428
Published: Aug. 20, 2024
Lanthanide
metal-organic
frameworks
(Ln-MOFs)
have
excellent
optical
properties
and
structural
diversity,
providing
a
unique
platform
for
the
development
of
fluorescent
sensing
materials.
In
work
described
herein,
series
isostructural
3D
Ln-MOFs
[Ln(L)(H
Journal of Materials Chemistry C,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
Lu-MOFs
with
formic
acid
as
the
sole
ligand
were
synthesized
by
a
formamide
hydrolysis
reaction.
The
luminescence
color
and
intensity
of
Lu–Eu-MOFs-bipy
can
be
controlled
energy
competition
transfer
between
4,4′-bipyridine
Eu
3+
.
ACS Energy Letters,
Journal Year:
2024,
Volume and Issue:
unknown, P. 484 - 495
Published: Dec. 27, 2024
Photochromism
(PC)
involves
profound
and
complex
optoelectronic
processes
the
interplay
of
color
centers
host
matrix.
To
date,
achieving
a
fast
PC
response
speed
remains
challenge.
Here,
new
"twin-perovskite"
niobate
ceramic,
Ba8Ti3Nb4O24:
Pr3+
(BTN:Pr3+),
exhibiting
remarkable
time
down
to
20
ms
record
contrast
42.3%
among
niobate-based
materials,
is
identified.
Experimental
theoretical
approaches
reveal
key
role
oxygen
vacancy
in
reaction.
It
proposed
that
related
short
spent
redistributing
charge
carriers
due
single
type
center
quick
transport
within
densely
packed
crystal
framework
featuring
face-sharing
twin-plane
structure.
Finally,
we
present
demo
experiments
real-time
write-display
information
repeatable
manner
demonstrate
bit-by-bit
optical
storage
at
high
write
speeds
could
be
read
dual
modes.
