Enabling superior cathode/sulfide electrolyte interfacial stability by Li3BO3 coating for all solid-state Li battery DOI
Jiashuai Wang, Chengdeng Wang, Haofeng Shi

et al.

Journal of Materials Science, Journal Year: 2024, Volume and Issue: 59(44), P. 20671 - 20685

Published: Nov. 1, 2024

Language: Английский

Construction of LiCl/LiF/LiZn hybrid SEI interface achieving high-performance sulfide-based all-solid-state lithium metal batteries DOI

Chaochao Wei,

Yujie Xiao,

Zhongkai Wu

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: 67(6), P. 1990 - 2001

Published: May 11, 2024

Language: Английский

Citations

35

Fluorine-Doped High-Performance Li6PS5Cl Electrolyte by Lithium Fluoride Nanoparticles for All-Solid-State Lithium-Metal Batteries DOI

Xiaorou Cao,

Shijie Xu, Yuzhe Zhang

et al.

Transactions of Tianjin University, Journal Year: 2024, Volume and Issue: 30(3), P. 250 - 261

Published: June 1, 2024

Language: Английский

Citations

6

Key challenges and advancements toward fast-charging all-solid-state lithium batteries DOI
Niaz Ahmad,

Cailing Fan,

Muhammad Faheem

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(18), P. 9529 - 9553

Published: Jan. 1, 2024

Next-generation energy storage systems rely heavily on the capability of fast charging as they allow electronic devices to be charged within a remarkably brief period.

Language: Английский

Citations

6

Tailored Engineering on the Interface Between Lithium Metal Anode and Solid‐State Electrolytes DOI Creative Commons
Qi Zhou,

Xiaosong Xiong,

Jun Peng

et al.

Energy & environment materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 4, 2024

The replacement of non‐aqueous organic electrolytes with solid‐state (SSEs) in lithium metal batteries (SLMBs) is considered a promising strategy to address the constraints lithium‐ion batteries, especially terms energy density and reliability. Nevertheless, few SLMBs can deliver required cycling performance long‐term stability for practical use, primarily due suboptimal interface properties. Given diverse solidification pathways leading different characteristics, it crucial pinpoint source deterioration develop appropriate remedies. This review focuses on Li|SSE issues between anode SSE, discussing recent advancements understanding (electro)chemistry, impact defects, evolutions that vary among SSE species. state‐of‐the‐art strategies concerning modified SEI, artificial interlayer, surface architecture, composite structure are summarized delved into internal relationships characteristics enhancements. current challenges opportunities characterizing modifying suggested as potential directions achieving SLMBs.

Language: Английский

Citations

4

Unravelling the electrochemical evolution mechanism of In2O3 anode in long-cycle all-solid-state lithium batteries with sulfide electrolytes DOI
Wanping Liu, Jun Liu, Xuelei Li

et al.

Rare Metals, Journal Year: 2025, Volume and Issue: unknown

Published: March 15, 2025

Language: Английский

Citations

0

Activating Forbidden Intercage‐Ionic‐Diffusivity by Anion‐Gradient‐Disordered Interphase for Ultrastable Argyrodite‐Based All‐Solid‐State Lithium Metal Batteries DOI
Ruiqi Guo,

Yuxi Zhong,

Peng Yu

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: April 24, 2025

Abstract Lithium argyrodite sulfide electrolytes show great potential in all‐solid‐state lithium metal batteries (ASSLMBs) due to their high ionic conductivity and ductile feature, among which Li 6 PS 5 I presents the most promising stability with metals but a low (≈10 −6 S cm −1 ). It is because of absence 2− /I − disorder thus forbidden + ion intercage migrations. Herein, particles iodine‐gradient‐disordered interphase were designed that opened up proscribed jumps synergistically blocked interfacial electron leakage for ultrastable ASSLMBs. Density functional theory calculations 7 spin‐lattice relaxation NMR experiments prove activated even accelerated conduction reduced migration barrier. Electrostatic profiles also certify transition‐shielding as origin parasitic‐reaction‐free interface. Gathered evidence of, other characterizations demonstrated combination conductivities (cold press 5.7 mS ), (1.5×10 −8 improved critical current density (1.65 mA −2 excellent (over 1,500 h) prominent cycling rate performance. This study provides insights on novel design fulfill cooperatively metal‐compatibility high‐performance

Language: Английский

Citations

0

Ca‐substituted Na3SbS4 glass–ceramic electrolytes: Achieving high conductivity and excellent interfacial stability DOI

Yu Shen,

Huan Tao,

Jingxin Lu

et al.

Journal of the American Ceramic Society, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 15, 2025

Abstract Super conductor Na 3 SbS 4 has received substantial attention in electrolyte research because of its high ionic conductivity and low grain boundary resistance. A breakthrough electrochemical stability with good yet to be captured. Calcium (Ca) appears as an ideal substitute for sodium (Na) due abundance geological resources, nontoxic properties, equivalent radius. The proposed 3‐2 x Ca glass–ceramic electrolytes were subsequently manufactured using ball milling heat treatment. results acquired the maximum 1.59 mS cm −1 at room temperature, which reached commercial use level when compared current popular lithium‐ion battery. Moreover, calcium ions partially replaced sites while creating massive vacancies maintain charge neutrality, resulting fast ion transport. Furthermore, a more stable bond Ca–S was formed interface, inhibited additional reactions electrolyte–metal interface demonstrated exceptional cyclic stability, making it viable solid‐state sodium‐ion batteries.

Language: Английский

Citations

0

Suppressing Hydrogen Evolution and Dendrite Formation on a Zn Anode by Coating In2O3 with Tailored Affinity to H* and Zn* DOI

Zeshen Deng,

Wenbiao Zhang, Qingsheng Gao

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: March 6, 2025

To suppress the hydrogen evolution reaction (HER) and dendrite formation on Zn anode in aqueous Zn-ion batteries, a submicrometer In2O3 coating (referred to as Zn@In2O3) was constructed via magnetron sputtering. Density functional theory (DFT) experimental data show that suppresses HER because of its weaker interactions with H* compared Zn, inhibiting Volmer step. At same time, exhibits moderate affinity for Zn*, higher than but lower at In2O3-Zn interface, thus facilitating desolvation hydrated Zn2+ ions while promoting deposition substrate beneath coating. The resultant suppression side reactions growth significantly enhance reversible plating/stripping Zn. optimized Zn@In2O3 stably cycles over 6400 h low voltage hysteresis 9.5 mV 1 mA cm-2 mAh symmetric cells. average Coulombic efficiency is increased from 95.8 99.6% owing Moreover, when coupled Mn0.15V2O5·nH2O cathode, battery maintains capacity retention 78.6% after 2000 5 A g-1. This facile economical modification anodes provides an idea realizing practical application AZIBs.

Language: Английский

Citations

0

Rocksalt-structured LiBi1-Sb S2 solid solution for all-solid-state batteries DOI
Yan Yang,

Zesen Gao,

Futing Sun

et al.

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 641, P. 236820 - 236820

Published: March 22, 2025

Language: Английский

Citations

0

Ge–O Dual-Doping toward a Highly Conductive, Air-Stable, and Lithium-Compatible Argyrodite Solid Electrolyte for All-Solid-State Lithium Batteries DOI
Yuhao Zhang, Bosen Zhang, Ting Pan

et al.

ACS Applied Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 4, 2025

Language: Английский

Citations

0