Environmental Science and Pollution Research, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 19, 2024
Language: Английский
Environmental Science and Pollution Research, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 19, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 486, P. 150163 - 150163
Published: March 4, 2024
Language: Английский
Citations
44Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(15)
Published: Feb. 15, 2024
Abstract Photocatalytic oxygen reductive H 2 O production is a promising approach to alternative industrial anthraquinone processes while suffering from the requirement of pure feedstock for practical application. Herein, we report spaced double hydrogen bond (IC−H‐bond) through multi‐component Radziszewski reaction in an imidazole poly‐ionic‐liquid composite (SI‐PIL‐TiO ) and levofloxacin hydrochloride (LEV) electron donor highly efficient selective photocatalytic air production. It found that IC−H‐bond formed by imino (−NH−) group SI‐PIL‐TiO carbonyl (−C=O) LEV can switch active sites characteristic covered state fully exposed one shield strong adsorption N air, propel intenser positive potential more orbitals binding patterns surface establish competitive selectivity chemisorption. Moreover, high enrichment as site 2e − reduction ensures rapid . Therefore, enables total utilization conversion efficiency 94.8 % direct reduction, achieving rate 1518 μmol/g/h 16 23 times compared without groups (PIL‐TiO TiO , respectively.
Language: Английский
Citations
39Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(31)
Published: May 20, 2024
How to achieve CO
Language: Английский
Citations
16Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(49)
Published: Aug. 13, 2024
Abstract The photoconversion of CO 2 into valuable chemical products using solar energy is a promising strategy to address both and environmental challenges. However, the strongly adsorbed frequently impedes seamless advancement subsequent reaction by significantly increasing activation energy. Here, we present BiFeO 3 material with lattice strain that collaboratively regulates d/p‐2π* orbitals hybridization between metal sites *CO as well *COOH intermediates achieve rapid conversion solidly critical intermediates, accelerating overall reduction kinetics. Quasi in situ X‐ray photoelectron spectroscopy Fourier Transform infrared combined theoretical calculation reveals optimized Fe enhance adsorption effect , continuous internal electrons are rapidly transferred injected surface under condition illumination, which promotes formation stability *COOH. Certainly, performance photoreduction improved 12.81‐fold compared base material. This work offers new perspective for process .
Language: Английский
Citations
9Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: unknown, P. 136242 - 136242
Published: Jan. 1, 2025
Language: Английский
Citations
1Chemical Papers, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 7, 2025
Language: Английский
Citations
1Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 128945 - 128945
Published: July 24, 2024
Language: Английский
Citations
7Reaction Kinetics Mechanisms and Catalysis, Journal Year: 2024, Volume and Issue: 137(5), P. 2847 - 2866
Published: May 28, 2024
Language: Английский
Citations
6Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 673, P. 943 - 957
Published: June 6, 2024
Language: Английский
Citations
6Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(19), P. 11591 - 11601
Published: Jan. 1, 2024
Visible-light photocatalytic reduction of carbon dioxide with the help photocatalysts has become an important means to mitigate greenhouse effect.
Language: Английский
Citations
5