Assembling Molecular Semiconductor Composite for Enhanced Photocatalytic Cyclohexene Oxidation DOI

Haiyan Yu,

Xueting Wang, Tingting Kong

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A molecular semiconductor composite was assembled by integrating atomically precise Ti 12 -oxo clusters and phosphotungstic acid into a cocrystal system.

Language: Английский

2D sp2 carbon-linked benzotrithiophene covalent organic frameworks for selective sulfoxidation with oxygen driven by green light DOI

Fengwei Huang,

Fulin Zhang,

Yuexin Wang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124628 - 124628

Published: Sept. 1, 2024

Language: Английский

Citations

2
A 2D sp2 Carbon Conjugated Pyrene Covalent Organic Framework with TEMPO for Selective Photocatalysis DOI Open Access
Huimin Hao, Fulin Zhang, Xiaoxiao Wang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 31, 2024

Abstract With recent developments, covalent organic frameworks (COFs) have attracted considerable attention in various applications, including visible light photocatalysis. Considering the properties of pyrene planum and π ‐electron conjugation, 2D sp 2 carbon‐conjugated imine‐linked COFs, Py‐sp c‐COF Py‐COF are synthesized with a well‐ordered crystalline structure. is significantly superior to for selective photocatalysis due carbon conjugation. By virtue porosity activity, TEMPO ((2,2,6,6‐tetramethylpiperidin‐1‐yl)oxyl) turns out be effective aerobic oxidation amines imines induced by green light. Substantially, mol% TEMPO, an electron–proton transfer mediator, facilitates conversions It ingenious design transformations cooperative COF redox mediator.

Language: Английский

Citations

2
Recent Progress on Bismuth-Based Materials for Full-Spectrum-Driven Photocatalysis DOI
Jing Liu, Shuo Du,

Qiuhui Zhu

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 114790 - 114790

Published: Nov. 1, 2024

Language: Английский

Citations

1
Optimal solutions and control strategies for photocatalytic conversion of toluene DOI Creative Commons
Liquan Jing, Hui Wang, Zheng Li

et al.

Resources Chemicals and Materials, Journal Year: 2024, Volume and Issue: unknown

Published: June 1, 2024

Toluene is widely used as a raw material for many chemical products/pharmaceutical intermediates and solvent in manufacturing industries. The conversion of toluene into higher value chemicals (benzyl alcohol, benzaldehyde, benzoic acid, etc.) using sunlight very promising means. To achieve the full utilization toluene, it necessary to construct photocatalysts with high selectivity while synergistically optimizing optimal reaction environment significantly affect photoconversion toluene. High-performance not only absorb sunlight, but also have abundant active sites generation free radicals, which can promote bonds cleavage thus greatly increasing yield higher-valued products. In addition, type photocatalyst modification strategy would influence photo-conversion. Therefore, makes sense that this review presents mechanism factors (mainly) photo-oxidation thorough analysis prediction by theoretical calculations, oxidation different (in particular halogen-containing perovskite materials) specific products, well photocatalysts' modifications. Finally, challenges prospects designing efficient process are summarized.

Language: Английский

Citations

0
Assembling Molecular Semiconductor Composite for Enhanced Photocatalytic Cyclohexene Oxidation DOI

Haiyan Yu,

Xueting Wang, Tingting Kong

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A molecular semiconductor composite was assembled by integrating atomically precise Ti 12 -oxo clusters and phosphotungstic acid into a cocrystal system.

Language: Английский

Citations

0