Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption DOI Creative Commons

Jian‐Jian Bian,

S. C. Tang,

Jiao Miao

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(48), P. 35697 - 35703

Published: Jan. 1, 2024

Two categories of supramolecular polymer monomers were produced by introducing the ureidopyrimidone quadruple-hydrogen bonding assemblies on calix[4]arene and β-cyclodextrin host units. The adsorption capacity these polymers for different metal ions was investigated static adsorption. results showed that at pH = 6 when equilibrium reached, with calixarene as main body adsorbed up to 99% Pb

Language: Английский

Fireproof Solid Polymer Electrolyte with Chemically Bonded Phosphorus Toward Stable and Safe Lithium‐Metal Battery DOI
Zhenxi Li,

Shuangshuang Zhu,

Shilun Gao

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 2, 2024

Abstract Lithium‐metal batteries (LMBs) are considered one of the most promising next‐generation high‐energy‐density battery systems. However, leakage problem and fire hazard commercial liquid electrolytes hinder their practical applications. Herein, a flame‐retardant solid polymer electrolyte (FRSPE) is fabricated by in situ polymerization methyl methacrylate (MMA), allyl diglycol carbonate (ADC), monomer, i.e., diethyl vinyl phosphonate (DEVP), which phosphorus chemically bonded to matrix avoid parasitic reaction between molecules with lithium (Li) anode. Compared previously reported (SPEs) possessing free phosphorus, significantly increased efficiency improved electrochemical performance can be achieved. With wide window (≈4.4V), high ionic conductivity (1.8 × 10 −4 S cm −1 ), superior compatibility Li anode, assembled Li/FRSPE/LiFePO 4 (LFP) cell exhibits stable cycling over temperature range (capacity retention 70.9%@1000 cycles 69.1%@200 at 25 80 °C, respectively). Furthermore, high‐voltage full cells, e.g., Li/LiCoO 2 (LCO) Li/LiNi 0.8 Co 0.1 Mn O (NCM811), FRSPE also deliver excellent performance. The current design principle framework provide new pathway for developing practical, safe, LMBs.

Language: Английский

Citations

4
Thermal-responsive luminescence/dielectric responses with reversibly shifted light emissions DOI Creative Commons
Mingming Zhu,

Pei‐Zhi Huang,

Linmei Li

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

By incorporating 18-crown-6 into PP-1, we constructed a molecular-rotor-type material, PCP-1, which exhibited switchable dielectrics and temperature-controlled PL response.

Language: Английский

Citations

0
Adhesion and Affinity of Supramolecular Adhesive on Fluorinated Surfaces DOI

Guohong Yao,

Zhiyuan Guo,

Gai Zhao

et al.

Materials Horizons, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The balance between cohesion and adhesion is controlled by a binary system in which tetrafluorophthalic acid the functional core of to fluoroplastics via fluorine–fluorine interactions OH⋯F/OH⋯O hydrogen bonds.

Language: Английский

Citations

0
Robust and tough polyamide hot-melt adhesives inspired by intersecting structures of plant cell walls and cytoplasm: Design for environmental adaptability DOI
Huajun Sun,

Kangbo Yang,

Nan Xiang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162564 - 162564

Published: April 1, 2025

Language: Английский

Citations

0
Mucus-Inspired Supramolecular Adhesives: Exploring the Synergy between Dynamic Networks and Functional Liquids DOI Creative Commons
Changshun Hou, Wenqing He, Xi Yao

et al.

ACS Nano, Journal Year: 2025, Volume and Issue: unknown

Published: April 14, 2025

The exceptional physicochemical and mechanical properties of mucus have inspired the development dynamic mucus-based materials for a wide range applications. Mucus's combination noncovalent interactions rich liquid phases confer properties. This perspective explores synergy between networks functional liquids in mucus-inspired supramolecular adhesives. It delves into biological principles underlying mucus's regulation adhesive properties, fundamentals design, transformative potential these biomedical Finally, this proposes directions molecular engineering materials, emphasizing need interdisciplinary approaches to harness their full sustainable

Language: Английский

Citations

0
A mild recycling of flame-retarding bisphenol-A epoxy towards formaldehyde-free wood adhesive by introducing hydrazone/ester dual reversible bonds DOI
Weijun Yang,

Lianhua Chen,

Ning Ding

et al.

Construction and Building Materials, Journal Year: 2025, Volume and Issue: 476, P. 141286 - 141286

Published: April 15, 2025

Language: Английский

Citations

0
Biphenylation, ester-free and stepwise reaction strategy of thiol-epoxy crosslinking network for durable thermally and hygrothermally resistant electronic packaging DOI
Chaobin He, Jingtao Zhou,

Xueyi Pan

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162891 - 162891

Published: April 1, 2025

Language: Английский

Citations

0
Spider Silk-Inspired Bio-Based Adhesive: Robust Adhesion Strength, Exceptional Flame Retardancy, and Full Recyclability DOI

Jin-Feng Feng,

Ting Wang,

Caihong Xu

et al.

ACS Materials Letters, Journal Year: 2025, Volume and Issue: unknown, P. 2031 - 2040

Published: April 27, 2025

Language: Английский

Citations

0
Nucleotide‐Tackified Degradable and Closed‐Loop Recyclable Underwater Adhesive DOI

Mingsong Huang,

Lingyu Liu,

Wei Guo

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 28, 2024

Abstract Sustainable underwater adhesives have drawn much interest in promising applications and environmental engineering. However, developing a convenient strategy to combine recyclability adhesion into adhesive materials remains formidable challenge. In this work, degradable closed‐loop recyclable tackifier is designed by nucleotide, via the ring‐opening polymerization of thioctic acid presence 5′‐adenosine monophosphate methacrylatoethyl trimethyl ammonium chloride. The nucleotide‐tackified present an excellent for various materials, tissues, on‐demand detachment behavior. demonstrate reusability, degradability, dual monomers monophosphate. Interestingly, waste residues processability can be employed again construction tough interfaces both air underwater, with further expanding sustainability. It envisioned that sustainable would offer insights advancing materials.

Language: Английский

Citations

3
Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption DOI Creative Commons

Jian‐Jian Bian,

S. C. Tang,

Jiao Miao

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(48), P. 35697 - 35703

Published: Jan. 1, 2024

Two categories of supramolecular polymer monomers were produced by introducing the ureidopyrimidone quadruple-hydrogen bonding assemblies on calix[4]arene and β-cyclodextrin host units. The adsorption capacity these polymers for different metal ions was investigated static adsorption. results showed that at pH = 6 when equilibrium reached, with calixarene as main body adsorbed up to 99% Pb

Language: Английский

Citations

0